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CAS: 583-39-1
分子式: C7H6N2S
分子量: 150.20
熔点: 300-304 °C(lit.)
中文名称: 
苯并二氮唑-2-硫酚
邻苯搅硫脲
麻疯宁
巯苯咪唑
1,3-二氢-2H-苯并咪唑-2-硫酮
防老剂MB
2-硫醇基苯并咪唑
2-巯基苯并咪唑
橡胶防老剂MB
英文名称: 
1,3-dihydro-2H-Benzimidazole-2-thione
Antioxidant MB
2-Mercaptobenzimidazole
2-benzimidazolethiol
2-benzimidazolinthion
2-mercaptobenzoimidazole
2-merkaptobenzimidazol
1,3-dihydro-2h-benzimidazole-2-thion
2H-Benzimidazole-2-thione,1,3-dihydro-
antiegene mb
1,3-Dihydro-2H-benzimi-dazole-2-thione
aomb
asm mb
mercaptobenzoimidazole
merkaptobenzimidazol
nci-c60980
o-phenylenethiourea
usaf ek-6540
usaf xf-21
Benzimidazole-2-thiol
展开更多英文名
性质描述: 白色片状结晶。熔点303-304℃(298℃),相对密度1.42。溶于乙醇、丙酮、乙酸乙酯,难溶于二氯甲烷、氯仿、苯、乙醚和汽油,不溶于水。有苦味。
生产方法: 由邻苯二胺与二硫化碳进行成环反应而得。在实际工业生产中,邻苯二胺(见C6H8N2,[95-54-5])是由邻硝基氯苯和浓氨水经加压氨化生成邻硝基苯胺,再硫化钠溶注保还原得到的,还原反应得到的邻苯二胺混合物可直接用于防老剂MB的生产。原料消耗(kg/t)硝基氯苯 1520二硫化碳(95%) 920
用途: 该品用作天然橡胶、二烯类合成橡胶及胶乳的抗氧剂,亦可用于聚乙烯。它是一种所谓的二次防老剂,与其他防老剂(如DNP、AP及其他非污染性防老剂)并用,可获得明显的协同效果。该品在橡胶中易分散,在日光下不变色。略有污染性。单独使用时用量和般为1-1.5份,当用量超过2份时,会产生喷霜现象。在乳胶泡沫橡胶中的用量为0.5-1份,在透明橡胶制品中的用量为0.5份。因本品有苦味,不宜用于与食品接触的橡胶制品中。2-巯基苯并咪唑在医药上是一种新抗麻疯药,毒性比砜类药物低,而疗效也底,可产生耐药性,无蓄积作用。可用于不适用砜类药物的患者。2-巯基并咪唑碱金属盐水溶液与水溶性锌盐溶液反应可得2-巯基苯并咪唑锌盐,即防老剂MBZ(C14H10N4S2Zn)。该品无毒。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
M813614MACKLIN2-巯基苯并咪唑98%30元/25g;   50元/100g;   120元/500g;   455元/2.5kg;   1500元/10kg;   展开
储存:室温
状态:白色到灰白色粉末
B0055TCI2-Mercaptobenzimidazole>98.0%(T)(HPLC)135元/25G;   645元/500G;   展开

基本信息

纯度/分析方法>98.0%(T)(HPLC)
分子式/分子量C7H6N2S = 150.20
外观与形状(20℃)固体
Reaxys-RN119867
PubChem物质ID87563259
SDBS (AIST Spectral DB)1728
Merck Index (14)1082
MDL编号MFCD00466107

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(HPLC)min. 98.0 area%
Purity(Neutralization titration)min. 98.0 %

物性(参考值)

熔点304 ℃
沸点451 ℃
最大吸收波长306(EtOH) nm
水溶性实际上不溶
溶解性(可溶于)乙醇,甲醇
溶解性(微溶于)丙酮
溶解度(极微溶)苯,氯仿,甲苯

安全信息

图形或危害标志
信号词危险
危险性说明H301 : 吞咽会中毒。
H316 : 造成轻微皮肤刺激。
H320 : 造成眼刺激。
H373 : 长期或反复接触可能损害器官。
H317 : 可能造成皮肤过敏反应。
H412 : 对水生生物有害并具有长期持续影响。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P273 : 避免释放到环境中。
P272 : 受沾染的工作服不得带出工作场地。
P260 : 不要吸入粉尘/ 烟/ 气体/ 烟雾/ 蒸气/ 喷雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P314 : 如感觉不适,须求医/就诊。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P333 + P313 : 如发生皮肤刺激或皮疹:求医/就诊。
P301 + P310 + P330 : 如误吞咽:立即呼叫急救中心/医生。漱口。
P405 : 存放处须加锁。

