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CAS: 607-01-2
分子式: C14H15P
分子量: 214.24
沸点: 130℃(1 t
中文名称: 
乙基二苯膦
乙基二苯基膦
英文名称: 
Diphenylethylphosphine
ethyldiphenylphosphine
推荐供应商
货号品牌产品名称规格包装、参考价格详情
E809160MACKLIN乙基二苯基膦98%34元/1g;   80元/5g;   362元/25g;   1071元/100g;   展开
储存:室温,干燥
折射率:n20/D 1.614(lit.)
E0519TCIEthyldiphenylphosphine>97.0%(GC)590元/5G;   展开

基本信息

纯度/分析方法>97.0%(GC)
分子式/分子量C14H15P = 214.25
外观与形状(20℃)液体
储存在惰性气体下存放于惰性气体之中
应避免的情况空气
Reaxys-RN744253
PubChem物质ID87569768
MDL编号MFCD00015170

技术规格

AppearanceColorless to Light yellow clear liquid
Purity(GC)min. 97.0 %

物性(参考值)

沸点157 ℃/15 mmHg
比重1.05
折射率1.61

安全信息

图形或危害标志
信号词警告
危险性说明H302 : 吞咽有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。

相关法规

RTECS#SY9242500
15-2150StremEthyldiphenylphosphine99%681元/5g;   2955元/25g;   展开
A18292Alfa AesarEthyldiphenylphosphine98%2218元/10g;   9282元/50g;   展开

基本信息

MDL
MFCD00015170

分子式
CH3CH2P(C6H5)2

分子量
214.25

沸点
130-132°/1mm

密度
1.048

形态
Liquid

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H315-H319-H335
Harmful if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
9

包装组
III

危险类别
22-36/37/38
Harmful if swallowed.Irritating to eyes, respiratory system and skin.

安全等级
26-36/37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.

欧盟危险品标志

TSCA

336904Sigma-AldrichEthyldiphenylphosphine98%454.88元/2 G;   展开

产品说明

应用

Catalyst for:

  • Three component coupling reactions of arylaldehydes with Me vinyl ketone and phthalimide
  • Regio- and stereoselective hydroalkynylation of methylenecyclopropanes
  • Synthesis of oxazolidines, thiazolidines, pyrrolidines, and indoles
  • Dimer to monomer conversion
  • Tandem Morita-Baylis-Hillman/Michael addition reactions
  • Platinum-catalyzed cyclization
  • Regioselective and stereoselective [3+2] cycloaddition
  • Platinum-catalyzed intermolecular hydroamination
  • Hydroformylation reactions

包装

2 g in glass bottle

基本信息

线性分子式(C6H5)2PCH2CH3
分子量214.24
Beilstein744253
MDL编号MFCD00015170
PubChem化学物质编号24860439
NACRESNA.22

产品性质

质量水平100
测定98%
reaction suitabilityreaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
折射率n20/D 1.614 (lit.)
bp293 ℃ (lit.)
密度1.048 g/mL at 25 ℃ (lit.)
官能团phosphine
SMILES stringCCP(c1ccccc1)c2ccccc2
InChI1S/C14H15P/c1-2-15(13-9-5-3-6-10-13)14-11-7-4-8-12-14/h3-12H,2H2,1H3
InChI keyWUOIAOOSKMHJOV-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 - H315 - H319 - H335
预防措施声明P301 + P312 + P330 - P302 + P352 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码10 - Combustible liquids
WGKWGK 3
闪点(F)230.0 °F - closed cup
闪点(C)110 ℃ - closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
240294FluorochemEthyldiphenylphosphine95%220元/1g;   528元/5g;   1650元/25g;   5346元/100g;   展开

基本信息

CAS Number607-01-2
MDL NumberMFCD00015170
Boiling Point157℃
Density1.05

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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