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CAS: 615-79-2
分子式: C7H10O4
分子量: 158.15
沸点: 101-103℃
熔点: 16-18℃
中文名称: 
乙基二唑脂
乙酰丙酮酸酯
乙酰丙酮酸乙酯
英文名称: 
ethyl 2,4-dioxovalerate
2,4-dioxo-pentanoic acid ethyl ester
Ethyl acetonoxalate
Ethyl acetopyruvate
Acetopyruvic acid ethyl ester
性质描述: 无色液体。熔点16-18℃,沸点101-103℃(1.6kPa),相对密度1.126,折光率1.4730(20℃)。溶于醇、醚,不溶于水。
生产方法: 草酸二酯与丙酮缩合(克氏反应)而得。将甲醇钠于40-45℃滴入草酸二乙酯及丙酮中,保温1h,冷却下滴加浓硫酸至pH=3.5。用苯提取反应物,提取液蒸除苯以后进行减压蒸馏。收集130-132℃(4.93kPa)馏分,得产品乙酰丙酮酸乙酯。
用途: 医药磺安甲基异噁唑的中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格
E823357MACKLIN乙酰丙酮酸乙酯97%27元/1g;   30元/5g;   116元/25g;   455元/100g;   咨询
储存:2~8℃
状态:无色到浅黄色液体
R0165TCIEthyl 2,4-Dioxovalerate>98.0%(GC)(T)450元/5G;   1850元/25G;   咨询

基本信息

纯度/分析方法>98.0%(GC)(T)
分子式/分子量C7H10O4 = 158.15
外观与形状(20℃)液体
Reaxys-RN607062
MDL编号MFCD00009124

技术规格

AppearanceColorless to Light orange to Yellow clear liquid
Purity(GC)min. 98.0 %
Purity(Neutralization titration)min. 98.0 %

物性(参考值)

熔点18 ℃
沸点215 ℃
比重1.13
折射率1.47
最大吸收波长284(Diethyl ether) nm
460228J&KEthyl Acetopyruvate98%187元/5G;   630元/25G;   咨询

基本信息

分子式C7H10O4
分子量158.15
熔点16-18
沸点101-103
闪点113
密度1.126
折光率(n20D)1.4740
MDL编码MFCD00009124
Beilstein607062
存储条件Store at 2-8℃

安全信息

防范说明P262
WGK3
A13808Alfa AesarEthyl Acetopyruvate98%645元/5g;   2836元/25g;   8207元/100g;   咨询

应用
Ethyl acetopyruvate is used in the preparation of 5-methyl-isoxazole-3-carboxylic acid ethyl ester. It is involved in the preparation of ethyl 5-amino-2-methylpyndine-4-carboxyIate by reacting with nitroacetamide.

备注
Hygroscopic. Store in a cool place. Incompatible with acids, bases, oxidizing agents and reducing agents.

基本信息

MDL
MFCD00009124

EINECS
210-447-5

分子式
C7H10O4

分子量
158.15

熔点
16-18°

沸点
108-109°/12mm

闪点
>110°(230°F)

密度
1.126

折射率
1.4730

灵敏度
Keep Cold. Store under Nitrogen.

形态
Liquid

溶解性
Miscible with water, ether,chloroform, methanol and ethanol.

Beilstein
607062

安全信息

TSCA

232564Sigma-AldrichEthyl 2,4-Dioxovalerate97%712.06元/25 G;   咨询

产品说明

一般描述

Assymmmetric hydrogenation of ethyl 2,4-dioxovalerate in the presence of chiral rhodium or ruthenium catalysts yields 2-hydroxy-4-methyltetrahydrofuran-2-one. Ethyl 2,4-dioxovalerate is a potential anti-fungal agent.

应用

吡唑合成。

包装

5, 25 g in glass bottle

基本信息

线性分子式CH3COCH2COCOOC2H5
分子量158.15
Beilstein607062
EC 号210-447-5
MDL编号MFCD00009124
PubChem化学物质编号24853912
NACRESNA.22

产品性质

质量水平200
测定97%
折射率n20/D 1.474 (lit.)
bp101-103 ℃/12 mmHg (lit.)
mp16-18 ℃ (lit.)
密度1.126 g/mL at 25 ℃ (lit.)
储存温度2-8℃
SMILES stringCCOC(=O)C(=O)CC(C)=O
InChI1S/C7H10O4/c1-3-11-7(10)6(9)4-5(2)8/h3-4H2,1-2H3
InChI keyOYQVQWIASIXXRT-UHFFFAOYSA-N

安全信息

储存分类代码10 - Combustible liquids
WGKWGK 3
闪点(F)235.4 °F - closed cup
闪点(C)113 ℃ - closed cup
个人防护装备Eyeshields, Gloves
067147FluorochemEthyl 2,4-Dioxopentanoate97%220元/1g;   352元/5g;   660元/10g;   1078元/25g;   咨询

基本信息

CAS Number615-79-2
MDL NumberMFCD00009124
Boiling Point101 - 103
Melting Point16 - 18
Density1.126

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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