[登录] [免费注册]
试剂仪器网
位置:首页 > 资料中心 > 化工字典 > 56-37-1
关键词:       仅模糊查询
CAS: 56-37-1
分子式: C13H22ClN
分子量: 227.28
熔点: 185℃
中文名称: 
苄基四乙基铵氯化物
苄基三乙基氯化铵
三乙基苄基氯化铵
英文名称: 
Benzenemethanaminium, N,N,N-triethyl-, chloride
benzyltriethyl-ammoniu chloride
n,n,n-triethyl-benzenemethanaminiu chloride
benzyltriethylammonium chloride
n,n,n-triethylbenzenemethanaminium chloride
teba
tebac
triethylbenzylammonium chloride
Benzenemethanaminium,N,N,N-triethyl-,chloride
Benzyl triethyl ammonium chlor
Benzyltriethylammoniun chloride
BTEAC
展开更多英文名
性质描述: 熔点185℃(分解)。
生产方法: 将氯化苄、三乙胺、丙酮加入反应锅,在63-64℃回流8小时。缓缓降至15℃,过滤,滤饼用丙酮洗涤,干燥,得TEBA。收率68.9%。
用途: 相转移催化剂。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
B802553MACKLIN三乙基苄基氯化铵98%32元/100g;   59元/500g;   208元/2.5kg;   800元/10kg;   700元/12X500g;   展开
储存:室温
状态:白色到灰色粉末或晶体
B0444TCIBenzyltriethylammonium Chloride>98.0%(T)110元/25G;   490元/500G;   展开

基本信息

纯度/分析方法>98.0%(T)
分子式/分子量C13H22ClN = 227.78
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (吸湿)
Reaxys-RN3574984
PubChem物质ID87563481
SDBS (AIST Spectral DB)3069
MDL编号MFCD00011824

技术规格

AppearanceWhite powder to crystal
Purity(Nonaqueous Titration)min. 98.0 %(calcd.on dried substance)
Solubility in Wateralmost transparency
Drying lossmax. 2.0 %

物性(参考值)

熔点192 ℃
水溶性可溶

安全信息

图形或危害标志
信号词警告
危险性说明H303 : 吞咽可能有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P312 : 如感觉不适,呼叫急救中心/医生。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。

相关法规

RTECS#BO8275000
179530J&KBenzyltriethylammonium Chloride98%130元/100G;   470元/500G;   展开

基本信息

分子式C13H22ClN
分子量227.78
熔点190-192
闪点>275
MDL编码MFCD00011824
Beilstein3574984
EINECS 编号200-270-1

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK1
RTECSBO8275000
TSCA
A13268Alfa AesarBenzyltriethylammonium Chloride99%444元/100g;   1539元/500g;   展开

应用
Benzyltriethylammonium chloride is used as a catalyst in the preparation of 2-phenylbutyronitrile from phenyl acetonitrile. It is involved in the Knoevenagel condensation of carbonyl compounds with active methylene compounds to give olefinic products. It acts as a phase transfer catalyst used in the alkylation reaction. It reacts with 1H-Pyridine-2-thione to get 2-Benzylsulfanyl-pyridine.

备注
Store in cool place. Hygroscopic. Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00011824

EINECS
200-270-1

分子式
(CH3CH2)3N(CH2C6H5)Cl

分子量
227.78

熔点
ca 190° dec.

灵敏度
Hygroscopic. Ambient temperatures.

形态
Crystalline powder

溶解性
Soluble in acetone, alcohol and water. Insoluble in ether.

Beilstein
3574984

GHS危害和防范说明

GHS符号

Hazard Statements
H303-H315-H319-H335
May be harmful if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste

RTECS
BO8275000

TSCA

C16402Alfa AesarBenzyltriethylammonium Chloride98%524元/100g;   1644元/500g;   6321元/2.5kg;   展开

基本信息

Ref#
16402

MDL
11824

分子式
C13 H22 Cl N

分子量
227.78

闪点
>275

形态
White to pale cream cryst powder

安全信息

危险等级
4.1

包装组
III

146552Sigma-AldrichBenzyltriethylammonium Chloride99%159.24元/25 G;   202.15元/100 G;   481.01元/500 G;   展开

产品说明

应用

苄基三乙基氯化铵是一种亲脂相转移催化剂,可用于相转移催化(PTC),催化缩聚反应在双相条件下形成高分子量聚合物。

其还可用于:

  • 活化羟基磷灰石和天然磷酸盐,分别在室温和不存在溶剂的情况下用作Knoevenagel缩合和Claisen-Schmidt缩合的固体载体。
  • 提高mCPBA氧化亚磺酰胺(由芳烃醛和芳醛的二乙缩醛生成),形成2-磺酰基恶唑烷的的效率。
  • 与氯化锑(V)结合形成催化体系,用于芳烃与酰基氯和磺酰氯的Friedel-Crafts酰化反应。

包装

25, 100, 500 g in glass bottle

基本信息

线性分子式C6H5CH2N(Cl)(C2H5)3
分子量227.77
Beilstein3574984
EC 号200-270-1
MDL编号MFCD00011824
PubChem化学物质编号24848786
NACRESNA.22

产品性质

质量水平200
测定99%
mp190-192 ℃ (dec.) (lit.)
SMILES string[Cl-].CC[N+](CC)(CC)Cc1ccccc1
InChI1S/C13H22N.ClH/c1-4-14(5-2,6-3)12-13-10-8-7-9-11-13;/h7-11H,4-6,12H2,1-3H3;1H/q+1;/p-1
InChI keyHTZCNXWZYVXIMZ-UHFFFAOYSA-M

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 1
闪点(F)527.0 °F - closed cup
闪点(C)> 275 ℃ - closed cup
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
157600AmethystBenzyltriethylammonium Chloride98%, 用于合成63元/100G;   126元/500G;   219元/2.5KG;   展开

基本信息

分子式C13H22ClN
分子量227.78
熔点190-192
闪点>275
MDL编码MFCD00011824
Beilstein3574984
EINECS 编号200-270-1

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK1
RTECSBO8275000
TSCA
044783FluorochemBenzyl triethylammonium chloride99%396元/250g;   1430元/1kg;   2970元/2.5kg;   展开

基本信息

CAS Number56-37-1
MDL NumberMFCD00011824
Boiling Point250℃
Melting Point190-200℃
Density0.646

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H317: May cause an allergic skin reaction.
H412: Harmful to aquatic life with long lasting effects.
防范说明 P261: Avoid breathing .
P264: Wash thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P272: Contaminated work clothing should not be allowed out of the workplace.
P273: Avoid release to the environment.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P333 + P313: If skin irritation or rash occurs: Get medical advice/attention.
P363: Wash contaminated clothing before reuse.
P501: Dispose of contents/container to local regulations..
CAS号首数字顺序排列: 1 2 3 4 5 6 7 8 9