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CAS: 6117-80-2
分子式: C4H8O2
分子量: 88.10
沸点: 235℃
熔点: 7-132℃
中文名称: 
顺-2-丁烯-1,4-二醇
顺式-1,2-二羟甲基乙烯
英文名称: 
cis-2-Butene-1,4-diol
cis-but-2-ene-1,4-diol
cis-2-Buten-1,4-diol
(Z)-2-Butene-1,4-diol
1,4-Dihydroxy-cis-2-butene
cis-1,4-Dihydroxy-2-butene
推荐供应商
货号品牌产品名称规格包装、参考价格
B802811MACKLIN顺-2-丁烯-1,4-二醇97%30元/25g;   60元/100g;   210元/500g;   375元/1kg;   1143元/5kg;   咨询
储存:室温
状态:无色到黄色液体
折射率:n20/D 1.479
B0693TCIcis-2-Butene-1,4-diol>94.0%(GC)165元/25G;   535元/500G;   咨询

基本信息

纯度/分析方法>94.0%(GC)
分子式/分子量C4H8O2 = 88.11
外观与形状(20℃)液体
Reaxys-RN1679241
PubChem物质ID87563694
SDBS (AIST Spectral DB)4007
MDL编号MFCD00002924

技术规格

AppearanceColorless to Light yellow clear liquid
Purity(GC)min. 94.0 %

物性(参考值)

熔点7 ℃
沸点235 ℃
闪点128 ℃
比重1.08
折射率1.48
水溶性完全溶解
溶解性(易溶于)乙醇,丙酮
溶解度(极微溶)

安全信息

图形或危害标志
信号词警告
危险性说明H302 : 吞咽有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
A19182Alfa Aesarcis-2-Butene-1,4-diol96%, remainder trans-isomer615元/250g;   1628元/1000g;   咨询

应用
cis-2-Butene-1, 4-diol is used as a probe for studying isomerization versus hydrogenation and hydrogenolysis reactions. (DPCB-OMe) efficiently catalyzes cyclodehydration of cis-2-butene-1,4-diol with active methylene compounds to give 2-vinyl-2,3-dihydrofurans in good to high yields. Grubbs's cross metathesis of eugenol with cis-2-butene-1, 4-diol to make a natural product, an organometallic experiment.

备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

基本信息

MDL
MFCD00002924

EINECS
228-085-1

分子式
C4H8O2

分子量
88.11

熔点
6-8°

沸点
131-132°/12mm

闪点
127°(260°F)

密度
1.070

折射率
1.4780

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Soluble in water.

Beilstein
1679241

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H315-H319-H335
Harmful if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
22-36/37/38
Harmful if swallowed.Irritating to eyes, respiratory system and skin.

安全等级
26-36/37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.

欧盟危险品标志

RTECS
EM4970000

TSCA

C10772Alfa Aesarcis-2-Butene-1,4-diol97%777元/100ml;   2365元/500ml;   12914元/2.5L;   咨询

基本信息

Ref#
10772

MDL
2924

分子式
C4 H8 O2

分子量
88.11

闪点
128

密度
1.07

形态
Liquid

B86206Sigma-Aldrichcis-2-Butene-1,4-diol97%242.02元/25 G;   783.86元/500 G;   咨询

基本信息

经验(实验)分子式C4H8O2
分子量88.11
Beilstein1679241
EC 号228-085-1
MDL编号MFCD00002924
PubChem化学物质编号24892082
NACRESNA.22

产品性质

质量水平100
测定97%
折射率n20/D 1.478 (lit.)
bp235 ℃ (lit.)
mp4-10 ℃ (lit.)
密度1.072 g/mL at 20 ℃ (lit.)
SMILES string[H]\C(CO)=C(/[H])CO
InChI1S/C4H8O2/c5-3-1-2-4-6/h1-2,5-6H,3-4H2/b2-1-
InChI keyORTVZLZNOYNASJ-UPHRSURJSA-N

安全信息

象形图GHS07GHS08
警示用语:Warning
危险声明H302 - H373
预防措施声明P260 - P264 - P270 - P301 + P312 - P314 - P501
危险分类Acute Tox. 4 Oral - STOT RE 2
储存分类代码10 - Combustible liquids
WGKWGK 3
闪点(F)260.6 °F - closed cup
闪点(C)127 ℃ - closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
095819Fluorochemcis-2-Butene-1,4-diol96%308元/50g;   616元/100g;   924元/500g;   咨询

基本信息

CAS Number6117-80-2
MDL NumberMFCD00002924
Density1.072

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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