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CAS: 578-58-5
分子式: C8H10O
分子量: 122.16
沸点: 170-172℃
中文名称: 
邻甲氧基甲苯
邻甲基苯甲醚
2-甲基苯甲醚
英文名称: 
o-Cresyl methyl ether
2-Methoxytoluene
o-Cresol Methyl Ether
2-Methylanisol
o-Methoxytoluene
1-Methoxy-2-methylbenzene
1-methoxy-2-methyl-benzene
Benzene,1-methoxy-2-methyl-
1-methoxy-2-methyl-benzen
2-methylanisole
性质描述: 无色液体。沸点为170-172℃,相对密度0.985,折光率1.5161,闪点51℃。溶于醇和醚,不溶于水。
生产方法: 由邻甲酚钠与硫酸二甲酯反应制得。将氢氧化钠配成20%的溶液,与邻甲酚搅拌混合,冷却至10℃以下,慢慢滴加硫酸二甲酯。加毕,升温至40℃保持20min,再与100℃反应12h。然后将反应物水洗至中性,除去水分,蒸馏,收集171℃馏分即得成品。
用途: 可作农药除草剂等产品合成时的中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
M824082MACKLIN2-甲基苯甲醚99%26元/5g;   30元/25g;   53元/100g;   236元/500g;   1100元/2.5kg;   展开
储存:2~8℃,干燥,密封
状态:澄清无色到淡黄色液体
折射率:n20/D 1.516(lit.)
M0150TCI2-Methoxytoluene>98.0%(GC)290元/25ML;   790元/100ML;   2190元/500ML;   展开

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C8H10O = 122.17
外观与形状(20℃)液体
Reaxys-RN1857415
PubChem物质ID87572250
SDBS (AIST Spectral DB)1798
MDL编号MFCD00008373

技术规格

AppearanceColorless to Almost colorless clear liquid
Purity(GC)min. 98.0 %

物性(参考值)

沸点171 ℃
闪点52 ℃
比重0.98
折射率1.52

安全信息

图形或危害标志
信号词警告
危险性说明H226 : 易燃液体和蒸气。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P240 : 容器和装载设备接地/等势联接。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P233 : 保持容器密闭。
P243 : 采取防止静电放电的措施。
P241 : 使用防爆的电气/通风/照明设备。
P242 : 只能使用不产生火花的工具。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P403 + P235 : 存放在通风良好的地方。保持低温。

运输信息

UN编号UN3271
类别3
包装类别 III
监管条件代码(*)
221851J&K2-Methylanisole99%95元/25G;   284元/100G;   1131元/500G;   展开

基本信息

分子式C8H10O
分子量122.17
沸点170-172
闪点52
密度0.985
折光率(n20D)1.5160
MDL编码MFCD00008373
EINECS 编号209-426-3

安全信息

图形或危害标志
提示语Warning
危险说明H226
防范说明P210
UN号码1993
危险分类3
包装等级III
WGK3
TSCA
A13897Alfa Aesar2-Methylanisole99%1286元/50g;   2907元/250g;   9855元/1000g;   展开

应用
The catalytic system of disubstituted aromatics was optimized for the 2-methylanisole reduction by a proper choice of the amine/Rh ratio which should be high enough to stabilize very small colloidal rhodium particles and low enough to avoid deactivation. The total synthesis of (?±)-heliannuol D and its epimer has been completed in 9 steps and 12% overall yield from 2-methylanisole. The thermal activation of 2-methylanisole (60?°C) by the Ir (III) complex TpMe2Ir (C6H5) 2 (N2)(1; TpMe2= hydrotris (3, 5-dimethylpyrazolyl) borate) yielded a mixture of hydride complexes. The total synthesis of the phenolic sesquiterpene mutisianthol has been accomplished in 12 steps from the readily available 2-methylanisole. The catalytic system was optimized for the 2-methylanisole reduction by a proper choice of the amine/Rh ratio which should be high enough to stabilize very small colloidal rhodium particles and low enough to avoid deactivation.

备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

基本信息

MDL
MFCD00008373

EINECS
209-426-3

分子式
C8H10O

分子量
122.17

沸点
170-172°

闪点
51°(123°F)

密度
0.985

折射率
1.5170

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Insoluble in water.

Beilstein
1857415

GHS危害和防范说明

GHS符号

Hazard Statements
H226
Flammable liquid and vapour.

Precautionary Statements
P261
Avoid breathing dust/fume/gas/mist/vapours/spray.

安全信息

危险等级
3

包装组
III

危险类别
10
Flammable.

安全等级
60
This material and its container must be disposed of as hazardous waste

TSCA

C12628Alfa Aesar2-Methylanisole99%645元/5g;   1686元/100g;   7535元/500g;   展开

基本信息

Ref#
12628

MDL
8373

分子式
C8 H10 O

分子量
122.17

闪点
51

密度
0.98

安全信息

危险等级
3

包装组
III

W268003Sigma-Aldrich2-Methylanisole≥99%, FG404.65元/;   761.03元/100 G;   3481.44元/1 KG;   展开

产品说明

一般描述

2-Methylanisole is found in mastic oils, virgin olive oils and frankincense.

包装

100 g in poly bottle
1 kg in poly bottle
5 kg in poly drum

基本信息

线性分子式CH3C6H4OCH3
分子量122.16
FEMA编号2680
EC 号209-426-3
欧洲委员会编号187
MDL编号MFCD00008373
PubChem化学物质编号24901245
Flavis编号4.014
NACRESNA.21

产品性质

质量水平400
生物来源synthetic
等级FG
Halal
Kosher
agencymeets purity specifications of JECFA
reg. complianceEU Regulation 1334/2008 & 178/2002
FDA 21 CFR 117
FDA 21 CFR 172.515
测定≥99%
折射率n20/D 1.516 (lit.)
bp170-172 ℃ (lit.)
密度0.985 g/mL at 25 ℃ (lit.)
文件see Safety & Documentation for available documents
性状检查floral; earthy; walnut
application(s)flavors and fragrances
食品过敏原no known allergens
SMILES stringCOc1ccccc1C
InChI1S/C8H10O/c1-7-5-3-4-6-8(7)9-2/h3-6H,1-2H3
InChI keyDTFKRVXLBCAIOZ-UHFFFAOYSA-N

安全信息

象形图GHS02
警示用语:Warning
危险声明H226
危险分类Flam. Liq. 3
储存分类代码3 - Flammable liquids
WGKWGK 3
闪点(F)125.6 °F - closed cup
闪点(C)52 ℃ - closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
242932Fluorochem1-Methoxy-2-methylbenzene98%220元/1g;   308元/25g;   3080元/500ml;   展开

基本信息

CAS Number578-58-5
MDL NumberMFCD00008373
Boiling Point171℃
Density0.97

安全信息

图形或危害标志
危险性说明 H226: Flammable liquid and vapour.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P210: Keep away from – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof ./ equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P370 + P378: In case of fire: Use sand, CO2 or extinguishing powder for extinction.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P403 + P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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