CAS 500997-69-3; n-di[(r)-1-phenylethyl]-[(r)-1,1′-spirobiindane-7,7′-diyl]-phosphoramidite; (r)-siphos-pe

CAS:

500997-69-3

分子式:

C₃₃H₃₂NO₂P

分子量:

505.6

沸点:

617.8±65.0 °C

中文名称:

n-di[(r)-1-phenylethyl]-[(r)-1,1′-spirobiindane-7,7′-diyl]-phosphoramidite

(11ar)-(+)-10,11,12,13-tetrahydrodiindeno[7,1-de:1′, 7′-fg][1,3,2]dioxaphosphocin-5-bis[(r)-1-phenylethyl]amine

(11ar)-(+)-10,11,12,13-四氢茚并[7,1-de:1′, 7′-fg][1,3,2]二氧磷-5-双[(r)-1-苯乙基]胺

n-二[(r)-1-苯乙基]-[(r)-1,1′-螺二氢茚-7,7′-二基]亚磷酰胺

英文名称:

(r)-siphos-pe

推荐供应商

货号	品牌	产品名称	规格	包装、参考价格	详情
R853904	MACKLIN	(11aR)-10,11,12,13-Tetrahydro-N,N-bis[(1R)-1-phenylethyl]-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine	≥98%,≥99% e.e.	252元/25mg; 702元/100mg; 1030元/250mg;	展开
储存：室温,干燥状态：固体
15-5162	Strem	(11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine	min. 98%	2055元/100mg; 8205元/500mg;	展开
Technical Notes: 1. Chiral ligands for coppe r-catalyzed asymmetric allylic alkylation with dialkylzincs . 2. Chiral ligands for copper-catalyzed asymmetric conjugate addition of diethylzinc to enones. 3. Chiral ligands for palladium- catalyzed asymmetric hydrosilylation of sty 4. Chiral ligands for copper catalyzed asymmetric ring-opening of oxabicyclic alkenes with Grignard re agents. 5. Chiral ligands for nickel-catalyzed asymmetric hydrovinylation of a-alkyI vinylarenes. 6. Chiral ligands for iridium-catalyzed asymmetric hydrogenation of cyclic enamines. 7.Chiral ligands for iridium-catalyzed asymmetric hydrogenation of cyclic imines . 8. Chiral ligands for gold-catalyzed asymmetric 2 + 2 cycloaddition reaction. 9. Chiral ligands for rhodium-catalyzed asymmetric hydroacylation of salicylaldehydes to homoallylic sulfides. 10. Chiral ligands for palladium-catalyzed asymmetric carboamination reactions.