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CAS: 5331-43-1
分子式: C8H10N2O2
分子量: 166.17
熔点: 67-70℃
中文名称: 
肼基甲酸苄酯
苄基肼基甲酸酯
肼羧酸苯甲酯
英文名称: 
benzyl hydrazinocarboxylate
benzyloxycarbonyl hydrazide
carbazic acid, benzyl ester
carbobenzoxyhydrazide
phenymethyl hydrazinecarboxylate
carbazic acid benzyl ester
Hydrazinecarboxylic acid,phenylmethyl ester
(Benzyloxycarbonyl)hydrazine
Benzyloxycarbonylhydrazine
Carbobenzoxyhydrazine
N-Cbz-hydrazine
Hydrazinecarboxylic acid, phenylmethyl ester
hydrazinecarboxylic acid, phenymethyl ester
((benzyloxy)carbonyl)hydrazine
benzyl carbazate
展开更多英文名
推荐供应商
货号品牌产品名称规格包装、参考价格详情
B802366MACKLIN肼甲酸苄酯98%29元/5g;   36元/25g;   89元/100g;   380元/500g;   1846元/2.5kg;   5430元/10kg;   展开
储存:室温
状态:白色到灰白色粉末
C1564TCIBenzyl Carbazate>98.0%(T)90元/5G;   290元/25G;   展开

基本信息

纯度/分析方法>98.0%(T)
分子式/分子量C8H10N2O2 = 166.18
外观与形状(20℃)固体
Reaxys-RN1952982
PubChem物质ID87566561
MDL编号MFCD00041890

技术规格

AppearanceWhite to Orange to Green powder to crystal
Purity(Bromination Method)min. 98.0 %
Melting point66.0 to 71.0 ℃

物性(参考值)

熔点69 ℃

安全信息

图形或危害标志
信号词危险
危险性说明H315 : 造成皮肤刺激。
H318 : 造成严重眼损伤。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。

相关法规

RTECS#MV1724950
171375J&KBenzyl Carbazate98%108元/5G;   236元/25G;   展开

基本信息

分子式C8H10N2O2
分子量166.18
熔点65-68
闪点110
MDL编码MFCD00041890
Beilstein1952982
EINECS 编号226-230-3

安全信息

图形或危害标志
提示语Danger
危险说明H318
防范说明P280
P305+P351+P338
WGK3
RTECSMV1724950
TSCA
A13005Alfa AesarBenzyl Carbazate98+%1217元/5g;   2214元/25g;   16884元/100g;   展开

应用
Benzyl carbazate is used as a reagent for preparation of benzyloxycarbonyl (Z, Cbz) hydrazides of carboxylic acids, particularly N-protected amino acids. Subsequent hydrogenolysis gives the hydrazide which can be converted to the azide for coupling with a further amino acid residue by the azide method. It is also used in the preparation of simple acyl or sulfonyl hydrazides avoiding diacylation.

备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Handle under inert gas. Protect from moisture. Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00041890

EINECS
226-230-3

分子式
C8H10N2O2

分子量
166.18

熔点
66-70°

灵敏度
Ambient temperatures.

形态
Crystalline

溶解性
Soluble in water (slightly), methanol and DMSO.

Beilstein
1952982

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H318-H335
Causes skin irritation.Causes serious eye damage.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
37/38-41
Irritating to respiratory system and skin.Risk of serious damage to eyes.

安全等级
26-37/39
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable gloves and eye/face protection.

RTECS
MV1724950

TSCA

499781Sigma-AldrichBenzyl Carbazate97%159.24元/5 G;   710.16元/25 G;   展开

基本信息

线性分子式H2NNHCO2CH2C6H5
分子量166.18
Beilstein1952982
EC 号226-230-3
MDL编号MFCD00041890
PubChem化学物质编号24873300
NACRESNA.22

产品性质

质量水平100
测定97%
mp65-68 ℃ (lit.)
application(s)peptide synthesis
SMILES stringNNC(=O)OCc1ccccc1
InChI1S/C8H10N2O2/c9-10-8(11)12-6-7-4-2-1-3-5-7/h1-5H,6,9H2,(H,10,11)
InChI keyRXUBZLMIGSAPEJ-UHFFFAOYSA-N

安全信息

象形图GHS05
警示用语:Danger
危险声明H318
预防措施声明P280 - P305 + P351 + P338
危险分类Eye Dam. 1
储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)230.0 °F - closed cup
闪点(C)110 ℃ - closed cup
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
018210FluorochemBenzyl Carbazate98%242元/1g;   330元/25g;   792元/100g;   3014元/500g;   展开

基本信息

CAS Number5331-43-1
MDL NumberMFCD00041890
Melting Point67-70

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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