CAS 619-45-4; 对氨基苯甲酸甲酯; p-amino-benzoic aci methyl ester

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M813645

MACKLIN

4-氨基苯甲酸甲酯

98.0%

30元/5g; 48元/25g; 177元/100g; 738元/500g;

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储存：室温,密封
状态：白色到米黄色粉末或晶体

A0510

TCI

Methyl 4-Aminobenzoate

>98.0%(GC)(T)

590元/25G;

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基本信息

纯度/分析方法	>98.0%(GC)(T)
分子式/分子量	C₈H₉NO₂ = 151.17
外观与形状(20℃)	固体
Reaxys-RN	775913
PubChem物质ID	87562121
SDBS (AIST Spectral DB)	6174
MDL编号	MFCD00007891

技术规格

Appearance	White to Light yellow powder to crystal
Purity(GC)	min. 98.0 %
Purity(Nonaqueous Titration)	min. 98.0 %
Melting point	111.0 to 115.0 ℃

物性(参考值)

熔点	114 ℃
水溶性	不溶
溶解性(可溶于)	甲醇

安全信息

图形或危害标志
信号词	警告
危险性说明	H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。
防范说明	P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/戴防护眼罩/戴防护面具。 P302 + P352 : 如皮肤沾染：用水充分清洗。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P332 + P313 : 如发生皮肤刺激：求医/就诊。

相关法规

RTECS#

DG2900000

199735

J&K

Methyl 4-Aminobenzoate

98%

116元/5G; 464元/25G; 1302元/100G; 5198元/500G;

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基本信息

分子式	C₈H₉NO₂
分子量	151.16
熔点	110-111
MDL编码	MFCD00007891
EINECS 编号	210-598-7

安全信息

图形或危害标志
提示语	Warning
危险说明	H316 H320 H335
防范说明	P280 P305+P351+P338
WGK	3
RTECS	DG2900000
TSCA	否

A11715

Alfa Aesar

Methyl 4-Aminobenzoate

98%

1293元/25g; 3840元/100g; 16168元/500g;

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应用
Methyl 4-aminobenzoate is used in the synthesis of guanidine alkaloids, (?±)-martinelline and (?±)-martinellic acid by a protic acid catalyzed hetero Diels-Alder coupling reaction with N-Cbz 2-pyrroline. It is also used in organic synthesis and acts as a dye intermediate. Further, it is used to prepare 4-(2-methyl-4-oxo-4H-quinazolin-3-yl)-benzoic acid methyl ester by reacting with 2-acetylamino-benzoic acid.

备注
Incompatible with strong oxidizing agents and strong bases.

基本信息

MDL
MFCD00007891

EINECS
210-598-7

分子式
C₈H₉NO₂

分子量
151.17

熔点
110-114°

灵敏度
Ambient temperatures.

形态
Crystalline powder

溶解性
Soluble in alcohol and ether. Slightly soluble in water.

Beilstein
775913

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

RTECS
DG2900000

TSCA
是

C23528

Alfa Aesar

Methyl 4-Aminobenzoate

98%

1659元/25g; 4127元/100g;

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基本信息

Ref#
23528

MDL
7891

分子式
C8 H9 N O2

分子量
151.17

形态
White to cream cryst powder

安全信息

危险等级
6.1

包装组
III

274186

Sigma-Aldrich

Methyl 4-Aminobenzoate

98%

379.95元/5 G; 851.75元/25 G; 1807.53元/100 G;

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产品说明

一般描述

研究了过氧化氢对 4-氨基苯甲酸甲酯的催化氧化。

应用

4-氨基苯甲酸甲酯用于通过质子酸催化的杂 Diels-Alder 与 N-Cbz 2-吡咯啉的偶联反应合成胍生物碱、(±)-马二碱和(±)-马来酸。

包装

5, 25, 100 g in glass bottle

基本信息

线性分子式	H₂NC₆H₄CO₂CH₃
分子量	151.16
Beilstein	775913
EC 号	210-598-7
MDL编号	MFCD00007891
PubChem化学物质编号	24856569
NACRES	NA.22

产品性质

质量水平	100
测定	98%
mp	110-111 ℃ (lit.)
SMILES string	COC(=O)c1ccc(N)cc1
InChI	1S/C8H9NO2/c1-11-8(10)6-2-4-7(9)5-3-6/h2-5H,9H2,1H3
InChI key	LZXXNPOYQCLXRS-UHFFFAOYSA-N

安全信息

储存分类代码	13 - Non Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves

035825

Fluorochem

Methyl 4-Aminobenzoate

98%

286元/10g; 440元/25g; 880元/100g;

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基本信息

CAS Number	619-45-4
MDL Number	MFCD00007891
Boiling Point	299℃ /760 mmHg
Melting Point	110-113℃

安全信息

图形或危害标志
危险性说明	H302: Harmful if swallowed. H315: Causes skin irritation. H319: Causes serious eye irritation. H332: Harmful if inhaled. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing . P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see relevant procedures. on this label). P330: Rinse mouth. P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to in accordance with local regulation .