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CAS: 5913-13-3
分子式: C8H17N
分子量: 127.23
沸点: 177℃
中文名称: 
(R)-(-)-1-环己基乙胺
英文名称: 
(R)-(-)-1-cyclohexylethylamine
(R)-(-)-α-Methylcyclohexanemethylamine
(R)-(-)-à-Methylcyclohexanemethylamine
推荐供应商
货号品牌产品名称规格包装、参考价格详情
R865096MACKLIN(R)-(-)-1-环己乙胺≥98%43元/250mg;   117元/1g;   358元/5g;   1229元/25g;   4628元/100g;  
储存:室温,干燥
状态:无色到几乎无色澄清液体
C1541TCI(R)-(-)-1-Cyclohexylethylamine>98.0%(GC)(T)610元/5G;   1660元/25G;  

基本信息

纯度/分析方法>98.0%(GC)(T)
分子式/分子量C8H17N = 127.23
外观与形状(20℃)液体
储存在惰性气体下存放于惰性气体之中
应避免的情况空气,湿气 (吸湿)
Reaxys-RN2935069
PubChem物质ID87566538
MDL编号MFCD00043338

技术规格

AppearanceColorless to Almost colorless clear liquid
Purity(GC)min. 98.0 %
Optical purity(GC,Mosher)min. 93.0 ee%
Purity(Nonaqueous Titration)min. 98.0 %

物性(参考值)

沸点60 ℃/12 mmHg
闪点51 ℃
比重0.87
比旋光度 [α]D-3.3° (neat)
折射率1.46

安全信息

图形或危害标志
信号词危险
危险性说明H314 : 造成严重皮肤灼伤和眼损伤。
H226 : 易燃液体和蒸气。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P240 : 容器和装载设备接地/等势联接。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P233 : 保持容器密闭。
P243 : 采取防止静电放电的措施。
P241 : 使用防爆的电气/通风/照明设备。
P242 : 只能使用不产生火花的工具。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽:漱口。不要诱导呕吐。
P363 : 沾染的衣服清洗后方可重新使用。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P403 + P235 : 存放在通风良好的地方。保持低温。
P405 : 存放处须加锁。

运输信息

UN编号UN2734
类别8 / 3
包装类别 II
监管条件代码(*)
L19051Alfa Aesar(R)-(-)-1-CyclohexylethylamineChiPros庐, 98%, ee 94+%379元/1g;   939元/5g;   3943元/25g;  

应用
(R)-(-)-1-Cyclohexylethylamine is used in the preparation of benzylidene(1-cyclohexylethyl)amine by reacting with benzaldehyde. It is also used to prepare chiral polymethacrylamides, which are employed as stationary phases for the liquid-chromatographic resolution of racemic amides. In addition to this, it is used in the preparation of polyamides bound to silica gel for high performance liquid chromatography, which are pressure-stable.

备注
Hygroscopic. Air sensitive. Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00043338

EINECS
227-634-2

分子式
C8H17N

分子量
127.23

沸点
177-178°

闪点
51°(123°F)

密度
0.866

折射率
1.4620

灵敏度
Air Sensitive. Store under Nitrogen. Ambient temperatures.

形态
Liquid

溶解性
Miscible with acetone, chloroform,dimethyl sulfoxide, ethanol, methanol, ether, petroleum ether and dichloromethane. Insoluble in water.

Beilstein
2935070

GHS危害和防范说明

GHS符号

Hazard Statements
H226-H314-H318
Flammable liquid and vapour.Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P280-P303+P361+P353-P305+P351+P338-P310
Wear protective gloves/protective clothing/eye protection/face protection.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Immediately call a POISON CENTER or doctor/physician.

安全信息

UN#
UN2733

危险等级
3

包装组
III

危险类别
10-34
Flammable.Causes burns.

安全等级
26-36/37/39-45
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

欧盟危险品标志

TSCA

448437Fluorochem(R)-1-Cyclohexylethanamine95%1012元/5g;   3366元/25g;  

基本信息

CAS Number5913-13-3
MDL NumberMFCD00043338
Density0.87

安全信息

图形或危害标志
危险性说明 H226: Flammable liquid and vapour.
H314: Causes severe skin burns and eye damage.
防范说明 P210: Keep away from – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof ./ equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P280: Wear .
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P363: Wash contaminated clothing before reuse.
P370 + P378: In case of fire: Use sand, CO2 or extinguishing powder for extinction.
P403 + P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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