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CAS: 570-22-9
分子式: C5H4N2O4
分子量: 156.10
熔点: 265℃
中文名称: 
4,5-咪唑二羧酸
4,5-二羧基咪唑
咪唑-4,5-二甲酸
4,5-二羧酸咪唑
咪唑-4,5-二羧酸
英文名称: 
imidazole-4,5-dicarboxylic acid
1h-imidazole-4,5-dicarboxylic acid
4,5-dicarboxyimidazole
4,5-imidazoledicarboxylate
alpha-beta-imidazolecarboxylic acid
glycoxalinedicarboxylic acid
4,5-imidazoledicarboxylic acid
H-Imidazole-4,5-dicarboxylic acid
,-Imidazoledicarboxylic acid
Glyoxalinedicarboxylic acid
性质描述: 白色结晶性粉末。熔点约280℃(分解为咪唑和二氧化碳)。溶于氨或碱溶液,不溶于水、乙醇、乙醚。
生产方法: 由邻苯二胺经环合、开环而得。将邻苯二胺加入甲酸中,搅拌加热,在95-98℃保温2h。降温至50-60℃,用10%氢氧化钠溶液调节至pH=10,降至室温,过滤,水洗,干燥,得苯骈咪唑。在搅拌下将苯并咪唑投入浓酸中,升温至100℃,慢慢滴加双氧水,加毕,在140-150℃搅拌反应1h,降温至40℃,加水稀释,析出结晶,过滤,水洗,干燥,得4,5-羧基咪唑。
用途: 用于生产咪唑。
推荐供应商
货号品牌产品名称规格包装、参考价格
I811794MACKLIN咪唑-4,5-二羧酸97%39元/5g;   110元/25g;   398元/100g;   1455元/500g;   咨询
储存:室温
状态:淡黄色到黄色-棕色粉末
I0003TCI1H-Imidazole-4,5-dicarboxylic Acid>98.0%(T)(HPLC)375元/5G;   咨询

基本信息

纯度/分析方法>98.0%(T)(HPLC)
分子式/分子量C5H4N2O4 = 156.10
外观与形状(20℃)固体
Reaxys-RN147774
PubChem物质ID87571413
MDL编号MFCD00005200

技术规格

AppearanceWhite to Orange to Green powder to crystal
Purity(HPLC)min. 98.0 area%
Purity(Neutralization titration)min. 98.0 %

物性(参考值)

熔点283 ℃(dec.)

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。

相关法规

RTECS#NI4760000
493510J&K4,5-Imidazoledicarboxylic acid99%196元/5G;   781元/25G;   2573元/100G;   咨询

基本信息

分子式C5H4N2O4
分子量156.10
熔点280-285
MDL编码MFCD00005200
Beilstein147774
EINECS 编号209-327-5

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
RTECSNI4760000
TSCA
A17783Alfa Aesar4,5-Imidazoledicarboxylic acid97%682元/5g;   1908元/25g;   6695元/100g;   咨询

基本信息

MDL
MFCD00005200

EINECS
209-327-5

分子式
C5H4N2O4

分子量
156.10

熔点
ca 283° dec.

密度
1.749

形态
Powder

Beilstein
147774

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

RTECS
NI4760000

TSCA

C41225Alfa Aesar4,5-Imidazoledicarboxylic acid99%3196元/25g;   咨询

基本信息

Ref#
41225

MDL
5200

分子式
C5 H4 N2 O4

分子量
156.1

形态
White to cream/pale yellow powder

8.18370Sigma-AldrichImidazole-4,5-dicarboxylic acidfor synthesis596.99元/10 G;   咨询

基本信息

经验(实验)分子式C5H4N2O4
分子量156.10
MDL编号MFCD00005200
EC索引号209-327-5

产品性质

质量水平200
自燃温度430 ℃
pH值(酸碱度)3.7 (20 ℃, 0.5 g/L in H2O)
mp270-275 ℃
溶解性 0.5 g/L
堆积密度650‑660 kg/m3
储存温度2-30℃
InChI1S/C5H4N2O4/c8-4(9)2-3(5(10)11)7-1-6-2/h1H,(H,6,7)(H,8,9)(H,10,11)
InChI keyZEVWQFWTGHFIDH-UHFFFAOYSA-N

安全信息

储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
985783Amethyst4,5-Imidazoledicarboxylic acid99%, 用于合成58元/5G;   146元/25G;   488元/100G;   1764元/500G;   咨询

基本信息

分子式C5H4N2O4
分子量156.10
熔点280-285
MDL编码MFCD00005200
Beilstein147774
EINECS 编号209-327-5

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
RTECSNI4760000
TSCA
009677FluorochemImidazole-4,5-dicarboxylic acid95%220元/1g;   220元/10g;   418元/25g;   1540元/100g;   14872元/1kg;   咨询

基本信息

CAS Number570-22-9
MDL NumberMFCD00005200
Melting Point280-285℃
Density1.749

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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