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CAS: 571-55-1
分子式: C9H11F3O4
分子量: 240.18
沸点: 80-82 °C
英文名称: 
Ethyl 2-(ethoxymethylene)-4,4,4-trifluoro-3-oxobutyrate,mixture of cis and trans
ethyl 2-(ethoxymethylene)-4,4,4-trifluoro-3-oxobu
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货号品牌产品名称规格包装、参考价格
E828168MACKLIN乙氧基-2-亚甲基三氟乙酰乙酸乙酯95%42元/5g;   185元/25g;   咨询
储存:室温
状态:无色到黄色和无色到橙色液体
折射率:n20/D 1.429(lit.)
E1087TCIEthyl 2-(Ethoxymethylene)-4,4,4-trifluoro-3-oxobutyrate>96.0%(GC)390元/5G;   1490元/25G;   咨询

基本信息

纯度/分析方法>96.0%(GC)
分子式/分子量C9H11F3O4 = 240.18
外观与形状(20℃)液体
储存温度0-10℃
应避免的情况加热
Reaxys-RN1712385
PubChem物质ID253662306
MDL编号MFCD02677683

技术规格

AppearanceLight orange to Yellow to Green clear liquid
Purity(GC)min. 96.0 %

物性(参考值)

沸点120 ℃/10 mmHg
闪点104 ℃
比重1.24
折射率1.43

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
192606J&KEthyl 2-(Ethoxymethylene)-4,4,4-trifluoro-3-oxobutyrate97%, 顺反异构体混合物272元/5G;   910元/25G;   咨询

基本信息

分子式C9H11F3O4
分子量240.18
熔点80-82
沸点80-82
密度1.235
折光率(n20D)1.4290
MDL编码MFCD02677683
存储条件Store at 2-8℃

安全信息

图形或危害标志
提示语Warning
危险说明H319
H335
H315
H302
防范说明P261
P301+
P312
P302+P352
P280
P305+P351+P338
WGK3
TSCA
H25927Alfa AesarEthyl 2-ethoxymethylene-4,4,4-trifluoro-3-oxobutyrate97%3628元/10g;   11391元/50g;   咨询

基本信息

MDL
MFCD02677683

分子式
C9H11F3O4

分子量
240.18

沸点
80-82°/1mm

闪点
104°(220°F)

密度
1.235

折射率
1.4290

形态
Liquid

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319
Causes skin irritation.Causes serious eye irritation.

Precautionary Statements
P280a-P264-P305+P351+P338-P321-P332+P313-P337+P313
Wear protective gloves and eye/face protection.Wash thoroughly after handling.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Specific treatment (see label).If skin irritation occurs: Get medical advice/attention.If eye irritation persists: Get medical advice/attention.

安全信息

危险类别
36/38
Irritating to eyes and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA

441236Sigma-AldrichEthyl 2-(ethoxymethylene)-4,4,4-trifluoro-3-oxobutyrate,mixture of cis and trans96%1232.39元/10 G;   咨询

产品说明

一般描述

Ethyl 2-(ethoxymethylene)-4,4,4-trifluoro-3-oxobutyrate has been reported to participate in the microwave-assisted synthesis of ethyl 1-[4-(2,3,3-trichloroacrylamido)phenyl]-5-(trifluoromethyl)-1H-pyrazole-4-carboxylate.

应用

Ethyl 2-(ethoxymethylene)-4,4,4-trifluoro-3-oxobutyrate may be employed as a starting reagent for the synthesis of 1-methyl-3-trifluoromethyl-1H-pyrazole-4- carboxylic acid.

包装

10 g in glass bottle

基本信息

线性分子式CF3COC(=CHOC2H5)CO2C2H5
分子量240.18
MDL编号MFCD02677683
PubChem化学物质编号24867645
NACRESNA.22

产品性质

质量水平100
测定96%
折射率n20/D 1.429 (lit.)
bp80-82 ℃/1 mmHg (lit.)
密度1.235 g/mL at 25 ℃ (lit.)
储存温度2-8℃
SMILES stringCCO\C=C(\C(=O)OCC)C(=O)C(F)(F)F
InChI1S/C9H11F3O4/c1-3-15-5-6(8(14)16-4-2)7(13)9(10,11)12/h5H,3-4H2,1-2H3/b6-5+
InChI keyXNGGOXOLHQANRB-AATRIKPKSA-N

安全信息

储存分类代码10 - Combustible liquids
WGKWGK 3
闪点(F)219.2 °F - closed cup
闪点(C)104.00 ℃ - closed cup
个人防护装备Eyeshields, Gloves
008919FluorochemEthyl 2-(ethoxymethylene)-4,4,4-trifluoroacetoacetate96%220元/1g;   396元/5g;   726元/10g;   1342元/25g;   咨询

基本信息

CAS Number571-55-1
MDL NumberMFCD02677683
Boiling Point80-82℃/1mm
Density1.235

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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