CAS 455-13-0; 4-碘三氟甲苯; 4-Iodo-α,α,α-trifluorotoluene

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品牌

产品名称

规格

包装、参考价格

I812152

MACKLIN

4-碘三氟甲苯

98%

27元/1g; 30元/5g; 67元/25g; 241元/100g; 1068元/500g;

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储存：室温,避光
状态：无色到橙色到棕色液体到固体
折射率：n20/D 1.516(lit.)

I0550

TCI

4-Iodobenzotrifluoride (stabilized with Copper chip)

>97.0%(GC)

730元/5G; 1775元/25G;

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基本信息

纯度/分析方法	>97.0%(GC)
分子式/分子量	C₇H₄F₃I = 272.01
外观与形状(20℃)	液体
应避免的情况	光
Reaxys-RN	1944013
PubChem物质ID	87571896
SDBS (AIST Spectral DB)	41187
MDL编号	MFCD00039398

技术规格

Appearance	Colorless to Yellow to Orange clear liquid
Purity(GC)	min. 97.0 %

物性(参考值)

沸点	185 ℃
闪点	68 ℃
比重	1.88
折射率	1.52

安全信息

图形或危害标志
信号词	警告
危险性说明	H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。 H227 : 可燃液体。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P210 : 远离热源/火花/明火/热表面。禁止吸烟。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/戴防护眼罩/戴防护面具。 P302 + P352 : 如皮肤沾染：用水充分清洗。 P370 + P378 : 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P332 + P313 : 如发生皮肤刺激：求医/就诊。 P403 + P235 : 存放在通风良好的地方。保持低温。

330887

J&K

4-Iodobenzotrifluoride

98%

66元/1G; 81元/5G; 202元/25G;

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基本信息

分子式	C₇H₄F₃I
分子量	272.00
熔点	22-23
沸点	185-186
闪点	69
密度	1.851
折光率(n20D)	1.5160
MDL编码	MFCD00039398
Beilstein	1944013
EINECS 编号	207-234-4

安全信息

图形或危害标志
提示语	Warning
危险说明	H315 H319 H335
防范说明	P261 P305+P351+P338
WGK	3

A12189

Alfa Aesar

4-Iodobenzotrifluoride

98%

283元/1g; 1125元/5g; 4117元/25g;

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应用
4-Iodobenzotrifluoride may be employed as substrate with electron-deficient aromatic ring, during Mizoroki-Heck reaction with acrylic acid, to afford 4-trifluoromethylcinnnamic acid. It undergoes aminocarbonylation in DMF using phosphoryl chloride to give N,N-dimethyl-(4-trifluoromethyl)benzamide.

备注
Light sensitive. Incompatible with strong oxidizing agents. Store in dark.

基本信息

MDL
MFCD00039398

EINECS
207-234-4

分子式
C₇H₄F₃I

分子量
272.01

熔点
-8°

沸点
68-70°/15mm

闪点
68°(154°F)

密度
1.851

折射率
1.5180

灵敏度
Light Sensitive. Ambient temperatures.

形态
Liquid

溶解性
Insoluble in water.

Beilstein
1944013

GHS危害和防范说明

GHS符号

Hazard Statements
H227-H315-H319-H335
Combustible liquid.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P210e-P261-P280a-P305+P351+P338-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA
是

C30618

Alfa Aesar

4-Iodobenzotrifluoride

97%

570元/1g; 1771元/5g;

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基本信息

Ref#
30618

MDL
39398

分子式
C7 H4 F3 I

分子量
272

闪点
68

密度
1851

365858

Sigma-Aldrich

4-Iodobenzotrifluoride

97%

285.7元/1 G; 808.31元/5 G;

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产品说明

一般描述

在 DMF 中，用磷酰氯将 4-碘苯三氟化物氨基羰基化，得到 N,N -二甲基-(4-三氟甲基)苯甲酰胺。本文研究了对 -对 -取代苯乙炔与对碘苯三氟化物的无铜薗头交叉偶联反应机理。

应用

在与丙烯酸的 Mizoroki-Heck 反应中，4-碘苯并三氟化物可用作具有缺电子芳香环的底物，以得到 4-三氟甲基肉桂酸。

包装

1, 5 g in glass bottle

基本信息

线性分子式	IC₆H₄CF₃
分子量	272.01
EC 号	207-234-4
MDL编号	MFCD00039398
PubChem化学物质编号	24862587
NACRES	NA.22

产品性质

质量水平	100
测定	97%
折射率	n20/D 1.516 (lit.)
bp	185-186 ℃/745 mmHg (lit.)
mp	−8.33 ℃ (lit.)
密度	1.851 g/mL at 25 ℃ (lit.)
SMILES string	FC(F)(F)c1ccc(I)cc1
InChI	1S/C7H4F3I/c8-7(9,10)5-1-3-6(11)4-2-5/h1-4H
InChI key	SKGRFPGOGCHDPC-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	10 - Combustible liquids
WGK	WGK 3
闪点(F)	156.2 °F - closed cup
闪点(C)	69 ℃ - closed cup
个人防护装备	Eyeshields, Gloves, type ABEK (EN14387) respirator filter

001196

Fluorochem

4-Iodobenzotrifluoride

97%

440元/25g; 1276元/100g;

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基本信息

CAS Number	455-13-0
MDL Number	MFCD00039398
Boiling Point	186.3℃/760mm
Melting Point	-8.33℃
Density	1.851

安全信息

图形或危害标志
危险性说明	H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing . P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see relevant procedures. on this label). P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to in accordance with local regulation .