CAS 502-44-3; EPSILON-己内酯; -Caprolactone

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货号

品牌

产品名称

规格

包装、参考价格

C743022

MACKLIN

ε-己内酯

Standard for GC, ≥99.9%(GC)

58元/5g;

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储存：室温
状态：液体

C805072

MACKLIN

ε-己内酯

99%

48元/100g; 136元/500g; 529元/2.5kg; 1888元/10kg; 1588元/12X500g;

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储存：室温
状态：无色到浅黄色液体
折射率：n20/D 1.463(lit.)

C0702

TCI

ε-Caprolactone

>99.0%(GC)

145元/25ML; 530元/500ML;

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基本信息

纯度/分析方法	>99.0%(GC)
分子式/分子量	C₆H₁₀O₂ = 114.14
外观与形状(20℃)	液体
Reaxys-RN	106919
PubChem物质ID	87565787
SDBS (AIST Spectral DB)	1940
MDL编号	MFCD00003267

技术规格

Appearance	Colorless to Light yellow to Light orange clear liquid
Purity(GC)	min. 99.0 %
Solubility in EtOH	almost transparency

物性(参考值)

熔点	-1 ℃
沸点	140 ℃/35 mmHg
闪点	115 ℃
比重	1.08
折射率	1.46
水溶性	完全混溶
溶解性(可与之混溶)	丙酮
溶解性(可溶于)	乙醇

安全信息

图形或危害标志
信号词	危险
危险性说明	H303 : 吞咽可能有害。 H315 : 造成皮肤刺激。 H318 : 造成严重眼损伤。
防范说明	P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/戴防护眼罩/戴防护面具。 P302 + P352 : 如皮肤沾染：用水充分清洗。 P312 : 如感觉不适，呼叫急救中心/医生。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P332 + P313 : 如发生皮肤刺激：求医/就诊。 P305 + P351 + P338 + P310 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。

相关法规

RTECS#

MO8400000

442127

J&K

ε-Caprolactone monomer

99%

81元/250G; 292元/1KG; 729元/2.5KG;

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基本信息

分子式	C₆H₁₀O₂
分子量	114.14
熔点	-1
沸点	235
闪点	109
密度	1.03
折光率(n20D)	1.4620-1.4640
MDL编码	MFCD00003267
Beilstein	106919
EINECS 编号	207-938-1

安全信息

图形或危害标志
提示语	Warning
危险说明	H315 H319
防范说明	P280 P302+P352 P305+P351+P338
WGK	2
RTECS	MO8400000
TSCA	是

A10299

Alfa Aesar

epsilon-Caprolactone

99%

302元/100g; 631元/500g; 2448元/2500g; 7308元/10000g;

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应用
ε-Caprolactone is widely used as a monomer in the manufacturing of highly specialized polymers. It is mainly utilized as a precursor to caprolactam. It finds an application in the synthesis of polyglecaprone, which is used as a suture material in surgery.

备注
Keep the container tightly closed in a dry and well-ventilated place. Combustible liquid.

基本信息

MDL
MFCD00003267

EINECS
207-938-1

分子式
C₆H₁₀O₂

分子量
114.14

熔点
-2°

沸点
235-236°

闪点
109°(228°F)

密度
1.078

折射率
1.4630

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Miscible with water and most organic solvents.

Beilstein
106919

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H318-H335
Causes skin irritation.Causes serious eye damage.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
37/38-41
Irritating to respiratory system and skin.Risk of serious damage to eyes.

安全等级
23-26-37/39-60
Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable gloves and eye/face protection.This material and its container must be disposed of as hazardous waste

RTECS
MO8400000

TSCA
是

C17344

Alfa Aesar

epsilon-Caprolactone monomer

99%

823元/250g; 1828元/1kg; 4065元/2.5kg;

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基本信息

Ref#
17344

MDL
3267

分子式
C6 H10 O2

分子量
114.14

闪点
109

密度
1.03

形态
Colorless liquid

704067

Sigma-Aldrich

ε-Caprolactone

97%

559.1元/100 G; 1833.91元/500 G;

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产品说明

一般描述

ε-己内酯是一种环状酯。由丁醇三丁基锡、乙基镁化溴，或乙酸钐或杂多酸诱发的己内酯开环聚合会形成聚己内酯(PCL)。

应用

ε-己内酯通常用于制备聚己内酯(PCL)。

包装

100, 500 g in poly bottle

基本信息

经验(实验)分子式	C₆H₁₀O₂
分子量	114.14
Beilstein	106919
EC 号	207-938-1
MDL编号	MFCD00003267
PubChem化学物质编号	329762090
NACRES	NA.23

产品性质

质量水平	200
蒸汽密度	3.9 (vs air)
蒸汽压	0.01 mmHg ( 20 ℃)
测定	97%
形式	liquid
折射率	n20/D 1.463 (lit.)
bp	97-98 ℃/15 mmHg (lit.)
密度	1.03 g/mL at 25 ℃ (lit.)
SMILES string	O=C1CCCCCO1
InChI	1S/C6H10O2/c7-6-4-2-1-3-5-8-6/h1-5H2
InChI key	PAPBSGBWRJIAAV-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H319
预防措施声明	P264 - P280 - P305 + P351 + P338 - P337 + P313
危险分类	Eye Irrit. 2
储存分类代码	10 - Combustible liquids
WGK	WGK 1
闪点(F)	228.2 °F - closed cup
闪点(C)	109 ℃ - closed cup
个人防护装备	Eyeshields, Gloves, type ABEK (EN14387) respirator filter

8.02801

Sigma-Aldrich

ε-Caprolactone

for synthesis

521.83元/250 ML;

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产品说明

分析说明

Assay (GC, area%): ≥ 98.0 % (a/a)
Density (d 20 °C/ 4 °C): 1.075 - 1.076
Water (K. F.): ≤ 0.10 %
Identity (IR): passes test

基本信息

经验(实验)分子式	C₆H₁₀O₂
分子量	114.14
MDL编号	MFCD00003267
EC索引号	207-938-1

产品性质

质量水平	200
蒸汽压	0.013 hPa ( 20 ℃)
测定	≥98.0% (GC)
自燃温度	204 ℃
效能	>2000 mg/kg LD₅₀, oral (Rat) 5990 mg/kg LD₅₀, skin (Rabbit)
expl. lim.	1.2-9 % (v/v)
bp	235 ℃/1013 hPa
mp	-1.5 ℃
转变温度	flash point 127 ℃
密度	1.07 g/cm³ at 20 ℃
储存温度	2-30℃
InChI	1S/C6H10O2/c7-6-4-2-1-3-5-8-6/h1-5H2
InChI key	PAPBSGBWRJIAAV-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H319
预防措施声明	P264 - P280 - P305 + P351 + P338 - P337 + P313
危险分类	Eye Irrit. 2
储存分类代码	10 - Combustible liquids
WGK	WGK 1
闪点(F)	228.2 °F - closed cup
闪点(C)	109 ℃ - closed cup

094875

Fluorochem

e-Caprolactone

99%

264元/25g; 396元/100g; 1210元/500g;

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基本信息

CAS Number	502-44-3
MDL Number	MFCD00003267
Boiling Point	97-98℃
Density	1.078

安全信息

图形或危害标志
危险性说明	H315: Causes skin irritation. H318: Causes serious eye damage. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing . P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310: Immediately call a POISON CENTER or doctor/physician. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see relevant procedures. on this label). P332 + P313: If skin irritation occurs: Get medical advice/ attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to in accordance with local regulation .