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CAS: 590-90-9
分子式: C4H8O2
分子量: 88.11
沸点: 73℃(12 t
中文名称: 
丁酮醇
乙酰乙醇
4-羟基-2-丁酮
英文名称: 
4-hydroxy-2-Butanone
4-Hydroxy-2-butanone
4-hydroxy-2-butanon
2-Hydroxyethyl methyl ketone
2-Butanone,4-hydroxy-
3-Oxobutanol
Acetonylcarbinol
性质描述: 该品存在于烟草的烟中,沸点109-110℃(4.0kPa),90℃(1.47kPa)。与水、乙醇、乙醚混溶。
生产方法: 由丙酮和甲醛反应而得。将甲醛溶液与丙酮按1:30(重量)混合,送入管道反应器,温度51-53℃,停留时间3-4min。在维生素A的中间体甲基乙烯酮的生产中,生成的4-羟基-2-丁酮反应液直接用于下道工序,用草酸脱水得至甲基乙烯酮。
用途: 医药中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
H810991MACKLIN4-羟基-2-丁酮95%40元/25g;   98元/100g;   485元/500g;   1848元/2.5kg;   6480元/10kg;   展开
储存:室温
状态:无色到黄色液体
折射率:1.430
H0584TCI4-Hydroxy-2-butanone>95.0%(GC)255元/25ML;   750元/100ML;   2090元/500ML;   展开

基本信息

纯度/分析方法>95.0%(GC)
分子式/分子量C4H8O2 = 88.11
外观与形状(20℃)液体
储存在惰性气体下存放于惰性气体之中
应避免的情况空气
Reaxys-RN1737666
PubChem物质ID87570968
SDBS (AIST Spectral DB)15443
MDL编号MFCD00059005

技术规格

AppearanceColorless to Almost colorless clear liquid
Purity(GC)min. 95.0 %

物性(参考值)

沸点170 ℃
闪点89 ℃
比重1.02
折射率1.43
水溶性完全混溶
溶解性(可与之混溶)乙醇,丙酮,乙醚

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H227 : 可燃液体。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P403 + P235 : 存放在通风良好的地方。保持低温。
613715J&K4-Hydroxy-2-butanone95%233元/25G;   671元/100G;   2060元/500G;   展开

基本信息

分子式C4H8O2
分子量88.11
沸点73-76
闪点33
密度1.023
折光率(n20D)1.4300
MDL编码MFCD00059005
Beilstein1737666
EINECS 编号209-693-6

安全信息

图形或危害标志
提示语Warning
危险说明H226
防范说明P262
UN号码1993
危险分类3
包装等级III
WGK3
L11456Alfa Aesar4-Hydroxy-2-butanone95%602元/25g;   1694元/100g;   展开

应用
4-Hydroxy-2-butanone is used in the preparation of fused benzazepine molecules as selective D3 receptor antagonists with pharmaceutical activity. It is also used in the preparation of verrucarin and mevalonic acid lactone. Further, it is used to prepare 3-buten-2-one through dehydration over an anatase titanium dioxide catalyst. It is also employed in the preparation of 4-methyl-5-hydroxymethylthiazole, (?±)-lineatin and beta-hydroxylactones.

备注
Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00059005

EINECS
209-693-6

分子式
C4H8O2

分子量
88.11

沸点
73-76°/12mm

闪点
89°(192°F)

密度
1.020

折射率
1.4310

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Miscible with water, alcohol, ethanol and ether.

Beilstein
1737666

GHS危害和防范说明

GHS符号

Hazard Statements
H227-H315-H319-H335
Combustible liquid.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P210e-P261-P280a-P305+P351+P338-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
23-26-37-60
Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste

TSCA

358442Fluorochem4-Hydroxybutan-2-one>95.0%(GC)264元/10g;   638元/25ml;   2200元/100ml;   5632元/500ml;   展开

基本信息

CAS Number590-90-9
MDL NumberMFCD00059005
Boiling Point73-76℃/12mmHg
Density1.023

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H227: Combustible liquid
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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