[登录] [免费注册]
试剂仪器网
位置:首页 > 资料中心 > 化工字典 > 589-92-4
关键词:       仅模糊查询
CAS: 589-92-4
分子式: C7H12O
分子量: 112.17
沸点: 169-171℃
熔点: -41 °C
中文名称: 
4-甲基环已酮
4-甲基环己酮
对甲基环己酮
英文名称: 
Tetrahydro-p-cresol
p-Methylcyclohexanone
4-methylcyclohexanone
4-methyl-cyclohexanon
methyl-4 cyclohexanone-1
4-methyl-cyclohexanone
4-Methyl cyclohexanone
性质描述: 无色液体,有丙酮味。熔点-40.6℃,沸点170℃,相对密度 20/4℃ 0.914,折光率1.4451,75℃时遇硝酸可爆炸。闪点48℃。溶于醇、醚,不溶于水。
生产方法: 由甲基环己醇氧化制得。
用途: 甲环亚硝脲的中间体。亦可用作溶剂。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
M813263MACKLIN4-甲基环己酮98%31元/5ml;   82元/25ml;   214元/100ml;   945元/500ml;   展开
储存:室温,易燃物区域
状态:无色到浅黄色液体
折射率:n20/D 1.4443(lit.)
M0199TCI4-Methylcyclohexanone>98.0%(GC)220元/25ML;   650元/100ML;   2475元/500ML;   展开

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C7H12O = 112.17
外观与形状(20℃)液体
Reaxys-RN506746
PubChem物质ID87572290
SDBS (AIST Spectral DB)5761
MDL编号MFCD00001643

技术规格

AppearanceColorless to Almost colorless clear liquid
Purity(GC)min. 98.0 %

物性(参考值)

沸点171 ℃
闪点48 ℃
比重0.92
折射率1.45
水溶性不溶
溶解性(可溶于)醇,乙醚

安全信息

图形或危害标志
信号词警告
危险性说明H302 : 吞咽有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H335 : 可能造成呼吸道刺激。
H336 : 可能造成昏昏欲睡或眩晕。
H305 : 吞咽及进入呼吸道可能有害。
H226 : 易燃液体和蒸气。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P240 : 容器和装载设备接地/等势联接。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P233 : 保持容器密闭。
P243 : 采取防止静电放电的措施。
P241 : 使用防爆的电气/通风/照明设备。
P242 : 只能使用不产生火花的工具。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P331 : 不得诱导呕吐。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P310 : 如误吞咽:立即呼叫急救中心/医生。
P304 + P340 + P312 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。如感觉不适,呼叫急救中心/医生。
P403 + P233 : 存放在通风良好的地方。保持容器密闭。
P403 + P235 : 存放在通风良好的地方。保持低温。
P405 : 存放处须加锁。

相关法规

RTECS#GW1750200

运输信息

UN编号UN2297
类别3
包装类别 III
监管条件代码(*)
119249J&K4-Methylcyclohexanone98%187元/25G;   606元/100G;   展开

基本信息

分子式C7H12O
分子量112.17
沸点169-171
闪点48
密度0.914
折光率(n20D)1.4443
MDL编码MFCD00001643
Beilstein506746
EINECS 编号209-665-3

安全信息

图形或危害标志
提示语Warning
危险说明H226
H302
防范说明P211
P281
UN号码2297
危险分类3
包装等级III
WGK3
RTECSGW1750200
A13186Alfa Aesar4-Methylcyclohexanone98+%321元/25g;   1101元/100g;   4658元/500g;   展开

应用
4-Methylcyclohexanone was used in the synthesis of the pinguisane-type sesquiterpenoid acutifolone A, in racemic form. It is used as intermediates of CCNU and it can be also be used as a solvent.

备注
Stable under recommended storage conditions. Incompatible with oxidizing agents.

基本信息

MDL
MFCD00001643

EINECS
209-665-3

分子式
C7H12O

分子量
112.17

熔点
-41°

沸点
169-171°

闪点
48°(118°F)

密度
0.914

折射率
1.4450

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Not miscible in water.

Beilstein
506746

GHS危害和防范说明

GHS符号

Hazard Statements
H226-H302
Flammable liquid and vapour.Harmful if swallowed.

Precautionary Statements
P210-P280a-P240-P241-P303+P361+P353-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Wear protective gloves and eye/face protection.Ground/bond container and receiving equipment.Use explosion-proof electrical/ventilating/lighting/ equipment.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
3

包装组
III

危险类别
10-22
Flammable.Harmful if swallowed.

安全等级
23-36-60
Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).Wear suitable protective clothing.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
GW1750200

TSCA

C17426Alfa Aesar4-Methylcyclohexanone98%463元/25g;   1095元/100g;   展开

基本信息

Ref#
17426

MDL
1643

分子式
C7 H12 O

分子量
112.17

闪点
40

密度
0.914

形态
Colorless liquid

安全信息

危险等级
3

包装组
III

W394807Sigma-Aldrich4-Methylcyclohexanone≥99%398.74元/;   533.85元/100 G;   2090.73元/1 KG;   6894.38元/4 KG;   展开

产品说明

一般描述

4-Methylcyclohexanone is a cyclic flavor ketone that is reported to be present in volatile oil of roasted sesame seeds.

