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CAS: 547-58-0
分子式: C14H14N3NaO3S
分子量: 327.34
熔点: 300℃
中文名称: 
4-{[4-(二甲氨基)苯]偶氮}苯磺酸钠盐
甲基橙
4-[[4-(二甲氨基)苯基]偶氮基]苯磺酸钠盐
对二甲氮基偶苯磺酸钠
金莲橙D
对二甲基氨基偶氮苯磺酸钠
甲基橙钠盐
4-[对(二甲氨基)苯偶氮]苯磺酸钠
英文名称: 
Benzenesulfonic acid, 4-[[4-(dimethylamino)phenyl]azo]-, sodium salt
p-((p-(dimethylamino)phenyl)azo)-benzenesulfonic aci sodium salt
4-dimethylaminoazobenzene-4'-sulphonic acid sodium salt
4-((4-(dimethylamino)phenyl)azo)-benzenesulfonic aci sodium salt
4-[[4-(dimethylamino)phenyl]azo]-benzenesulfonic aci sodium salt
c.i. 13025
c.i. acid orange 52
ci 13025
ci acid orange 52
eniamethyl orange
gold orange
Sodium p-dimethylaminoazobenzene sulfonate
helianthine
helianthine b
kca methyl orange
methyl orange b
methyloranz
orange 3
orange iii
oranz iii
oranz kysela 52
oranz methylova
p-((p-(dimethylamino)phenyl)azo)benzenesulfonic acid sodium salt
sodium 4-(dimethylamino) azobenzene-4'-sulfonate
sodium p-dimethylaminoazobenzenesulfonate
tropaeolin
4-dimethylaminoazobenzene-4-sulfonic acid,sodium salt
abcol methyl orange
c.i. acid orange 52(methyl orange)
c.i.acidorange52(methylorange)
Benzenesulfonic acid,4-[[4-(dimethylamino)phenyl]azo]-,sodium salt
4-[4-(Dimethylamino)phenylazo]benzenesulfonic acid sodium salt
Methyl Orange solution
Methyl Orange sodium salt,ACS
Acid Orange 52
C.I.13025
展开更多英文名
性质描述: 橙黄色粉末或结晶状鳞片。该品1份可溶于500份水中,易溶于热水,几乎不溶于醇。
生产方法: 由对氨基苯磺酸经重氮化后与N,N-二甲基苯反应而得。将对氨基磺酸溶解于2.5%的碳酸钠溶液中,加入亚硝酸钠,待完全溶解后,加入碎冰和盐酸进行重氮化反应,析出重氮盐结晶。向重氮盐溶液中加入N,N-二甲基苯胺和冰醋酸的混合液,搅拌10min后慢慢加入10%氢氧化钠溶液至碱性。冷却结晶,过滤,用饱和盐水洗涤,干燥,用水重结晶,得甲基橙。
用途: 作酸碱指示剂,pH3.1(红)-4.4(黄),也用于生物染色。
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M0017TCIMethyl Orange (0.1% in Water) [for Titration]330元/500ML;   展开

基本信息

分子式/分子量C14H14N3NaO3S = 327.33
外观与形状(20℃)液体
Reaxys-RN3581305
PubChem物质ID87572136
Merck Index (14)6105
颜色13025
MDL编号MFCD00007502

技术规格

AppearanceOrange to Brown to Dark red clear liquid
Transition interval(pH)(yellowish red)3.1 to 4.4(redish yellow)

相关法规

RTECS#DB6327000
M0489TCIMethyl Orange>98.0%(HPLC)555元/25G;   展开

基本信息

纯度/分析方法>98.0%(HPLC)
分子式/分子量C14H14N3NaO3S = 327.33
外观与形状(20℃)固体
Reaxys-RN3581305
PubChem物质ID87572534
Merck Index (14)6105
颜色13025
MDL编号MFCD00007502

技术规格

AppearanceOrange to Brown powder to crystal
Purity(HPLC)min. 98.0 area%
Lambda max.460.0 to 470.0 nm(pH 4.8 buffer sol.)
Absorbancemin. 0.330(5mg/L, pH 4.8 buffer sol., 460.0 to 470.0 nm)(after drying)
Drying lossmax. 10.0 %
Transition interval(pH)(yellowish red)3.1 to 4.4(reddish yellow)

物性(参考值)

最大吸收波长465(pH 4.8 buffer sol.) nm
水溶性实际上不溶
溶解性(不溶于)醇,乙醚

安全信息

图形或危害标志
信号词危险
危险性说明H301 : 吞咽会中毒。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P301 + P310 + P330 : 如误吞咽:立即呼叫急救中心/医生。漱口。
P405 : 存放处须加锁。

