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CAS: 607-57-8
分子式: C13H9NO2
分子量: 211.22
熔点: 155-158℃
中文名称: 
2-硝基芴
β-硝基芴
英文名称: 
2-nitro-9h-fluoren
2-nitro-9h-fluorene
2-nitrofluorene
2-nitro-fluoren
性质描述: 黄色针状结晶。熔点156℃。
生产方法: 将60g芴和500ml冰乙酸混匀,搅拌加热至50℃,滴加80ml浓硝酸。加热至80℃反应5min,冷至室温,滤出生成的2-硝基芴,用冷的冰乙酸洗涤、水洗,冰乙酸重结晶,得56g纯品,收率79%。
用途: 有机合成中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格
N814532MACKLIN2-硝基芴98%30元/1g;   75元/5g;   339元/25g;   998元/100g;   4699元/500g;   咨询
储存:室温
状态:浅黄色到黄色和浅米黄色到米黄色和浅棕色到棕色粉末
N0201TCI2-Nitrofluorene>99.0%(HPLC)465元/25G;   1400元/100G;   咨询

基本信息

纯度/分析方法>99.0%(HPLC)
分子式/分子量C13H9NO2 = 211.22
外观与形状(20℃)固体
Reaxys-RN1877983
PubChem物质ID87573572
SDBS (AIST Spectral DB)5946
MDL编号MFCD00001117

技术规格

AppearanceWhite to Orange to Green powder to crystal
Purity(HPLC)min. 99.0 area%
Melting point155.0 to 159.0 ℃

物性(参考值)

熔点155 ℃
水溶性不溶
溶解性(可溶于)苯,丙酮

安全信息

图形或危害标志
信号词警告
危险性说明H351 : 怀疑致癌。
H411 : 对水生生物有毒并具有长期持续影响。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P273 : 避免释放到环境中。
P202 : 在阅读并明了所有安全措施前切勿搬动。
P201 : 使用前取得专用说明。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P391 : 收集溢出物。
P308 + P313 : 如接触到或有疑虑:求医/就诊。
P405 : 存放处须加锁。

相关法规

RTECS#LL8225000

运输信息

UN编号UN3077
类别9
包装类别 III
监管条件代码(*)
H55744Alfa Aesar2-Nitrofluorene98%522元/5g;   1707元/25g;   咨询

基本信息

MDL
MFCD00001117

EINECS
210-138-5

分子式
C13H9NO2

分子量
211.22

熔点
156-158°

形态
Powder

GHS危害和防范说明

GHS符号

Hazard Statements
H351-H401-H411
Suspected of causing cancer.Toxic to aquatic life.Toxic to aquatic life with long lasting effects.

Precautionary Statements
P201-P280-P202-P308+P313-P405-P501a
Obtain special instructions before use.Wear protective gloves/protective clothing/eye protection/face protection.Do not handle until all safety precautions have been read and understood.IF exposed or concerned: Get medical advice/attention.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
40-51/53
Limited evidence of a carcinogenic effect.Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

安全等级
36/37-57-60
Wear suitable protective clothing and gloves.Use appropriate container to avoid environmental contamination.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
LL8225000

TSCA

N16754Sigma-Aldrich2-Nitrofluorene98%880.55元/5 G;   咨询

基本信息

经验(实验)分子式C13H9NO2
分子量211.22
EC 号210-138-5
MDL编号MFCD00001117
PubChem化学物质编号24897517
NACRESNA.22

产品性质

质量水平100
测定98%
形式powder
mp156-158 ℃ (lit.)
SMILES string[O-][N+](=O)c1ccc-2c(Cc3ccccc-23)c1
InChI1S/C13H9NO2/c15-14(16)11-5-6-13-10(8-11)7-9-3-1-2-4-12(9)13/h1-6,8H,7H2
InChI keyXFOHWECQTFIEIX-UHFFFAOYSA-N

安全信息

象形图GHS08GHS09
警示用语:Warning
危险声明H351 - H411
预防措施声明P201 - P273 - P308 + P313
危险分类Aquatic Chronic 2 - Carc. 2
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
R-098NAccuStandard2-Nitrofluorene463元/100mg;   咨询
2-Nitrofluorene2-硝基芴607-57-8
079245Fluorochem2-Nitro-9H-fluorene95%220元/1g;   264元/5g;   418元/10g;   792元/25g;   2640元/100g;   咨询

基本信息

CAS Number607-57-8
MDL NumberMFCD00001117
Melting Point155℃

安全信息

图形或危害标志
危险性说明 EUH401: To avoid risks to human health and the environment, comply with the instructions for use.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H351: Suspected of causing cancer ..
H411: Toxic to aquatic life with long lasting effects.
防范说明 P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear .
P281: Use personal protective equipment as required.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313: IF exposed or concerned: Get medical advice/ attention.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P391: Collect spillage.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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