包装

4 kg in steel drum
100 g in glass bottle
1 kg in glass bottle

基本信息

线性分子式CH3C6H9(=O)
分子量112.17
FEMA编号3948
Beilstein506746
EC 号209-665-3
MDL编号MFCD00001643
PubChem化学物质编号24901949
NACRESNA.21

产品性质

质量水平400
生物来源synthetic
reg. complianceFDA 21 CFR 117
测定≥99%
折射率n20/D 1.4443 (lit.)
bp169-171 ℃ (lit.)
密度0.914 g/mL at 25 ℃ (lit.)
文件see Safety & Documentation for available documents
性状检查musty; animal
application(s)flavors and fragrances
食品过敏原no known allergens
SMILES stringCC1CCC(=O)CC1
InChI1S/C7H12O/c1-6-2-4-7(8)5-3-6/h6H,2-5H2,1H3
InChI keyVGVHNLRUAMRIEW-UHFFFAOYSA-N

安全信息

象形图GHS02GHS07
警示用语:Warning
危险声明H226 - H302
预防措施声明P210 - P301 + P312 + P330
危险分类Acute Tox. 4 Oral - Flam. Liq. 3
储存分类代码3 - Flammable liquids
WGKWGK 1
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
173614Sigma-Aldrich4-Methylcyclohexanone99%425.29元/25 ML;   925.81元/100 ML;   3486.05元/500 ML;   展开

产品说明

应用

4-甲基环己酮用于合成外消旋形式的苯甲硅烷型倍半萜烯 acutifolone A。

包装

25, 100, 500 mL in glass bottle

基本信息

线性分子式CH3C6H9(=O)
分子量112.17
Beilstein506746
EC 号209-665-3
MDL编号MFCD00001643
PubChem化学物质编号24850461
NACRESNA.22

产品性质

质量水平100
测定99%
形式liquid
折射率n20/D 1.4443 (lit.)
bp169-171 ℃ (lit.)
密度0.914 g/mL at 25 ℃ (lit.)
SMILES stringCC1CCC(=O)CC1
InChI1S/C7H12O/c1-6-2-4-7(8)5-3-6/h6H,2-5H2,1H3
InChI keyVGVHNLRUAMRIEW-UHFFFAOYSA-N

安全信息

象形图GHS02GHS07
警示用语:Warning
危险声明H226 - H302
预防措施声明P210 - P301 + P312 + P330
危险分类Acute Tox. 4 Oral - Flam. Liq. 3
储存分类代码3 - Flammable liquids
WGKWGK 1
闪点(F)118.4 °F - closed cup
闪点(C)48 ℃ - closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
8.20788Sigma-Aldrich4-Methylcyclohexanonefor synthesis351.49元/100 ML;   展开

产品说明

分析说明

Assay (GC, area%): ≥ 98.0 % (a/a)
Density (d 20 °C/ 4 °C): 0.915 - 0.917
Identity (IR): passes test

基本信息

线性分子式4-(CH3)C6H9(=O)
分子量112.17
MDL编号MFCD00001643
EC索引号209-665-3

产品性质

质量水平200
蒸汽压20 hPa ( 65 ℃)
测定≥98.0% (GC)
效能800 mg/kg LD50, oral (Rat)
bp169-171 ℃/1013 hPa
mp-41 ℃
转变温度flash point 48 ℃
密度0.92 g/cm3 at 20 ℃
储存温度2-30℃
InChI1S/C7H12O/c1-6-2-4-7(8)5-3-6/h6H,2-5H2,1H3
InChI keyVGVHNLRUAMRIEW-UHFFFAOYSA-N

安全信息

象形图GHS02GHS07
警示用语:Warning
危险声明H226 - H302
预防措施声明P210 - P233 - P240 - P241 - P242 - P301 + P312
危险分类Acute Tox. 4 Oral - Flam. Liq. 3
储存分类代码3 - Flammable liquids
WGKWGK 1
闪点(F)118.4 °F - closed cup
闪点(C)48 ℃ - closed cup
241022Fluorochem4-Methylcyclohexanone95%286元/25g;   946元/100g;   4554元/500ml;   展开

基本信息

CAS Number589-92-4
MDL NumberMFCD00001643
Boiling Point171℃
Density0.92

安全信息

图形或危害标志
危险性说明 H226: Flammable liquid and vapour.
H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P210: Keep away from – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof ./ equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P370 + P378: In case of fire: Use CO2 for extinction.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P403 + P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
CAS号首数字顺序排列: 1 2 3 4 5 6 7 8 9