相关法规

RTECS#DB6327000

运输信息

UN编号UN2811
类别6.1
包装类别 III
监管条件代码(*)
313050J&KMethyl Orange, indicator指示剂61元/25G;   200元/100G;   798元/500G;   展开

基本信息

分子式C14H14N3NaO3S
分子量327.32
MDL编码MFCD00007502
Merck14,6105
EINECS 编号208-925-3

安全信息

图形或危害标志
提示语Danger
危险说明H301
防范说明P264
P270
P301+P310
UN号码3143
危险分类6.1
包装等级III
WGK3
038695Alfa AesarMethyl Orange0.1% w/v aq. soln.567元/500ml;   展开

备注
Transition interval: pH 3.2 (pink or red) to pH 4.4 (yellow)

基本信息

MDL
MFCD00007502

EINECS
208-925-3

分子式
C14H14N3NaO3S

分子量
327.34

密度
0.987

灵敏度
Ambient temperatures.

形态
Liquid

安全信息

TSCA

A17604Alfa AesarMethyl Orange522元/100g;   1907元/500g;   展开

应用
Methyl Orange is a pH indicator used in titrations for acids. It is also used for histological microscopy. Further, it is used as counter stain to crystal violet in staining pollen tubes.

备注
Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00007502

EINECS
208-925-3

分子式
C14H14N3NaO3S

分子量
327.34

熔点
>300°

灵敏度
Ambient temperatures.

形态
Powder

溶解性
Soluble in ethanol. Partially soluble in hot water. Slightly soluble in cold water and pyrimidine. Insoluble in ether and alcohol.

Beilstein
4732884

Merck
14,6105

GHS危害和防范说明

GHS符号

Hazard Statements
H301
Toxic if swallowed.

Precautionary Statements
P264-P270-P301+P310a-P321-P405-P501a
Wash thoroughly after handling.Do not eat, drink or smoke when using this product.Do not eat, drink or smoke when using this product.Specific treatment (see label).Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
III

危险类别
25
Toxic if swallowed.

安全等级
36-45-60
Wear suitable protective clothing.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

RTECS
DB6327000

TSCA

017874Alfa AesarMethyl OrangeACS181元/5g;   325元/25g;   853元/100g;   展开

应用
Methyl orange is a pH indicator frequently used in titrations, also used for histological microscopy.

Grade Specifications
Specifications: Clarity of solution P.T., Visual transition interval from pH 3.2 (pink or red) to pH 4.4 (yellow)

备注
Store at room temperature. Store in a cool, dry place in tightly closed container. Incompatible with oxidizing agents.

基本信息

MDL
MFCD00007502

EINECS
208-925-3

分子式
C14H14N3NaO3S

分子量
327.34

熔点
>300°

灵敏度
Ambient temperatures.

形态
Crystalline

溶解性
Soluble in 500 parts water. More soluble in hot water

Beilstein
4732884

Merck
14,6105

GHS危害和防范说明

GHS符号

Hazard Statements
H301
Toxic if swallowed.

Precautionary Statements
P264-P270-P301+P310a-P321-P405-P501a
Wash thoroughly after handling.Do not eat, drink or smoke when using this product.Do not eat, drink or smoke when using this product.Specific treatment (see label).Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
III

危险类别
25
Toxic if swallowed.

安全等级
36-45-60
Wear suitable protective clothing.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

RTECS
DB6327000

TSCA

C15142Alfa AesarMethyl Orangepure, indicator746元/100g;   2976元/500g;   展开

基本信息

Ref#
15142

MDL
7502

分子式
C14 H14 N3 Na O3 S

分子量
327.32

形态
Crystalline

安全信息

危险等级
6.1

包装组
III

C41466Alfa AesarMethyl OrangeACS reagent505元/10g;   607元/25g;   916元/100g;   展开

基本信息

Ref#
41466

MDL
7502

分子式
C14 H14 N3 Na O3 S

分子量
327.32

形态
Crystalline

安全信息

危险等级
6.1

包装组
III

M216-25Alfa AesarMETHYL ORANGE CERT ACS 25G765元/25g;   展开

基本信息

Ref#
F51507

安全信息

危险等级
6.1

包装组
III

SM54-500Alfa AesarMETHYL ORANGE SOL R 500ML492元/500ml;   展开

基本信息

Ref#
F52894

安全信息

危险等级
6.1

包装组
III

M216-500Alfa AesarMETHYL ORANGE CERT ACS 500G1901元/500g;   展开

基本信息

Ref#
F51516

安全信息

危险等级
6.1

包装组
III

1.01322SupelcoMethyl orange (C.I. 13025)indicator ACS,Reag. Ph Eur1225.32元/25 G;   4288.62元/100 G;   30633元/1 KG;   展开

