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CAS: 54010-75-2
分子式: ZnC2F6O6S2
分子量: 363.51
熔点: 300℃
中文名称: 
三氟甲烷磺酸锌
英文名称: 
trifluoro-methanesulfonic aci zinc salt
zinc trifluoromethanesulfonate
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T708513MACKLIN三氟甲烷磺酸锌电解液0.25M Zn(CF3SO3)2 in Acrylonitrile520元/25ml;   1488元/100ml;   展开
储存:2-8°C
T708516MACKLIN三氟甲烷磺酸锌电解液1M Zn(CF3SO3)2 in H2O788元/25ml;   展开
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Z768886MACKLIN三氟甲烷磺酸锌(II)≥99%(T), 电解质用120元/1g;   360元/5g;   1090元/25g;   展开
储存:2~8°C, 惰性气体
状态:白色到几乎白色粉末到晶体
Z820658MACKLIN三氟甲烷磺酸锌98%28元/1g;   37元/5g;   82元/25g;   280元/100g;   1380元/500g;   6808元/2.5kg;   展开
储存:2~8°C, inert gas
状态:白色到灰白色粉末
T1294TCIZinc(II) Trifluoromethanesulfonate>98.0%(T)330元/5G;   1050元/25G;   展开

基本信息

纯度/分析方法>98.0%(T)
分子式/分子量C2F6O6S2Zn = 363.51
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (吸湿)
Reaxys-RN4028195
PubChem物质ID87577065
MDL编号MFCD00013229

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(Chelometric Titration)min. 98.0 %

物性(参考值)

熔点527 ℃
水溶性可溶

安全信息

图形或危害标志
信号词危险
危险性说明H314 : 造成严重皮肤灼伤和眼损伤。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P260 : 不要吸入粉尘或烟雾。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽:漱口。不要诱导呕吐。
P363 : 沾染的衣服清洗后方可重新使用。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P405 : 存放处须加锁。

运输信息

UN编号UN1759
类别8
包装类别 III
监管条件代码(*)
147935J&KZinc trifluoromethanesulfonate97.5%301元/10G;   1202元/50G;   展开

基本信息

分子式C2F6O6S2Zn
分子量363.53
MDL编码MFCD00013229
EINECS 编号258-922-6
存储条件Corrosives

安全信息

图形或危害标志
提示语Danger
危险说明H314
H318
防范说明P280
P301+P330+P331
P305+P351+P338
P310
UN号码3261
危险分类8
包装等级III
WGK3
TSCA
30-4000StremZinc trifluoromethanesulfonatemin. 98%375元/5g;   1308元/25g;   展开

Technical Notes:

1.Catalyst for the addition of acetylenes to carbonyls and nitrones.

2. Claisen rearrangement.

3.Catalyst for the enantioselective Henry and Aza-Henry reactions .

4.Pd-catalyzed hydroalkylation of styrenes with zinc reagents .

References:

1. Acc. Chem. Res., 2000, 33, 373.

2.J. Am. Chem. Soc., 2001, 123, 9472. 3.J. Am. Chem. Soc., 2002, 124, 13646 4. Angew. Chem. Int. Ed., 2005, 44, 3881.

5.Angew. Chem. Int. Ed., 2006, 45, 11 7.

6.J. Am. Chem. Soc., 2009, 131, 1 8042.

L15969Alfa AesarZinc trifluoromethanesulfonate98%453元/5g;   1555元/25g;   展开

应用
Zinc trifluoromethanesulfonate acts as a catalyst for the preparation of dithioketals. It is used as a Lewis acid catalyst in silylation reactions. It is also used as a catalyst for greener amine synthesis by reductive amination with hydrogen gas.

备注
Hygroscopic. Incompatible with strong oxidizing agents and acids.

基本信息

MDL
MFCD00013229

EINECS
258-922-6

分子式
C2F6O6S2Zn

分子量
363.51

熔点
>300°

灵敏度
Hygroscopic. Store under Nitrogen. Ambient temperatures.

形态
Powder

溶解性
Soluble in water and acetonitrile. Slightly soluble in methanol. Insoluble in dichloromethane.

Beilstein
4028195

GHS危害和防范说明

GHS符号

Hazard Statements
H314-H318
Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
III

危险类别
34
Causes burns.

安全等级
20-26-36/37/39-45-60
When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA

C31709Alfa AesarZinc trifluoromethanesulfonate98%913元/10g;   2734元/50g;   展开

基本信息

Ref#
31709

MDL
13229

分子式
C2 F6 O6 S2 Zn

分子量
363.51

形态
White powder

安全信息

危险等级
8

包装组
III

290068Sigma-AldrichZinc trifluoromethanesulfonate98%830.67元/10 G;   3495.68元/50 G;   展开

产品说明

一般描述

我们致力于为您提供更环保的替代产品,以符合“绿色化学的12项原则”的一项或多项原则要求。该产品为增强型,提高了催化效率。点击此处了解更多详情。

包装

10, 50 g in glass bottle

基本信息

线性分子式(CF3SO3)2Zn
分子量363.53
Beilstein4028195
EC 号258-922-6
MDL编号MFCD00013229
PubChem化学物质编号24857423
NACRESNA.22

产品性质

质量水平200
测定98%
reaction suitabilitycore: zinc
reagent type: catalyst
环保替代产品特性Catalysis
Learn more about the Principles of Green Chemistry.
mp≥300 ℃ (lit.)
环保替代产品分类Aligned
SMILES string[Zn++].[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F
InChI1S/2CHF3O3S.Zn/c2*2-1(3,4)8(5,6)7;/h2*(H,5,6,7);/q;;+2/p-2
InChI keyCITILBVTAYEWKR-UHFFFAOYSA-L

安全信息

储存分类代码8A - Combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
013959FluorochemZinc trifluoromethanesulfonate98%396元/5g;   1034元/25g;   2200元/100g;   展开

基本信息

CAS Number54010-75-2
MDL NumberMFCD00013229
Melting Point>300℃

安全信息

图形或危害标志
危险性说明 H314: Causes severe skin burns and eye damage.
防范说明 P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P280: Wear .
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P363: Wash contaminated clothing before reuse.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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