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CAS: 56602-33-6
分子式: C12H22F6N6OP2
分子量: 442.28
熔点: 136-140℃
中文名称: 
卡特缩合剂
苯并三唑-1-三(三甲氨基)-三氟磷酸酯
英文名称: 
(Benzotriazol-1-yloxy)tris(dimethylamino)phosphonium hexafluorophosphate
Benzotriazol-1-yloxytris(dimethylamino)phosphonium hexafluorophosphate
Castro's Reagent
1H-Benzotriazol-1-yloxytris(dimethylamino)phosphonium Hexafluorophosphate
BOP Reagent
benzotriazol-1-yl-oxy-tris(dimethylamino)phosphonium hexafluorophosphate
benzotriazol-1-yl-oxytris(dimethylamino)phosphonium hexa-fluorophosphate(bop)
(1-hydroxy-1h-benzotriazolato-o)tris(n-methylmethanaminato)-phosphorus(1++
benzotriazol-1-yloxytris(dimethylamino)-phosphonium hexafluorophosphate
推荐供应商
货号品牌产品名称规格包装、参考价格详情
B802385MACKLIN卡特缩合剂98%34元/5g;   59元/25g;   156元/100g;   680元/500g;   展开
储存：2~8°C
状态：白色到棕色晶体
B1651TCI1H-Benzotriazol-1-yloxytris(dimethylamino)phosphonium Hexafluorophosphate [Coupling Reagent for Peptide]>98.0%(HPLC)95元/5G;   240元/25G;   690元/100G;   展开

基本信息

纯度/分析方法>98.0%(HPLC)
分子式/分子量C12H22F6N6OP2 = 442.29
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况光,湿气 (分解)
Reaxys-RN4287025
PubChem物质ID87564552
MDL编号MFCD00011948

技术规格

AppearanceWhite to Light yellow powder to crystal
Purity(HPLC)min. 98.0 area%
Lambda max.253.0 to 257.0 nm(CH3CN)
Absorbancemin. 0.280(0.02g/L, CH3CN, 253.0 to 257.0 nm)

物性(参考值)

最大吸收波长255(CH3CN) nm

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染：用水充分清洗。
P337 + P313 : 如仍觉眼刺激：求医/就诊。
P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激：求医/就诊。
151585J&KBenzotriazol-1-yloxytris(dimethylamino)-phosphonium hexafluorophosphate98%60元/5G;   142元/25G;   447元/100G;   展开

基本信息

分子式C12H22F6N6OP2
分子量442.28
熔点136-140
MDL编码MFCD00011948
Beilstein4287025
EINECS 编号260-279-1
存储条件Store at 2-8℃

安全信息

图形或危害标志
提示语Danger
危险说明H228
H315
H335
防范说明P210
P370+P378
UN号码1325
危险分类4.1
包装等级II
WGK3
TSCA否
A16140Alfa Aesar1H-Benzotriazol-1-yloxytris(dimethylamino)phosphonium hexafluorophosphate98%403元/1g;   954元/5g;   4319元/25g;   展开

应用
1H-Benzotriazol-1-yloxytris(dimethylamino)phosphonium hexafluorophosphate is used as a reagent for peptide coupling, lactonization, selective esterification, amidation of alfa amino acids without racemization and synthesis of magnolamide for antioxidative activity and catalyst for 9-acridinecaroboxamide derivative. It is also used as a precursor for the synthesis of phenyl esters of amino acids. It acts as a substitute for (Benzotriazol-1-yloxy)tris(dimethylamino)phosphonium hexafluorophosphate (BOP) reagent.

备注
Moisture and light sensitive. Incompatible with strong oxidizing agents. Store in a cool place. Keep the container tightly closed.

基本信息

MDL
MFCD00011948

EINECS
260-279-1

分子式
C12H22F6N6OP2

分子量
442.29

熔点
ca 138° dec.

灵敏度
Keep Cold. Moisture Sensitive. Light Sensitive. Store under Nitrogen.

形态
Crystalline powder

溶解性
Soluble in methanol, acetone and dichloromethane. Insoluble in water.

Beilstein
4287025

GHS危害和防范说明

GHS符号

Hazard Statements
H228-H315-H319-H335
Flammable solid.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P210-P261-P280-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
4.1

包装组
II

危险类别
11-36/37/38-44
Highly flammable.Irritating to eyes, respiratory system and skin.Risk of explosion if heated under confinement.

安全等级
26-37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA
否

226084Sigma-Aldrich(Benzotriazol-1-yloxy)tris(dimethylamino)phosphonium hexafluorophosphate97%193.02元/1 G;   411.82元/5 G;   展开

产品说明

应用

试剂用于：
肽偶联
酯的合成
羧酸的酯化
质粒 CAN 包封脂质体
具有抗氧化活性的木兰花酰胺的合成
9-吖啶卡罗酰胺衍生物的合成催化剂

包装

1, 5 g in glass bottle

基本信息

经验(实验)分子式C12H22F6N6OP2
分子量442.28
Beilstein4287025
EC 号260-279-1
MDL编号MFCD00011948
PubChem化学物质编号24853542
NACRESNA.22

产品性质

质量水平200
测定97%
形式powder
reaction suitabilityreaction type: Coupling Reactions
mp>130 ℃ (dec.) (lit.)
application(s)peptide synthesis
储存温度2-8℃
SMILES stringF[P-](F)(F)(F)(F)F.CN(C)[P+](On1nnc2ccccc12)(N(C)C)N(C)C
InChI1S/C12H22N6OP.F6P/c1-15(2)20(16(3)4,17(5)6)19-18-12-10-8-7-9-11(12)13-14-18;1-7(2,3,4,5)6/h7-10H,1-6H3;/q+1;-1
InChI keyMGEVGECQZUIPSV-UHFFFAOYSA-N

安全信息

象形图GHS02GHS07
警示用语：Danger
危险声明H228 - H315 - H335
预防措施声明P210 - P240 - P241 - P261 - P264 - P302 + P352
危险分类Flam. Sol. 1 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
补充剂危害EUH044
储存分类代码4.1A - Other explosive hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
536379AmethystBenzotriazol-1-yloxytris(dimethylamino)-phosphonium hexafluorophosphate98%, 用于合成55元/5G;   86元/25G;   237元/100G;   938元/500G;   展开

基本信息

分子式C12H22F6N6OP2
分子量442.28
熔点136-140
MDL编码MFCD00011948
Beilstein4287025
EINECS 编号260-279-1
存储条件Store at 2-8℃

安全信息

图形或危害标志
提示语Danger
危险说明H228
H315
H335
防范说明P210
P261
UN号码1325
危险分类4.1
包装等级II
WGK3
TSCA否
009018FluorochemBenzotriazol-1-yloxytris(dimethylamino)phosphonium hexafluorophosphate98%308元/5g;   616元/25g;   880元/100g;   2970元/500g;   展开

基本信息

CAS Number56602-33-6
MDL NumberMFCD00011948
Melting Point>130℃ (dec)

安全信息

图形或危害标志
危险性说明 EUH044: Risk of explosion if heated under confinement.
H228: Flammable solid.
H315: Causes skin irritation.
H335: May cause respiratory irritation.
防范说明 P210: Keep away from – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof / equipment.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P370 + P378: In case of fire: Use for extinction.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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