产品说明

分析说明

Transition range: pH 3.1 - pH 4.4pink - orange yellow
Appearance of solution: passes test
Loss on drying (110 °C): ≤ 5
Transition range (according to ACS): passes test
Sensitivity test: passes test

基本信息

经验(实验)分子式C14H14N3NaO3S
分子量327.33
MDL编号MFCD00007502
EC索引号208-925-3

产品性质

质量水平200
等级ACS reagent
agencyreag. Ph. Eur.
效能60 mg/kg LD50, oral (Rat)
缺失≤5% loss on drying, 110℃
pH值(酸碱度)6.5 (20 ℃, 5 g/L in H2O)
mp>300 ℃
堆积密度200‑400 kg/m3
储存温度2-30℃
InChI1S/C14H15N3O3S/c1-17(2)13-7-3-11(4-8-13)15-16-12-5-9-14(10-6-12)21(18,19)20/h3-10H,1-2H3,(H,18,19,20)/p-1
InChI keyIETWCRRCPURZOC-UHFFFAOYSA-M

安全信息

象形图GHS06
警示用语:Danger
危险声明H301
预防措施声明P264 - P270 - P301 + P310 - P405 - P501
危险分类Acute Tox. 3 Oral
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
114510Sigma-AldrichMethyl OrangeACS reagent, Dye content 85 %577.46元/25 G;   794.16元/100 G;   2931.01元/500 G;   展开

产品说明

包装

25, 100, 500 g in glass bottle

生化/生理作用

甲基橙是一种偶氮染料,可用作pH指示剂。

基本信息

经验(实验)分子式C14H14N3NaO3S
分子量327.33
颜色索引号13025
Beilstein4732884
EC 号208-925-3
MDL编号MFCD00007502
PubChem化学物质编号24847177
NACRESNA.47

产品性质

质量水平200
等级ACS reagent
形式powder
组成Dye content, 85%
technique(s)titration: suitable
pH范围3.0 - 4.4, pink to yellow
视觉变色范围3.2 - 4.4, red to yellow
mp>300 ℃
λmax505 nm
application(s)diagnostic assay manufacturing
hematology
histology
储存温度room temp
SMILES string[Na+].CN(C)c1ccc(cc1)\N=N\c2ccc(cc2)S([O-])(=O)=O
InChI1S/C14H15N3O3S.Na/c1-17(2)13-7-3-11(4-8-13)15-16-12-5-9-14(10-6-12)21(18,19)20;/h3-10H,1-2H3,(H,18,19,20);/q;+1/p-1/b16-15+;
InChI keySTZCRXQWRGQSJD-GEEYTBSJSA-M

安全信息

象形图GHS06
警示用语:Danger
危险声明H301
预防措施声明P301 + P330 + P331 + P310
危险分类Acute Tox. 3 Oral
储存分类代码6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
68250Sigma-AldrichMethyl Orangefor microscopy (Hist.), indicator (pH 3.0-4.4)308.65元/25 G;   481.76元/100 G;   1802.51元/500 G;   展开

产品说明

一般描述

甲基橙是一种橙色的合成型燃料,会随着溶液pH值的变化而发生颜色变化。它在酸性溶液中基本呈现为红色而在碱性溶液中为黄色。

基本信息

经验(实验)分子式C14H14N3NaO3S
分子量327.33
颜色索引号13025
Beilstein4732884
EC 号208-925-3
MDL编号MFCD00007502
PubChem化学物质编号329760496
NACRESMA.02

产品性质

质量水平200
等级for microscopy (Hist.)
indicator (pH 3.0-4.4)
形式powder
technique(s)titration: suitable
pH范围3.0 - 4.4, pink to yellow
溶解性methanol: water (1:1): 0.1 g/10 mL, orange to very deep orange
λmax501.4 nm in H2O (acidified)
application(s)diagnostic assay manufacturing
hematology
histology
储存温度room temp
SMILES string[Na+].CN(C)c1ccc(cc1)\N=N\c2ccc(cc2)S([O-])(=O)=O
InChI1S/C14H15N3O3S.Na/c1-17(2)13-7-3-11(4-8-13)15-16-12-5-9-14(10-6-12)21(18,19)20;/h3-10H,1-2H3,(H,18,19,20);/q;+1/p-1/b16-15+;
InChI keySTZCRXQWRGQSJD-GEEYTBSJSA-M

安全信息

象形图GHS06
警示用语:Danger
危险声明H301
预防措施声明P264 - P270 - P301 + P310 - P405 - P501
危险分类Acute Tox. 3 Oral
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
492450FluorochemMethyl Orange220元/1g;   264元/10g;   462元/25g;   4202元/250g;   7590元/1kg;   展开

基本信息

CAS Number547-58-0
MDL NumberMFCD00007502

安全信息

图形或危害标志
危险性说明 H301: Toxic if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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