CAS 6002-34-2; 叔丁基二苯基膦; <i>tert</i>-butyldiphenylphosphine

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D828349

MACKLIN

叔丁基二苯基膦

98%

32元/1g; 146元/5g; 711元/25g;

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储存：2~8°C，干燥,惰性气体保护
状态：白色固体晶体

Y24202

Alfa Aesar

tert-Butyldiphenylphosphine

504元/1g; 1531元/5g; 2552元/10g; 5670元/25g;

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基本信息

分子量
242.3

591688

Sigma-Aldrich

tert-Butyldiphenylphosphine

97%

849.31元/1 G; 2582.65元/5 G;

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产品说明

应用

Catalyst for:

Nickel/Lewis acid-catalyzed carbocyanation of alkynes with acetonitrile or substituted acetonitriles
Palladium catalyzed hydrocarboxylation of acetylene with carbon monoxide to acrylic acid under mild conditions
Palladium to form a catalyst for methoxycarbonylation reactions
Ru-catalyzed transfer hydrogenation in reductive coupling of disubstituted allenes with aldehydes
Stereoselective silylation by dehydrogenative Si-O coupling with Si-stereogenic silanes

Phosphine ligand in nickel-catalyzed carbocyanation of alkynes
Monodentate P-Donor Ligands (LKB-P)

包装

1, 5 g in glass bottle

基本信息

线性分子式	(C₆H₅)₂PC(CH₃)₃
分子量	242.30
EC 号	227-848-6
MDL编号	MFCD00015004
PubChem化学物质编号	24881351
NACRES	NA.22

产品性质

质量水平	100
测定	97%
reaction suitability	reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: ligand reaction type: Cross Couplings
bp	144-146 ℃/2 mmHg (lit.)
mp	52-57 ℃ (lit.)
官能团	phosphine
SMILES string	CC(C)(C)P(c1ccccc1)c2ccccc2
InChI	1S/C16H19P/c1-16(2,3)17(14-10-6-4-7-11-14)15-12-8-5-9-13-15/h4-13H,1-3H3
InChI key	QZUPHAGRBBOLTB-UHFFFAOYSA-N

安全信息

储存分类代码	12 - Non Combustible Liquids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

460572

Fluorochem

tert-Butyldiphenylphosphine

97%

1364元/1g; 4114元/5g; 14344元/25g;

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基本信息

CAS Number	6002-34-2
MDL Number	MFCD00015004

安全信息

图形或危害标志
危险性说明	H301: Toxic if swallowed. H315: Causes skin irritation. H317: May cause an allergic skin reaction. H319: Causes serious eye irritation. H335: May cause respiratory irritation. H360: May damage fertility or the unborn child ..
防范说明	P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well-ventilated area. P272: Contaminated work clothing should not be allowed out of the workplace. P280: Wear . P281: Use personal protective equipment as required. P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: . P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313: IF exposed or concerned: Get medical advice/ attention. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see . on this label). P330: Rinse mouth. P332 + P313: If skin irritation occurs: Get medical advice/ attention. P333 + P313: If skin irritation or rash occurs: Get medical advice/attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P363: Wash contaminated clothing before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to local regulations.