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CAS: 4408-64-4
分子式: C5H9NO4
分子量: 147.13
熔点: 218-221℃
中文名称: 
甲基亚氨二乙酸
英文名称: 
Methylimino diacetic acid
n-methyliminodiacetic acid
Methyliminodiacetic acid
N-(Carboxymethyl)-N-methyl-glycine
性质描述: 白色结晶体。熔点215℃。
生产方法: 氯乙酸钠溶液和甲胺溶液在50℃以下反应,向反应混合加入二水合氯化钡溶液,滤集析出的甲基亚氨二乙酸钡盐。再将钡盐与硫酸作用,分离硫酸钡沉淀。滤液减压浓缩,加入无水甲醇,冷却,过滤,甲醇洗涤,于100℃干燥,得甲基亚氨二乙酸。收率63-71%。
用途: 用于有机合成。
推荐供应商
货号品牌产品名称规格包装、参考价格
N824155MACKLINN-甲基亚氨二乙酸98%30元/5g;   55元/25g;   166元/100g;   648元/500g;   咨询
储存:室温
状态:白色到灰白色粉末或晶体或块状
M2090TCIN-Methyliminodiacetic Acid>98.0%(GC)(T)320元/5G;   815元/25G;   咨询

基本信息

纯度/分析方法>98.0%(GC)(T)
分子式/分子量C5H9NO4 = 147.13
外观与形状(20℃)固体
Reaxys-RN1765449
PubChem物质ID160871207
MDL编号MFCD00004284

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(GC)min. 98.0 %
Purity(Neutralization titration)min. 98.0 %

物性(参考值)

熔点219 ℃(dec.)
水溶性可溶

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
132156J&KN-Methyliminodiacetic Acid99%178元/5G;   616元/25G;   咨询

基本信息

分子式C5H9NO4
分子量147.13
熔点220
MDL编码MFCD00004284
Beilstein1765449
EINECS 编号224-557-6

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
TSCA
L02589Alfa AesarN-Methyliminodiacetic Acid99%613元/5g;   2120元/25g;   咨询

应用
N-Methyliminodiacetic acid is used to prepare bis-(1H-benzoimidazol-2-ylmethyl)-methyl-amine by condensation with benzene-1,2-diamine. It is involved in Suzuki cross-coupling with N-methyliminodiacetic acid (MIDA) boronates. It acts as a reagent utilized for protecting boronic acids and as a chelating agent for various metals.

备注
Incompatible with strong bases.

基本信息

MDL
MFCD00004284

EINECS
224-557-6

分子式
C5H9NO4

分子量
147.13

熔点
ca 220° dec.

灵敏度
Ambient temperatures.

溶解性
Soluble in water. Slightly soluble in dimethyl sulfoxide.

Beilstein
1765449

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA

C12701Alfa AesarN-Methyliminodiacetic Acid99%864元/5g;   3019元/25g;   咨询

基本信息

Ref#
12701

MDL
4284

分子式
C5 H9 N O4

分子量
147.13

M51008Sigma-AldrichMethyliminodiacetic acid99%160.47元/5 G;   444.08元/25 G;   咨询

基本信息

线性分子式CH3N(CH2CO2H)2
分子量147.13
EC 号224-557-6
MDL编号MFCD00004284
PubChem化学物质编号24896977
NACRESNA.22

产品性质

质量水平100
测定99%
mp220 ℃ (dec.) (lit.)
SMILES stringCN(CC(O)=O)CC(O)=O
InChI1S/C5H9NO4/c1-6(2-4(7)8)3-5(9)10/h2-3H2,1H3,(H,7,8)(H,9,10)
InChI keyXWSGEVNYFYKXCP-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
066640Fluorochem[(Carboxymethyl)(methyl)amino]acetic acid97%264元/5g;   440元/25g;   1078元/100g;   咨询

基本信息

CAS Number4408-64-4
MDL NumberMFCD00004284
Melting Point220 ℃

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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