[登录] [免费注册]
试剂仪器网
位置:首页 > 资料中心 > 化工字典 > 5437-45-6
关键词:       仅模糊查询
CAS: 5437-45-6
分子式: C9H9BrO2
分子量: 229.07
沸点: 166-170℃
中文名称: 
苄基溴乙酸酯
二溴乙酸苄酯
溴乙酸苄酯
英文名称: 
bromo-acetic aci benzyl ester
bromo-acetic aci phenylmethyl ester
benzyl 2-bromoacetate
benzyl bromoacetate
bromoacetic acid benzyl ester
merbac 35
benzylbromoacetate
推荐供应商
货号品牌产品名称规格包装、参考价格详情
B802230MACKLIN溴乙酸苄酯96%39元/25g;   105元/100g;   495元/500g;   2448元/2.5kg;   展开
储存:室温
状态:无色到浅黄色液体
折射率:n20/D 1.544(lit.)
B1674TCIBenzyl Bromoacetate>96.0%(GC)200元/25G;   1490元/500G;   展开

基本信息

纯度/分析方法>96.0%(GC)
分子式/分子量C9H9BrO2 = 229.07
外观与形状(20℃)液体
Reaxys-RN973658
PubChem物质ID87564575
SDBS (AIST Spectral DB)23262
MDL编号MFCD00000190

技术规格

AppearanceColorless to Light yellow clear liquid
Purity(GC)min. 96.0 %

物性(参考值)

沸点170 ℃/22 mmHg
比重1.46
折射率1.54
水溶性不溶

安全信息

图形或危害标志
信号词警告
危险性说明H302 + H312 + H332 : 吞咽、皮肤接触或吸入有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P302 + P352 + P312 : 如皮肤沾染:用水充分清洗。如感觉不适,呼叫急救中心/医生。
P304 + P340 + P312 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。如感觉不适,呼叫急救中心/医生。

相关法规

RTECS#AF5957215
508990J&KBenzyl Bromoacetate96%186元/50G;   587元/250G;   展开

基本信息

分子式C9H9BrO2
分子量229.07
沸点166-170
闪点113
密度1.446
折光率(n20D)1.5440
MDL编码MFCD00000190
Beilstein973658
EINECS 编号226-611-4

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
RTECSAF5957215
TSCA
A17630Alfa AesarBenzyl Bromoacetate97%411元/50g;   1467元/250g;   4841元/1000g;   展开

应用
It is employed in biological research purpose. Benzyl bromoacetate was used in the alkylation of (-)-2,3-O-isopropylidene-D-threitol that afforded lipopeptide, 2-[(4R,5R)-5-({[(9H-fluoren-9-yl)methoxy]carbonylaminomethyl}-2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]acetic acid.

备注
Store away from oxidizing agents and strong bases. Keep the container tightly closed in a cool, dry place. Store under 20?C Freezer, Under Inert Atmosphere.

基本信息

MDL
MFCD00000190

EINECS
226-611-4

分子式
C6H5CH2CO2CH2Br

分子量
229.08

沸点
157-159°/10mm

闪点
>110°(230°F)

密度
1.460

折射率
1.5440

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Not miscible or difficult to mix in water.

Beilstein
973658

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P280g-P305+P351+P338
Wear protective gloves.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

RTECS
AF5957215

TSCA

245631Sigma-AldrichBenzyl Bromoacetate96%365.49元/50 G;   1175.14元/250 G;   展开

产品说明

应用

将溴乙酸苄酯用于 (-)-2,3- O -异亚丙基-D-苏糖醇的烷基化,得到脂肽 2-[(4 R ,5 R )-5-({ [(9 H -芴-9-基)甲氧基] 羰基氨甲基 }-2,2-二甲基-1,3-二氧杂环戊烷-4-基)甲氧基] 乙酸 。

包装

50, 250 g in glass bottle

基本信息

线性分子式BrCH2COOCH2C6H5
分子量229.07
Beilstein973658
EC 号226-611-4
MDL编号MFCD00000190
PubChem化学物质编号24854747
NACRESNA.22

产品性质

质量水平200
测定96%
形式liquid
折射率n20/D 1.544 (lit.)
bp166-170 ℃/22 mmHg (lit.)
密度1.446 g/mL at 25 ℃ (lit.)
SMILES stringBrCC(=O)OCc1ccccc1
InChI1S/C9H9BrO2/c10-6-9(11)12-7-8-4-2-1-3-5-8/h1-5H,6-7H2
InChI keyJHVLLYQQQYIWKX-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码10 - Combustible liquids
WGKWGK 3
闪点(F)235.4 °F - closed cup
闪点(C)113 ℃ - closed cup
个人防护装备Eyeshields, Gloves, type ABEK (EN14387) respirator filter
319046FluorochemBenzyl 2-bromoacetate97%220元/25g;   594元/100g;   1144元/250g;   展开

基本信息

CAS Number5437-45-6
MDL NumberMFCD00000190

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
CAS号首数字顺序排列: 1 2 3 4 5 6 7 8 9