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CAS: 609-67-6
分子式: C7H4ClIO
分子量: 266.47
沸点: 106 °C/0.1kPa
熔点: 28°C (凝固点)
中文名称: 
邻碘苯甲酰氯
2-碘苯甲酰氯
英文名称: 
2-Iodobenzoyl chloride
2-iodo-benzoyl chlorid
o-Iodoebenzoyl chloride
性质描述: 无色针状结晶。熔点35-38℃,沸点159℃(3.6kPa),135℃(2.53kPa),105-106℃(0.133kPa)。溶于乙醇、乙醚和苯。遇水分解。
生产方法: 由邻碘苯甲酸与氯化亚砜反应而得。将邻碘苯甲酸与新蒸馏的氯化亚砜按摩尔比1:1.3混合,在水浴上加热,搅拌反应1h,至不再逸出二氧化硫和氯化氢气体为止。常压下蒸出过量的氯化亚砜,然后减压蒸馏,收集133-135℃(2.53kPa)馏分,即得邻碘苯甲酰氯。收率94%。
用途: 用于有机合成。该品有腐蚀性,有毒。
推荐供应商
货号品牌产品名称规格包装、参考价格
I858229MACKLIN邻碘苯甲酰氯98%26元/1g;   64元/5g;   250元/25g;   898元/100g;   咨询
储存:室温,干燥,惰性气体存储
状态:白色到淡红黄色固体或液体
I0402TCI2-Iodobenzoyl Chloride>97.0%(T)585元/10G;   1095元/25G;   咨询

基本信息

纯度/分析方法>97.0%(T)
分子式/分子量C7H4ClIO = 266.46
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况光,湿气 (分解)
Reaxys-RN2042672
PubChem物质ID87571755
SDBS (AIST Spectral DB)17242
MDL编号MFCD00001040

技术规格

AppearanceWhite to Light yellow to Dark green powder to lump
Purity(GC)min. 95.0 %
Purity(Argentometric Titration)min. 97.0 %

物性(参考值)

熔点28 ℃
沸点106 ℃/1 mmHg
溶解性(可溶于)甲苯

安全信息

图形或危害标志
信号词危险
危险性说明H314 : 造成严重皮肤灼伤和眼损伤。
H290 : 可能腐蚀金属。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P260 : 不要吸入粉尘或烟雾。
P234 : 只能在原容器中存放。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P390 : 吸收溢出物,防止材料损坏。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽:漱口。不要诱导呕吐。
P363 : 沾染的衣服清洗后方可重新使用。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P406 : 贮存于抗腐蚀/带抗腐蚀衬里的容器中。
P405 : 存放处须加锁。

运输信息

UN编号UN3261
类别8
包装类别 III
监管条件代码(*)
277171J&K2-Iodobenzoyl Chloride98%945元/25G;   咨询

基本信息

分子式C7H4ClIO
分子量266.46
熔点27-31
沸点105-106
闪点110
MDL编码MFCD00001040
Beilstein2042672
EINECS 编号210-196-1

安全信息

图形或危害标志
提示语Danger
危险说明H314
防范说明P280
P305+P351+P338
P310
UN号码3261
危险分类8
包装等级II
WGK3
TSCA
A13558Alfa Aesar2-Iodobenzoyl Chloride98%1311元/10g;   5446元/50g;   21793元/250g;   咨询

应用
2-Iodobenzoyl chloride has been used in palladium-catalyzed synthesis of carbomethoxy functional group-induced isoindolin-1-ones, preparation of starting materials required for the synthesis of novel cyclic derivatives of pentavalent iodine, benziodazole oxides.

备注
Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

基本信息

MDL
MFCD00001040

EINECS
210-196-1

分子式
C7H4ClIO

分子量
266.47

熔点
27-32°

沸点
105-106°/1mm

闪点
>110°(230°F)

灵敏度
Moisture Sensitive. Ambient temperatures.

形态
Crystalline solid

溶解性
Reacts with water.

Beilstein
2042672

GHS危害和防范说明

GHS符号

Hazard Statements
H314-H318
Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P280-P305+P351+P338-P309-P310
Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF exposed or if you feel unwell:Immediately call a POISON CENTER or doctor/physician.

安全信息

危险等级
8

包装组
III

危险类别
34
Causes burns.

安全等级
26-36/37/39-45
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

欧盟危险品标志

TSCA

252115Sigma-Aldrich2-Iodobenzoyl Chloride98%748.5元/5 G;   咨询

产品说明

应用

2-Iodobenzoyl chloride has been used in:

  • palladium-catalyzed synthesis of carbomethoxy functional group-induced isoindolin-1-ones
  • preparation of starting materials required for the synthesis of novel cyclic derivatives of pentavalent iodine, benziodazole oxides

包装

5 g in glass bottle

基本信息

线性分子式IC6H4COCl
分子量266.46
Beilstein2042672
EC 号210-196-1
MDL编号MFCD00001040
PubChem化学物质编号24855183
NACRESNA.22

产品性质

测定98%
bp105-106 ℃/1 mmHg (lit.)
mp27-31 ℃ (lit.)
SMILES stringClC(=O)c1ccccc1I
InChI1S/C7H4ClIO/c8-7(10)5-3-1-2-4-6(5)9/h1-4H
InChI keyMVIVDSWUOGNODP-UHFFFAOYSA-N

安全信息

象形图GHS05
警示用语:Danger
危险声明H314
预防措施声明P280 - P305 + P351 + P338 - P310
危险分类Skin Corr. 1B
储存分类代码8B - Non-combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)230.0 °F - closed cup
闪点(C)110 ℃ - closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
044618Fluorochem2-Iodobenzoyl Chloride95+%220元/1g;   748元/10g;   1628元/25g;   5808元/100g;   咨询

基本信息

CAS Number609-67-6
MDL NumberMFCD00001040
Boiling Point105 - 106
Melting Point27 - 31 ℃

安全信息

图形或危害标志
危险性说明 H314: Causes severe skin burns and eye damage.
H318: Causes serious eye damage.
防范说明 P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P280: Wear .
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P363: Wash contaminated clothing before reuse.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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