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CAS: 611-19-8
分子式: C7H6Cl2
分子量: 161.03
沸点: 213-214℃
熔点: -13-94℃
中文名称: 
2-氯苯甲基氯
邻氯氯苄
邻氯苄基氯
α,2-二氯甲苯
英文名称: 
o-chlorobenzylchloride
1-chloro-2-chloromethyl-benzene
1-chloro-2-(chloromethyl)benzene
2-chlorobenzyl chloride
alpha,2-dichlorotoluene
alpha,o-dichlorotoluene
1-chloro-2-(chloromethyl)-benzen
o,alpha-dichlorotoluene
o-chlorobenzyl chloride
alpha,o-dichloro-toluen
α,2-Dichlorotoluene
à,2-Dichlorotoluene
,2-Dichlorotoluene
Benzene,1-chloro-2-(chloromethyl)-
OCBC
展开更多英文名
性质描述: 液体。熔点-17℃,沸点213-214℃(217℃),94-95℃(1.33kPa),相对密度1.2699(0/4℃),折射率1.5895,闪点82℃。
生产方法: 以邻甲苯胺为原料,经重氮化置换,氯化而得。将邻甲苯胺,盐酸,水混合,冷至0-5℃,将亚硝酸钠滴入,进行重氮化反应。在迅速搅拌下,于0℃倒入氯化亚铜,自然升温至20-25℃,最后升至60-65℃,保温20min后冷却,静置、分层、洗涤、蒸馏,得到邻氯甲苯。邻氯甲苯与三氯化磷混合,于130-140℃通氯,得邻氯氯苄。
用途: 有机合成原料,医药工业用于制兴奋药酶抑宁等。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
C822558MACKLIN邻氯氯苄≥99%39元/25g;   72元/100g;   235元/500g;   901元/2.5kg;   展开
储存:2~8℃, 干燥, 惰性气体保存
状态:澄清液体
D0420TCI2-Chlorobenzyl Chloride>99.0%(GC)150元/25G;   450元/500G;   展开

基本信息

纯度/分析方法>99.0%(GC)
分子式/分子量C7H6Cl2 = 161.03
外观与形状(20℃)液体
储存温度0-10℃
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (分解),加热
Reaxys-RN471700
PubChem物质ID87567100
SDBS (AIST Spectral DB)1585
MDL编号MFCD00000893

技术规格

AppearanceColorless to Almost colorless clear liquid
Purity(GC)min. 99.0 %

物性(参考值)

沸点97 ℃/15 mmHg
闪点117 ℃
比重1.28
折射率1.56

安全信息

图形或危害标志
信号词危险
危险性说明H302 + H312 + H332 : 吞咽、皮肤接触或吸入有害。
H316 : 造成轻微皮肤刺激。
H319 : 造成严重眼刺激。
H372 : 长期或反复接触会对器官造成损害。
H335 : 可能造成呼吸道刺激。
H336 : 可能造成昏昏欲睡或眩晕。
H410 : 对水生生物毒性极大并具有长期持续影响。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P273 : 避免释放到环境中。
P260 : 不要吸入粉尘/ 烟/ 气体/ 烟雾/ 蒸气/ 喷雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P391 : 收集溢出物。
P314 : 如感觉不适,须求医/就诊。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P302 + P352 + P312 : 如皮肤沾染:用水充分清洗。如感觉不适,呼叫急救中心/医生。
P304 + P340 + P312 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。如感觉不适,呼叫急救中心/医生。
P403 + P233 : 存放在通风良好的地方。保持容器密闭。
P405 : 存放处须加锁。

相关法规

RTECS#CZ0195000

运输信息

UN编号UN2235
类别6.1
包装类别 III
监管条件代码(*)
A11900Alfa Aesar2-Chlorobenzyl Chloride98+%681元/250g;   1221元/500g;   2927元/2500g;   展开

应用
2-Chlorobenzyl chloride was used as a sensory irritant to evaluate the characteristic modifications of the normal breathing pattern of exposed mice. It is used as an intermediate for organic chemicals, pharmaceuticals, and dyes.

备注
Store away from strong bases and oxidizing agents. Keep away from heat. Incompatible with Alcohols, Amines, Metals.

基本信息

MDL
MFCD00000893

EINECS
210-258-8

分子式
C7H6Cl2

分子量
161.03

熔点
-13°

沸点
213-214°

闪点
109°(228°F)

密度
1.272

折射率
1.5590

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Not miscible in water.

Beilstein
471700

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H312-H331-H314-H318-H400-H410
Harmful if swallowed.Harmful in contact with skin.Toxic if inhaled.Causes severe skin burns and eye damage.Causes serious eye damage.Very toxic to aquatic life.Very toxic to aquatic life with long lasting effects.

Precautionary Statements
P273-P280-P305+P351+P338-P309-P310-P501a
Avoid release to the environment.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF exposed or if you feel unwell:Immediately call a POISON CENTER or doctor/physician.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
III

危险类别
20/21/22-34-50/53
Harmful by inhalation, in contact with skin and if swallowed.Causes burns.Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

安全等级
26-36/37/39-45-60-61
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous wasteAvoid release to the environment. Refer to special instructions/safety data sheets.

欧盟危险品标志

RTECS
CZ0195000

TSCA

C18653Alfa Aesar2-Chlorobenzyl Chloride98+%771元/250ml;   2609元/1L;   展开

基本信息

Ref#
18653

MDL
893

分子式
C7 H6 Cl2

分子量
161.03

闪点
82

密度
1.27

安全信息

危险等级
8

包装组
III

088365Fluorochem1-Chloro-2-chloromethyl-benzene98%418元/250g;   展开

基本信息

CAS Number611-19-8
MDL NumberMFCD00000893
Density1.274

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
H372: Causes damage to organs ..
H410: Very toxic to aquatic life with long lasting effects.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P314: Get medical advice/attention if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P391: Collect spillage.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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