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CAS: 4336-70-3
分子式: C20H17ClNP
分子量: 337.78
熔点: 268-270℃
中文名称: 
(氰甲基)三苯基氯化膦
英文名称: 
cyanomethyltriphenylphosphonium chloride
(cyanomethyl)triphenyl-phosphoniu chloride
(cyanomethyl)triphenylphosphonium chloride
cyanomethyl triphenylphosphonium chloride
推荐供应商
货号品牌产品名称规格包装、参考价格
C821416MACKLIN(氰甲基)三苯基氯化膦98%29元/5g;   52元/25g;   204元/100g;   1015元/500g;   咨询
储存:室温
状态:灰白色晶体粉末
C1739TCI(Cyanomethyl)triphenylphosphonium Chloride>98.0%(T)(HPLC)450元/25G;   1540元/100G;   咨询

基本信息

纯度/分析方法>98.0%(T)(HPLC)
分子式/分子量C20H17ClNP = 337.79
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (吸湿)
Reaxys-RN3800456
PubChem物质ID87566706
MDL编号MFCD00031672

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(HPLC)min. 98.0 area%
Purity(Nonaqueous Titration)min. 98.0 %
Solubility in Watervery faint turbidity

物性(参考值)

水溶性可溶
溶解性(可溶于)甲醇

安全信息

图形或危害标志
信号词危险
危险性说明H301 : 吞咽会中毒。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P310 + P330 : 如误吞咽:立即呼叫急救中心/医生。漱口。
P405 : 存放处须加锁。

相关法规

RTECS#TA2075000

运输信息

UN编号UN3439
类别6.1
包装类别 III
监管条件代码(*)
162211J&K(Cyanomethyl)triphenylphosphonium Chloride98%186元/5G;   623元/25G;   2264元/100G;   咨询

基本信息

分子式C20H17ClNP
分子量337.78
熔点275
MDL编码MFCD00031672
Beilstein6222047
EINECS 编号224-383-0

安全信息

图形或危害标志
提示语Warning
危险说明H302
H312
H315
H319
H332
H335
防范说明P261
P280
P305+P351+P338
WGK3
RTECSTA2075000
TSCA
A13096Alfa Aesar(Cyanomethyl)triphenylphosphonium Chloride98+%559元/5g;   1773元/25g;   6627元/100g;   26344元/500g;   咨询

基本信息

MDL
MFCD00031672

EINECS
224-383-0

分子式
NCCH2P(C6H5)3Cl

分子量
337.79

熔点
ca 270° dec.

灵敏度
Hygroscopic. Ambient temperatures.

形态
Crystalline powder

Beilstein
6222047

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H312-H331-H315-H319-H335
Harmful if swallowed.Harmful in contact with skin.Toxic if inhaled.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
20/21/22-36/37/38
Harmful by inhalation, in contact with skin and if swallowed.Irritating to eyes, respiratory system and skin.

安全等级
26-36/37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.

欧盟危险品标志

RTECS
TA2075000

TSCA

464937Sigma-Aldrich(Cyanomethyl)triphenylphosphonium Chloride98%1187.48元/25 G;   咨询

产品说明

应用

Reactant involved in:

  • Condenation reactions
  • Wittig reactions
  • Synthesis of phosphonium-iodonium ylides
  • Preparation of α,β-unsaturated esters, amides, and nitriles

包装

25 g in glass bottle

基本信息

线性分子式NCCH2P(C6H5)3Cl
分子量337.78
EC 号224-383-0
MDL编号MFCD00031672
PubChem化学物质编号24870234
NACRESNA.22

产品性质

质量水平100
测定98%
reaction suitabilityreaction type: C-C Bond Formation
mp275 ℃ (dec.) (lit.)
SMILES string[Cl-].N#CC[P+](c1ccccc1)(c2ccccc2)c3ccccc3
InChI1S/C20H17NP.ClH/c21-16-17-22(18-10-4-1-5-11-18,19-12-6-2-7-13-19)20-14-8-3-9-15-20;/h1-15H,17H2;1H/q+1;/p-1
InChI keyARPLQAMUUDIHIT-UHFFFAOYSA-M

安全信息

储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
003709FluorochemCyanomethyl triphenylphosphonium chloride95%286元/10g;   572元/25g;   1606元/100g;   咨询

基本信息

CAS Number4336-70-3
MDL NumberMFCD00031672
Melting Point268-270℃

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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