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CAS: 50-79-3
分子式: C7H4Cl2O2
分子量: 191.01
沸点: 301 °C(lit.)
熔点: 151-154 °C(lit.)
中文名称: 
2,5-二氯苯甲酸
英文名称: 
2,5-dichlorobenzoicacid
2,5-dichlorobenzoic acid
2,5-dichloro-benzoic aci
性质描述: 针状结晶体。熔点154℃,沸点301℃。溶于乙醇和乙醚,可溶于热水。在蒸气中有部分挥发。
生产方法: 1.光气法 由对二氯苯与光气反应得2,5-二氯苯甲酰氯,再经水解而得。2.氯甲基化法由对二氯苯与多聚甲醛作用,再经高锰酸钾氧化而得。对二氯苯的氯甲基化收率为53.4%,第三步氧化反应的收率为83%。3.三氯苯法以1,2,4-三氯苯为原料,制成2,5-二氯苯腈后再经碱解而得。4.苯甲酰氯法由苯甲酰氯经氯化、水解而得。苯甲酰氯的氯化温度控制在35-45℃之间,得到的氯化物主要成分为2,5-二氯苯甲酰氯(含量65%),再在存在浓硫酸的条件下,于40-50℃水解。5.对二氯苯四氯化碳法。
用途: 作有机合成中间体。用于合成除草剂豆科威、地草平等,该农药药害少,不受雨天影响。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
D806372MACKLIN2,5-二氯苯甲酸97%31元/10g;   47元/50g;   179元/250g;   679元/1kg;   1665元/2.5kg;   展开
储存:室温
状态:白色粉末或晶体
D0338TCI2,5-Dichlorobenzoic Acid>98.0%(GC)(T)100元/25G;   390元/100G;   展开

基本信息

纯度/分析方法>98.0%(GC)(T)
分子式/分子量C7H4Cl2O2 = 191.01
外观与形状(20℃)固体
Reaxys-RN973353
PubChem物质ID87567029
SDBS (AIST Spectral DB)5591
MDL编号MFCD00002416

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(GC)min. 98.0 %
Purity(Neutralization titration)min. 98.0 %
Melting point152.0 to 156.0 ℃

物性(参考值)

熔点154 ℃

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。

相关法规

RTECS#DG6825000
210617J&K2,5-Dichlorobenzoic Acid99%89元/5G;   139元/25G;   357元/100G;   展开

基本信息

分子式C7H4Cl2O2
分子量191.01
熔点151-154
沸点301
MDL编码MFCD00002416
Beilstein973353
EINECS 编号200-065-7

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
RTECSDG6825000
TSCA
C16324Alfa Aesar2,5-Dichlorobenzoic Acid97%530元/10g;   1262元/50g;   5336元/250g;   展开

基本信息

Ref#
16324

MDL
2416

分子式
C7 H4 Cl2 O2

分子量
191.01

144940Sigma-Aldrich2,5-Dichlorobenzoic Acid97%622.79元/50 G;   2839.44元/250 G;   展开

产品说明

一般描述

2,5-Dichlorobenzoic acid is converted to 4-chlorocatechol by Pseudomonas sp. CPE2 strain.

应用

2,5-Dichlorobenzoic acid was used as calibration standard to investigate the gas-phase OH reaction products of biphenyl, monochlorobiphenyl and dichlorophenyl.

包装

50, 250 g in poly bottle

基本信息

线性分子式Cl2C6H3CO2H
分子量191.01
Beilstein973353
EC 号200-065-7
MDL编号MFCD00002416
PubChem化学物质编号24848693
NACRESNA.22

产品性质

质量水平100
测定97%
bp301 ℃ (lit.)
mp151-154 ℃ (lit.)
SMILES stringOC(=O)c1cc(Cl)ccc1Cl
InChI1S/C7H4Cl2O2/c8-4-1-2-6(9)5(3-4)7(10)11/h1-3H,(H,10,11)
InChI keyQVTQYSFCFOGITD-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
127100Fluorochem2,5-Dichlorobenzoic Acid98%220元/1g;   308元/25g;   660元/100g;   5324元/1kg;   展开

基本信息

CAS Number50-79-3
MDL NumberMFCD00002416
Melting Point154-157℃

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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