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CAS: 618-40-6
分子式: C7H10N2
分子量: 122.17
沸点: 75-78℃(3
中文名称: 
1-甲基-1-苯基肼
1-甲基-1-苯肼
英文名称: 
α-Methylphenylhydrazine
1-Methylphenylhydrazine
Methyl phenyl hydrazine
Phenyl methyl hydrazine
N-methyl-N-phenyl-hydrazine
Hydrazine,1-methyl-1-phenyl-
1-methyl-1-phenyl-hydrazin
1-methyl-1-phenylhydrazine
N-Methyl-N-phenylhydrazine
性质描述: 无色或浅黄色液体。沸点227℃(99.3kPa),131℃(4.67kPa),相对密度1.0404(20/4℃),折光率1.5691,闪点96℃。能与乙醇、乙醚、氯仿和苯混溶,微溶于水。
生产方法: 由N-亚硝基甲基苯胺还原而得。将锌粉和水搅成悬浮液,在10-20℃缓缓加入N-亚硝基甲基胺和冰醋酸配成的溶液,加毕,在室温下继续搅拌1h。然后加热到80℃,趁热滤出未反应的锌粉。滤液冷却后加入过量的40%氢氧化钠溶液,使沉淀出来的氢氧化钠重新溶解。分出油层,减压蒸馏,收集106-109℃(1.73kPa)馏分,即为成品。收率50%以上。
用途: 用于有机合成,用于酮和糖的测定。
推荐供应商
货号品牌产品名称规格包装、参考价格
M861916MACKLIN1-甲基-1-苯肼95%(GC)(T)133元/1g;   497元/5g;   2234元/25g;   咨询
储存:室温,干燥,惰性气体存储
状态:微黄色到非常暗黄色到非常暗橙色液体
M0399TCI1-Methyl-1-phenylhydrazine>95.0%(GC)(T)580元/5G;   1920元/25G;   咨询

基本信息

纯度/分析方法>95.0%(GC)(T)
分子式/分子量C7H10N2 = 122.17
外观与形状(20℃)液体
储存温度0-10℃
储存在惰性气体下存放于惰性气体之中
应避免的情况光,空气,加热
Reaxys-RN507683
PubChem物质ID87572460
SDBS (AIST Spectral DB)3073
MDL编号MFCD00007627

技术规格

AppearanceColorless to Yellow to Orange clear liquid
Purity(GC)min. 95.0 %
Purity(Nonaqueous Titration)min. 95.0 %

物性(参考值)

沸点109 ℃/15 mmHg
闪点92 ℃
比重1.04
折射率1.58
水溶性实际上不溶
溶解性(可与之混溶)乙醚,苯,氯仿,乙醇

安全信息

图形或危害标志
信号词警告
危险性说明H302 + H312 + H332 : 吞咽、皮肤接触或吸入有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H227 : 可燃液体。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P302 + P352 + P312 : 如皮肤沾染:用水充分清洗。如感觉不适,呼叫急救中心/医生。
P304 + P340 + P312 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。如感觉不适,呼叫急救中心/医生。
P403 + P235 : 存放在通风良好的地方。保持低温。

相关法规

RTECS#MV7712000
B22440Alfa Aesar1-Methyl-1-phenylhydrazine97%2580元/5g;   9272元/25g;   23495元/100g;   咨询

应用
1-Methyl-1-phenylhydrazine is used to make other chemicals.

备注
Storage temperature is 2 - 8?°C. Incompatible with oxidizing agents.

基本信息

MDL
MFCD00007627

EINECS
210-547-9

分子式
C7H10N2

分子量
122.17

沸点
54-55°/0.3mm

闪点
92°(198°F)

密度
1.038

折射率
1.5830

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Slightly soluble in water.

GHS危害和防范说明

GHS符号

Hazard Statements
H227-H302-H315-H319-H335
Combustible liquid.Harmful if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P210e-P261-P280a-P305+P351+P338-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
III

危险类别
22-36/37/38
Harmful if swallowed.Irritating to eyes, respiratory system and skin.

安全等级
23-26-36/37-60
Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
MV7712000

TSCA

C35479Alfa Aesar1-Methyl-1-phenylhydrazine96%2695元/5g;   12670元/25g;   咨询

基本信息

Ref#
35479

MDL
7627

分子式
C7 H10 N2

分子量
122.17

闪点
96

密度
1.04

安全信息

危险等级
6.1

包装组
III

093280Fluorochem1-Methyl-1-phenylhydrazine95%220元/1g;   1078元/5g;   3102元/25g;   咨询

基本信息

CAS Number618-40-6
MDL NumberMFCD00007627

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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