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CAS: 620-72-4
分子式: C8H7BrO2
分子量: 215.05
沸点: 134℃(15
熔点: 31-33℃
中文名称: 
α-溴乙酸苯酯
溴乙酸苯丙酯
英文名称: 
phenyl bromoacetate
Phenyl -bromoacetate
Bromoacetic acid phenyl ester
性质描述: 片状结晶。熔点32℃,沸点140℃(2.67kPa)。溶于乙醇和乙醚。
生产方法: 由苯酚与溴乙酰溴反应而得。将新蒸馏的苯酚加入溴乙酰溴中,缓缓加热至110℃,保温2h,用碱液吸收反应放出的溴化氢。反应毕,减压蒸馏,收集105-110℃(0.93kPa)馏分,得溴乙酸苯酯。
用途: 用作油漆和金属切削液的防腐剂。
推荐供应商
货号品牌产品名称规格包装、参考价格
P815529MACKLIN溴乙酸苯酯98%29元/5g;   55元/25g;   215元/100g;   998元/500g;   咨询
储存:室温
状态:白色到棕色固体,粉末或晶体
P1936TCIPhenyl Bromoacetate>95.0%(GC)450元/25G;   咨询

基本信息

纯度/分析方法>95.0%(GC)
分子式/分子量C8H7BrO2 = 215.05
外观与形状(20℃)固体
Reaxys-RN1940686
PubChem物质ID125308075
MDL编号MFCD00192391

技术规格

AppearanceWhite or Colorless to Yellow to Orange powder to lump to clear liquid
Purity(GC)min. 95.0 %

物性(参考值)

熔点31 ℃
沸点112 ℃/2 mmHg

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
484232J&KPhenyl Bromoacetate98%471元/10G;   2113元/50G;   咨询

基本信息

分子式C8H7BrO2
分子量215.04
熔点31-33
沸点134
密度1.508
MDL编码MFCD00192391

安全信息

防范说明P262
WGK3
H60464Alfa AesarPhenyl Bromoacetate98%613元/5g;   5003元/50g;   咨询

应用
Phenyl bromoacetate may be employed as alkylation reagent in the preparation of 2-(phenoxycarbonyl)methyl triazoles. It may be used in the synthesis of the A-ring of cylindrospermopsin and in the synthesis of 2-{2-[1-(4-hydroxy-6-methyl-2-oxo-2H-pyran-3-yl)ethylidene]hydrazinyl}-1,3-thiazolidin-4-one3, 2-{2-[1-(4-hydroxy-6-methyl-2-oxo-2H-pyran-3-yl)ethylidene]hydrazinyl}-3-methyl-1,3-thiazolidin-4-one3, 3-ethyl-2-{2-[1-(4-hydroxy-6-methyl-2-oxo-2H-pyran-3-yl)ethylidene]hydrazinyl}-1,3-thiazolidin-4-one3 and 2-{2-[1-(4-hydroxy-6-methyl-2-oxo-2H-pyran-3-yl)ethylidene] hydrazinyl}-3-phenyl-1,3-thiazolidin-4-one3.

备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store under inert gas.

基本信息

MDL
MFCD00192391

分子式
C8H7BrO2

分子量
215.04

熔点
31-33°

沸点
134°

闪点
113°(235°F)

密度
1.508

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Soluble in ethanol and ether, insoluble in water.

安全信息

TSCA

404276Sigma-AldrichPhenyl Bromoacetate98%1150.11元/10 G;   3823.72元/50 G;   咨询

产品说明

一般描述

Phenyl bromoacetate is an aromatic ester.

应用

Phenyl bromoacetate may be employed as alkylation reagent in the preparation of 2-(phenoxycarbonyl)methyl triazoles. It may be used in the synthesis of the A-ring of cylindrospermopsin. It may be used in the synthesis of the following 4-thiazolidinones:

  • 2-{2-[1-(4-hydroxy-6-methyl-2-oxo-2H-pyran-3-yl)ethylidene]hydrazinyl}-1,3-thiazolidin-4-one
  • 2-{2-[1-(4-hydroxy-6-methyl-2-oxo-2H-pyran-3-yl)ethylidene]hydrazinyl}-3-methyl-1,3-thiazolidin-4-one
  • 3-ethyl-2-{2-[1-(4-hydroxy-6-methyl-2-oxo-2H-pyran-3-yl)ethylidene]hydrazinyl}-1,3-thiazolidin-4-one
  • 2-{2-[1-(4-hydroxy-6-methyl-2-oxo-2H-pyran-3-yl)ethylidene] hydrazinyl}-3-phenyl-1,3-thiazolidin-4-one

包装

10, 50 g in glass bottle

基本信息

线性分子式BrCH2CO2C6H5
分子量215.04
MDL编号MFCD00192391
PubChem化学物质编号24865235
NACRESNA.22

产品性质

测定98%
bp134 ℃/15 mmHg (lit.)
mp31-33 ℃ (lit.)
密度1.508 g/mL at 25 ℃ (lit.)
SMILES stringBrCC(=O)Oc1ccccc1
InChI1S/C8H7BrO2/c9-6-8(10)11-7-4-2-1-3-5-7/h1-5H,6H2
InChI keyUEWYUCGVQMZMGY-UHFFFAOYSA-N

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type N95 (US)
235583FluorochemPhenyl 2-bromoacetate95%264元/10g;   528元/25g;   1628元/100g;   10186元/1kg;   咨询

基本信息

CAS Number620-72-4
MDL NumberMFCD00192391
Density1.508

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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