相关法规

RTECS#DE1050000

运输信息

UN编号UN2811
类别6.1
包装类别 III
监管条件代码(*)
609479J&K2-Mercaptobenzimidazole98%72元/25G;   234元/100G;   565元/500G;   1026元/1KG;   展开

基本信息

分子式C7H6N2S
分子量150.20
熔点300-305
闪点>250
MDL编码MFCD00466107
Beilstein119867
EINECS 编号209-502-6

安全信息

图形或危害标志
提示语Danger
危险说明H301
H312
H315
H319
H332
H335
防范说明P261
P280
P301+P310
P305+P351+P338
UN号码2811
危险分类6.1
包装等级III
WGK2
RTECSDE1050000
TSCA
A18350Alfa Aesar2-Mercaptobenzimidazole97%407元/100g;   867元/250g;   1474元/500g;   6239元/2500g;   展开

应用
2-Mercaptobenzimidazole is used as an antidegradant. It is utilized for protecting rubber from oxidation. It is also employed as an intermediate in the preparation of rabeprazole. Further, it finds application in anti-leprosy drugs in medicine. In addition to this, it is used as a copper plating brightener.

备注
Moisture sensitive. Incompatible with strong oxidizing agents and strong bases.

基本信息

MDL
MFCD00466107

EINECS
209-502-6

分子式
C7H6N2S

分子量
150.20

熔点
305-310°

闪点
>250°(487°F)

密度
1.42

灵敏度
Ambient temperatures.

形态
Powder

溶解性
Slightly soluble in water.

Beilstein
119867

Merck
14,1082

GHS危害和防范说明

GHS符号

Hazard Statements
H301
Toxic if swallowed.

Precautionary Statements
P264-P270-P301+P310a-P321-P405-P501a
Wash thoroughly after handling.Do not eat, drink or smoke when using this product.Do not eat, drink or smoke when using this product.Specific treatment (see label).Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
III

危险类别
22
Harmful if swallowed.

安全等级
36-60
Wear suitable protective clothing.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
DE1050000

TSCA

1598042USPRabeprazole Related Compound CUnited States Pharmacopeia (USP) Reference Standard11011.4元/25 MG;   展开

产品说明

一般描述

This product is provided as delivered and specified by the issuing Pharmacopoeia. All information provided in support of this product, including SDS and any product information leaflets have been developed and issued under the Authority of the issuing Pharmacopoeia.
For further information and support please go to the website of the issuing Pharmacopoeia.

分析说明

These products are for test and assay use only. They are not meant for administration to humans or animals and cannot be used to diagnose, treat, or cure diseases of any kind.  ​

其他说明

USP issued SDS can be found here.
Sales restrictions may apply.

基本信息

经验(实验)分子式C7H6N2S
分子量150.20
Beilstein119867
MDL编号MFCD00466107
PubChem化学物质编号329751017
NACRESNA.24

产品性质

等级pharmaceutical primary standard
manufacturer/tradenameUSP
mp300-304 ℃ (lit.)
application(s)pharmaceutical (small molecule)
格式neat
储存温度2-8℃
SMILES stringS=C1Nc2ccccc2N1
InChI1S/C7H6N2S/c10-7-8-5-3-1-2-4-6(5)9-7/h1-4H,(H2,8,9,10)
InChI keyYHMYGUUIMTVXNW-UHFFFAOYSA-N

安全信息

象形图GHS06GHS08
警示用语:Danger
危险声明H301 - H317 - H373 - H412
预防措施声明P260 - P273 - P280 - P301 + P310 - P302 + P352 - P314
危险分类Acute Tox. 3 Oral - Aquatic Chronic 3 - Skin Sens. 1A - STOT RE 2
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 2
闪点(F)752.0 °F - closed cup
闪点(C)> 400 ℃ - closed cup
M3205Sigma-Aldrich2-Mercaptobenzimidazole98%244.23元/5 G;   426.44元/100 G;   894.21元/500 G;   展开

产品说明

一般描述

2-巯基苯并咪唑能降低金属腐蚀速度,是良好的缓蚀剂。

应用

2-巯基苯并咪唑用于:

  • 与芳香酮反应制备2-苯并咪唑基硫代苯乙酮,这是合成噻唑并[3,2-a]苯并咪唑的关键中间体。
  • 合成 S-芳基化2-巯基苯并咪唑,合成物由与CuI和1,10-菲咯啉形成的取代芳基碘化物进行 S-芳基化反应得到。

