| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | |
| T819583 | MACKLIN | 1,1-硫代羰基二咪唑 | 95% | 40元/1g; 108元/5g; 350元/25g; 1230元/100g; 4325元/500g; | 咨询 |
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| C1376 | TCI | 1,1'-Thiocarbonyldiimidazole | >95.0%(GC)(T) | 700元/5G; 2310元/25G; | 咨询 |
基本信息 | 纯度/分析方法 | >95.0%(GC)(T) | | 分子式/分子量 | C7H6N4S = 178.21 | | 外观与形状(20℃) | 固体 | | 储存温度 | 0-10℃ | | 储存在惰性气体下 | 存放于惰性气体之中 | | 应避免的情况 | 湿气 (分解) | | Reaxys-RN | 609349 | | PubChem物质ID | 87566387 | | SDBS (AIST Spectral DB) | 13750 | | MDL编号 | MFCD00005289 |
技术规格 | Appearance | Light yellow to Brown powder to crystal | | Purity(GC) | min. 95.0 % | | Purity(Nonaqueous Titration) | min. 95.0 % | | Melting point | 97.0 to 106.0 ℃ |
物性(参考值) 安全信息 | 图形或危害标志 |  | | 信号词 | 警告 | | 危险性说明 | H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
| | 防范说明 | P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染：用水充分清洗。
P337 + P313 : 如仍觉眼刺激：求医/就诊。
P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激：求医/就诊。
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| 295030 | J&K | 1,1'-Thiocarbonyldiimidazole | 95% | 425元/5G; 1484元/25G; | 咨询 |
基本信息 | 分子式 | C7H6N4S | | 分子量 | 178.21 | | 熔点 | 96-103 | | MDL编码 | MFCD00005289 | | Beilstein | 609349 | | EINECS 编号 | 228-183-4 | | 存储条件 | Store at 2-8℃ Corrosives |
安全信息 | 图形或危害标志 |  | | 提示语 | Danger | | 危险说明 | H302
H314 | | 防范说明 | P280
P301+P312
P301+P330+P331
P305+P351+P338
P310 | | WGK | 3 |
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| B22008 | Alfa Aesar | 1,1'-Thiocarbonyldiimidazole | tech 90% | 1096元/10g; 3214元/50g; 10920元/250g; | 咨询 |
应用
1,1'-Thiocarbonyldiimidazole is used as a reagent for the deoxygenation of alcohols with tributyltin hydride and diols with lithium aluminum hydride. It is also used to deoxygenate carboxylic monosaccharide analogues. Further, it is a useful reagent involved in biochemical synthesis. In addition to this, it is used to prepare 1-[bis-(4-methoxy-phenyl)-methyl]-1H-imidazole by reacting with 4,4'-dimethoxy-benzhydrol. 备注
Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Store in a cool place. Incompatible with strong oxidizing agents and strong acids. 基本信息 MDL
MFCD00005289 EINECS
228-183-4 分子式
C7H6N4S 分子量
178.22 熔点
98-102° 灵敏度
Keep Cold. Moisture Sensitive. Store under Argon. 形态
Powder 溶解性
Soluble in terahydrofuran, toluene and dichloromethane. Beilstein
609349 GHS危害和防范说明 GHS符号
Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation. Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations. 安全信息 危险类别
36/37/38
Irritating to eyes, respiratory system and skin. 安全等级
26-37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste TSCA
否 |
| C16848 | Alfa Aesar | 1,1'-Thiocarbonyldiimidazole | 90%, tech. | 2149元/10g; 4394元/25g; | 咨询 |
基本信息 Ref#
16848 MDL
5289 分子式
C7 H6 N4 S 分子量
178.21 形态
Yellow powder |
