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CAS: 49761-82-2
分子式: C8H12N2O2
分子量: 168.19
沸点: 147-150 ℃(lit.)
熔点: 45-47 ℃(lit.)
中文名称: 
N-Boc-咪唑
英文名称: 
1-(tert-Butoxycarbonyl)imidazole
N-Boc-imidazole
N-(tert-Butoxycarbonyl)imidazole
N-tert-Butoxycarbonylimidazole
Boc-imidazole
推荐供应商
货号品牌产品名称规格包装、参考价格详情
N820232MACKLIN1-叔丁氧羰基咪唑98%22元/5g;   60元/25g;   234元/100g;   1156元/500g;   展开
储存:室温
状态:白色粉末或固体
B0916TCIN-tert-Butoxycarbonylimidazole>98.0%(T)620元/10G;   展开

基本信息

纯度/分析方法>98.0%(T)
分子式/分子量C8H12N2O2 = 168.20
外观与形状(20℃)固体
Reaxys-RN607792
PubChem物质ID87563880
MDL编号MFCD00014497

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(GC)min. 97.0 %
Purity(Nonaqueous Titration)min. 98.0 %
Melting point45.0 to 49.0 ℃
Solubility in Toluenealmost transparency

物性(参考值)

熔点46 ℃
沸点64 ℃/1 mmHg

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
L00506Alfa Aesar1-Boc-imidazole98%459元/5g;   1512元/25g;   展开

应用
1-Boc-imidazole is used in the preparation of water soluble polyrotaxane, via modification of α-cyclodextrin in the presence of KOH and N,N?-carbonyldiimidazole.

备注
Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

基本信息

MDL
MFCD00014497

EINECS
256-475-1

分子式
C8H12N2O2

分子量
168.20

熔点
44-48°

灵敏度
Keep Cold.

溶解性
Soluble in hexane, acetone, and DMF.

Beilstein
607792

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA

424013Sigma-Aldrich1-(tert-Butoxycarbonyl)imidazole97%813.6元/10 G;   展开

产品说明

一般描述

1-(tert-butoxycarbonyl)imidazole is an imidazole derivative. Its gas-phase elimination kinetics study has been studied both theoretically and experimentally.

应用

1-(tert-butoxycarbonyl)imidazole was used in the preparation of water soluble polyrotaxane, via modification of α-cyclodextrin in the presence of KOH and N,N′-carbonyldiimidazole.

包装

10 g in glass bottle

基本信息

经验(实验)分子式C8H12N2O2
分子量168.19
EC 号256-475-1
MDL编号MFCD00014497
PubChem化学物质编号24866546
NACRESNA.22

产品性质

测定97%
bp147-150 ℃ (lit.)
mp45-47 ℃ (lit.)
SMILES stringCC(C)(C)OC(=O)n1ccnc1
InChI1S/C8H12N2O2/c1-8(2,3)12-7(11)10-5-4-9-6-10/h4-6H,1-3H3
InChI keyMTBKGWHHOBJMHJ-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)235.4 °F - closed cup
闪点(C)113 ℃ - closed cup
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
916038Amethyst1-(tert-Butoxycarbonyl)imidazole98%, 用于合成58元/5G;   156元/25G;   509元/100G;   展开

基本信息

分子式C8H12N2O2
分子量168.19
熔点45-47
沸点147-150
闪点113
MDL编码MFCD00014497
Beilstein607792
EINECS 编号256-475-1

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
TSCA
339964Fluorochemtert-Butyl 1H-imidazole-1-carboxylate98%220元/10g;   220元/1g;   374元/25g;   1210元/100g;   展开

基本信息

CAS Number49761-82-2
MDL NumberMFCD00014497
Melting Point45-47℃

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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