包装

5 g in glass bottle
100, 500 g in poly bottle

基本信息

经验(实验)分子式C7H6N2S
分子量150.20
Beilstein119867
EC 号209-502-6
MDL编号MFCD00466107
PubChem化学物质编号24896821
NACRESNA.22

产品性质

质量水平200
测定98%
mp300-304 ℃ (lit.)
SMILES stringS=C1Nc2ccccc2N1
InChI1S/C7H6N2S/c10-7-8-5-3-1-2-4-6(5)9-7/h1-4H,(H2,8,9,10)
InChI keyYHMYGUUIMTVXNW-UHFFFAOYSA-N

安全信息

象形图GHS06GHS08
警示用语:Danger
危险声明H301 - H317 - H373 - H412
预防措施声明P260 - P273 - P280 - P301 + P310 - P302 + P352 - P314
危险分类Acute Tox. 3 Oral - Aquatic Chronic 3 - Skin Sens. 1A - STOT RE 2
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 2
个人防护装备dust mask type N95 (US), Eyeshields, Faceshields, Gloves
PHR3123SupelcoRabeprazole Related Compound Cpharmaceutical secondary standard, certified reference material6205.72元/50 mg;   展开

产品说明

一般描述

Pharmaceutical secondary standards for application in quality control provide pharma laboratories and manufacturers with a convenient and cost-effective alternative to the preparation of in-house working standards

分析说明

These secondary standards offer multi-traceability to the USP, EP and BP primary standards, where they are available.

其他说明

This Certified Reference Material (CRM) is produced and certified in accordance with ISO 17034 and ISO/IEC 17025. All information regarding the use of this CRM can be found on the certificate of analysis.

附注

To see an example of a Certificate of Analysis for this material enter LRAA6959(changes by product) in the Documents slot below. This is an example certificate only and may not be the lot that you receive.

基本信息

经验(实验)分子式C7H6N2S
分子量150.20
Beilstein119867
MDL编号MFCD00466107

产品性质

等级certified reference material
pharmaceutical secondary standard
CofAcurrent certificate can be downloaded
包装pkg of 50 mg
mp300-304 ℃ (lit.)
application(s)pharmaceutical
药典可追溯性traceable to USP 1598042
储存温度2-8℃
SMILES stringS=C1Nc2ccccc2N1
InChI1S/C7H6N2S/c10-7-8-5-3-1-2-4-6(5)9-7/h1-4H,(H2,8,9,10)
InChI keyYHMYGUUIMTVXNW-UHFFFAOYSA-N

安全信息

象形图GHS06GHS08
警示用语:Danger
危险声明H301 - H317 - H373 - H412
预防措施声明P260 - P273 - P280 - P301 + P310 - P302 + P352 - P314
危险分类Acute Tox. 3 Oral - Aquatic Chronic 3 - Skin Sens. 1A - STOT RE 2
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 2
闪点(F)Not applicable
闪点(C)Not applicable
51810Supelco2-Mercaptobenzimidazoleanalytical standard903.9元/50 MG;   展开

产品说明

应用

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

基本信息

经验(实验)分子式C7H6N2S
分子量150.20
Beilstein119867
EC 号209-502-6
MDL编号MFCD00466107
PubChem化学物质编号329757747
NACRESNA.24

产品性质

质量水平100
等级analytical standard
测定≥98.5% (HPLC)
保质期limited shelf life, expiry date on the label
technique(s)HPLC: suitable
gas chromatography (GC): suitable
mp300-304 ℃ (lit.)
application(s)forensics and toxicology
veterinary
格式neat
储存温度2-8℃
SMILES stringS=C1Nc2ccccc2N1
InChI1S/C7H6N2S/c10-7-8-5-3-1-2-4-6(5)9-7/h1-4H,(H2,8,9,10)
InChI keyYHMYGUUIMTVXNW-UHFFFAOYSA-N

安全信息

象形图GHS06GHS08
警示用语:Danger
危险声明H301 - H317 - H373 - H412
预防措施声明P260 - P273 - P280 - P301 + P310 - P302 + P352 - P314
危险分类Acute Tox. 3 Oral - Aquatic Chronic 3 - Skin Sens. 1A - STOT RE 2
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 2
闪点(F)752.0 °F - closed cup
闪点(C)> 400 ℃ - closed cup
068818Fluorochem2-Mercaptobenzimidazole97%220元/25g;   330元/100g;   展开

基本信息

CAS Number583-39-1
MDL NumberMFCD00005593
Melting Point301-305℃

安全信息

图形或危害标志
危险性说明 H301: Toxic if swallowed.
H312: Harmful in contact with skin.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P322: Specific measures (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P363: Wash contaminated clothing before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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