[登录] [免费注册]
试剂仪器网
位置:首页 > 资料中心 > 化工字典 > 479-59-4
关键词:       仅模糊查询
CAS: 479-59-4
分子式: C12H15N
分子量: 173.26
沸点: 280°C(lit.)
熔点: 37°C
中文名称: 
久洛尼定
英文名称: 
Julolidine
2,3,6,7-Tetrahydro-1H,5H-benzo[ij]puinolizine
5h-benzo[ij]quinolizine, 2,3,6,7-tetrahydro-1
性质描述: 白色晶体。熔点34-36℃(97%商品)。其溴氢酸盐([83647-41-7])的熔点239-242℃。
生产方法: 66.5g(0.5mol)四氢喹啉和400g1-溴-3-氯丙烷在150-160℃油浴中加热20h,冷却后加入50ml浓盐酸和500ml水,进行水蒸气蒸馏,除去过量的1-溴-3-氯丙烷。用40%氢氧化钠将剩余物调至碱性,用乙醚提取。乙醚提取液用水洗涤,经粒状氢氧化钠干燥,蒸除乙醚,减压蒸馏,收集105-110℃(0.133kPa)馏分,得67-70g久洛尼定。
用途: 用于有机合成。
推荐供应商
货号品牌产品名称规格包装、参考价格
J861974MACKLIN久洛尼定≥97%(GC)(T)30元/1g;   127元/5g;   605元/25g;   1888元/100g;   咨询
储存:2-8°C,惰性气体存储
状态:黄色到橙色到红棕色粉末或固体
J0007TCIJulolidine>97.0%(GC)(T)795元/5G;   3190元/25G;   咨询

基本信息

纯度/分析方法>97.0%(GC)(T)
分子式/分子量C12H15N = 173.26
外观与形状(20℃)固体
储存温度0-10℃
储存在惰性气体下存放于惰性气体之中
应避免的情况光,空气,加热
Reaxys-RN139925
PubChem物质ID87558509

技术规格

AppearanceWhite or Colorless to Yellow to Orange powder to lump to clear liquid
Purity(GC)min. 97.0 %
Purity(Nonaqueous Titration)min. 97.0 %
Melting point35.0 to 39.0 ℃

物性(参考值)

熔点37 ℃
沸点280 ℃
溶解性(可溶于)甲苯

安全信息

图形或危害标志
信号词警告
危险性说明H341 : 怀疑可造成遗传性缺陷。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P202 : 在阅读并明了所有安全措施前切勿搬动。
P201 : 使用前取得专用说明。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P308 + P313 : 如接触到或有疑虑:求医/就诊。
P405 : 存放处须加锁。
186458J&KJulolidine98%656元/5G;   2527元/25G;   咨询

基本信息

分子式C12H15N
分子量173.26
熔点34-36
沸点280
闪点113
MDL编码MFCD00006917
Beilstein139925
EINECS 编号207-535-0
存储条件Store at 2-8℃

安全信息

防范说明P262
WGK3
TSCA
B22976Alfa AesarJulolidine98%725元/1g;   1802元/5g;   6434元/25g;   咨询

应用
Julolidine used as amine building block and in chemoluminescent dye. Also used in photoconductive materials, chemiluminescence substances, chromogenic substrates in analytical redox reactions, dye intermediates, potential antidepressants and tranquilizers, nonlinear optical materials, high sensitivity photopolymerizable materials, and for improving color stability in photography.

备注
Air sensitive. Store away from air, oxidizing agents, carbon dioxide. Store under dry inert gas.

基本信息

MDL
MFCD00006917

EINECS
207-535-0

分子式
C12H15N

分子量
173.26

熔点
32-37°

沸点
170-173°/31mm

闪点
>110°(230°F)

灵敏度
Keep Cold. Air Sensitive. Store under Argon.

形态
Solid

溶解性
Soluble in toluene. Insoluble in water.

Beilstein
139925

安全信息

TSCA

J1001Sigma-AldrichJulolidine97%885.86元/5 G;   咨询

基本信息

经验(实验)分子式C12H15N
分子量173.25
EC 号207-535-0
MDL编号MFCD00006917
PubChem化学物质编号24896190
NACRESNA.23

产品性质

质量水平100
测定97%
mp34-36 ℃ (lit.)
储存温度2-8℃
SMILES stringC1CN2CCCc3cccc(C1)c23
InChI1S/C12H15N/c1-4-10-6-2-8-13-9-3-7-11(5-1)12(10)13/h1,4-5H,2-3,6-9H2
InChI keyDZFWNZJKBJOGFQ-UHFFFAOYSA-N

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)235.4 °F - closed cup
闪点(C)113 ℃ - closed cup
325062Fluorochem1,2,3,5,6,7-Hexahydropyrido[3,2,1-ij]quinoline95%264元/1g;   1012元/5g;   1936元/10g;   4026元/25g;   咨询

基本信息

CAS Number479-59-4
MDL NumberMFCD00006917

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H341: Suspected of causing genetic defects ..
防范说明 P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P281: Use personal protective equipment as required.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313: IF exposed or concerned: Get medical advice/ attention.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
CAS号首数字顺序排列: 1 2 3 4 5 6 7 8 9