| 88545 | Sigma-Aldrich | 1,1′-Thiocarbonyldiimidazole | ≥95.0% (S) | 262.01元/1 G; 865.38元/5 G; 2728.07元/25 G; | 咨询 |
产品说明 应用 - 1,1′-硫羰基二咪唑(TCDI)可用于在Corey-Winter烯烃合成中通过形成环状硫代碳酸酯而实现邻位二醇脱氧。
- 它可用于(+)-hapalindole Q、12-epi-fischerindole U和welwitindolinone A的对映选择性全合成。
- 它还可以作为链转移剂用于制备三硫代碳酸盐、黄酸盐和二硫代氨基甲酸盐，从而用于可逆加成断裂链转移和大分子设计(RAFT/MADIX)聚合。
包装 1, 5, 25 g in glass bottle 其他说明 用于合成硫酰胺；用于改进的 Corey-Winter 烯烃合成；通过醇与 Bu3SnH-AIBN 发生自由基反应制备硫代氨基甲酸酯 基本信息 | 经验(实验)分子式 | C7H6N4S | | 分子量 | 178.21 | | Beilstein | 609349 | | EC 号 | 228-183-4 | | MDL编号 | MFCD00005289 | | PubChem化学物质编号 | 57653315 | | NACRES | NA.22 |
产品性质 | 质量水平 | 200 | | 测定 | ≥95.0% (S) | | reaction suitability | reaction type: Carbonylations | | mp | 98-102 ℃ (lit.) | | 储存温度 | 2-8℃ | | SMILES string | S=C(n1ccnc1)n2ccnc2 | | InChI | 1S/C7H6N4S/c12-7(10-3-1-8-5-10)11-4-2-9-6-11/h1-6H | | InChI key | RAFNCPHFRHZCPS-UHFFFAOYSA-N |
安全信息 | 储存分类代码 | 13 - Non Combustible Solids | | WGK | WGK 3 | | 闪点(F) | Not applicable | | 闪点(C) | Not applicable | | 个人防护装备 | Eyeshields, Gloves, type N95 (US) |
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| 156051 | Sigma-Aldrich | 1,1′-Thiocarbonyldiimidazole | technical grade, 90% | 511.1元/5 G; 971.03元/10 G; | 咨询 |
产品说明 包装 5, 10 g in glass bottle 应用 生化合成中的有用试剂。
本品可用于醇与三丁基氢化锡以及二醇与氢化铝锂发生脱氧反应。 基本信息 | 经验(实验)分子式 | C7H6N4S | | 分子量 | 178.21 | | Beilstein | 609349 | | EC 号 | 228-183-4 | | MDL编号 | MFCD00005289 | | PubChem化学物质编号 | 24849589 | | NACRES | NA.22 |
产品性质 | 等级 | technical grade | | 质量水平 | 100 | | 测定 | 90% | | reaction suitability | reaction type: Carbonylations | | mp | 98-102 ℃ (lit.) | | SMILES string | S=C(n1ccnc1)n2ccnc2 | | InChI | 1S/C7H6N4S/c12-7(10-3-1-8-5-10)11-4-2-9-6-11/h1-6H | | InChI key | RAFNCPHFRHZCPS-UHFFFAOYSA-N |
安全信息 | 储存分类代码 | 13 - Non Combustible Solids | | WGK | WGK 3 | | 闪点(F) | Not applicable | | 闪点(C) | Not applicable | | 个人防护装备 | Eyeshields, Gloves, type N95 (US) |
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| 333755 | Amethyst | 1,1'-Thiocarbonyldiimidazole | 95%, 用于合成 | 52元/1G; 134元/5G; 454元/25G; 1494元/100G; | 咨询 |
基本信息 | 分子式 | C7H6N4S | | 分子量 | 178.21 | | 熔点 | 96-103 | | MDL编码 | MFCD00005289 | | Beilstein | 609349 | | EINECS 编号 | 228-183-4 | | 存储条件 | Store at 2-8℃ Corrosives |
安全信息 | 图形或危害标志 | | | 提示语 | Danger | | 危险说明 | H302
H314 | | 防范说明 | P280
P301+P312
P301+P330+P331
P305+P351+P338
P310 | | WGK | 3 |
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| 035595 | Fluorochem | 1,1-Thiocarbonyldiimidazole | 95% | 396元/5g; 858元/25g; 2244元/100g; 5280元/250g; | 咨询 |
基本信息 | CAS Number | 6160-65-2 | | MDL Number | MFCD00005289 | | Melting Point | 95-103℃ | | Density | 1.3 |
安全信息 | 图形或危害标志 | | | 危险性说明 | H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
| | 防范说明 | P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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