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CAS: 593-71-5
分子式: CH2ClI
分子量: 176.38
沸点: 108-109℃
中文名称: 
氯碘甲烷
英文名称: 
chloro-iodo-methane
Methane,chloroiodo-
chloroiodomethane
Methylene chloroiodide
性质描述: 无色液体。沸点107-109℃,相对密度(20/4℃)2.411,折光率1.5822。
生产方法: 将二氯甲烷与碘化钠混合,在室温下搅拌,滴加二甲基甲酰胺。加毕,升温至反应物缓缓回流(约71℃)10h。静置过夜后进行水蒸气蒸馏,从馏出液中分出有机层,用水洗涤,有机层干燥后分馏得到氯碘甲烷。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
C804803MACKLIN氯碘甲烷>97.0%(GC),含稳定剂铜29元/5g;   75元/25g;   275元/100g;   1365元/500g;   展开
储存:2~8°C
状态:无色到红色,紫色,或棕色液体
折射率:n20/D 1.582(lit.)
C1179TCIChloroiodomethane (stabilized with Copper chip)>97.0%(GC)590元/25G;   1490元/100G;   展开

基本信息

纯度/分析方法>97.0%(GC)
分子式/分子量CH2ClI = 176.38
外观与形状(20℃)液体
Reaxys-RN1730802
PubChem物质ID87566206
SDBS (AIST Spectral DB)22650
MDL编号MFCD00001078

技术规格

AppearanceColorless to Light orange to Yellow clear liquid
Purity(GC)min. 97.0 %

物性(参考值)

沸点108 ℃
比重2.44
折射率1.58
水溶性不溶

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H341 : 怀疑可造成遗传性缺陷。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P202 : 在阅读并明了所有安全措施前切勿搬动。
P201 : 使用前取得专用说明。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P308 + P313 : 如接触到或有疑虑:求医/就诊。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P405 : 存放处须加锁。
A11032Alfa AesarChloroiodomethane98%, stab. with copper356元/10g;   1244元/50g;   4671元/250g;   6498元/500g;   展开

应用
Chloroiodomethane is used as an intermediate in pharmaceuticals, organic synthesis, agrochemicals and dyestuff. It is also useful in cyclopropanation (Simmon-Smith reaction), Mannich reaction, aminomethylation and in epoxidation.

备注
It is incompatible with strong oxidizing agents and strong bases.

基本信息

MDL
MFCD00001078

EINECS
209-804-8

分子式
ClCH2I

分子量
176.38

沸点
108-109°

闪点
None

密度
2.416

折射率
1.5822

灵敏度
Light Sensitive. Ambient temperatures.

形态
Liquid

溶解性
Miscible with acetone, benzene, diethyl ether and alcohol.

Beilstein
1730802

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
III

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
23-26-37-60
Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste

TSCA

C22215Alfa AesarChloroiodomethane98%, stabilized2852元/25ml;   10114元/100ml;   56542元/500ml;   展开

基本信息

Ref#
22215

MDL
1078

分子式
C H2 Cl I

分子量
176.38

密度
2.42

安全信息

危险等级
6.1

包装组
III

242861Sigma-AldrichChloroiodomethane97%385.5元/5 G;   851.75元/25 G;   展开

产品说明

一般描述

研究了氯碘甲烷在低温基质中的光解以及新生自由基对的重组 。

包装

5, 25 g in ampule

基本信息

线性分子式ClCH2I
分子量176.38
Beilstein1730802
EC 号209-804-8
MDL编号MFCD00001078
PubChem化学物质编号24854589
NACRESNA.22

产品性质

质量水平100
测定97%
形式liquid
包含 copper as stabilizer
折射率n20/D 1.582 (lit.)
bp108-109 ℃ (lit.)
密度2.422 g/mL at 25 ℃ (lit.)
SMILES stringClCI
InChI1S/CH2ClI/c2-1-3/h1H2
InChI keyPJGJQVRXEUVAFT-UHFFFAOYSA-N

安全信息

象形图GHS06
警示用语:Danger
危险声明H301 - H315 - H319 - H335
预防措施声明P261 - P264 - P270 - P301 + P310 - P302 + P352 - P305 + P351 + P338
危险分类Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type ABEK (EN14387) respirator filter
135417AmethystChloroiodomethane98%, 用于合成, 含稳定剂铜屑42元/5G;   194元/25G;   699元/100G;   2796元/500G;   展开

基本信息

分子式CH2ClI
分子量176.38
沸点108
密度2.422
折光率(n20D)1.582
MDL编码MFCD00001078
Beilstein1730802
EINECS 编号209-804-8

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
UN号码2810
危险分类6.1
包装等级III
WGK3
067664FluorochemChloroiodomethane98%440元/5g;   1386元/25g;   4158元/100g;   15774元/500g;   展开

基本信息

CAS Number593-71-5
MDL NumberMFCD00001078
Density2.422

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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