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CAS: 433-06-7
分子式: C9H9F3O2S
分子量: 238.23
沸点: 87-92°C/0.1mm Hg (Lit.)
熔点: 36-38°C (Lit.)
中文名称: 
2,2,2-三氟乙基对甲苯磺酸酯
英文名称: 
2,2,2-trifluoroethyl tosylate
2,2,2-Trifluoroethyl p-toluenesulfonate
p-Toluenesulfonic acid 2,2,2-trifluoroethyl ester
2,2,2-trifluoro-ethano 4-methylbenzenesulfonate
推荐供应商
货号品牌产品名称规格包装、参考价格详情
T838162MACKLIN2,2,2-三氟乙基对甲苯磺酸酯99 %25元/5g;   64元/25g;   190元/100g;   830元/500g;   展开
储存:室温,干燥
状态:白色固体
T1516TCI2,2,2-Trifluoroethyl p-Toluenesulfonate>98.0%(GC)(T)455元/25G;   展开

基本信息

纯度/分析方法>98.0%(GC)(T)
分子式/分子量C9H9F3O3S = 254.22
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (分解)
Reaxys-RN2699394
PubChem物质ID87577276
SDBS (AIST Spectral DB)23643
MDL编号MFCD00000443

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(GC)min. 98.0 %
Purity(Ester Value)min. 98.0 %
Melting point38.0 to 42.0 ℃
Solubility in Methanolalmost transparency

物性(参考值)

熔点40 ℃
沸点104 ℃/0.8 mmHg

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
135149J&K2,2,2-Trifluoroethyl p-Toluenesulfonate98%237元/25G;   778元/100G;   3342元/500G;   展开

基本信息

分子式C9H9F3O3S
分子量254.23
熔点36-38
沸点87-92
闪点113
MDL编码MFCD00000443
Beilstein2699394
EINECS 编号207-085-5

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
TSCA
A17871Alfa Aesar2,2,2-Trifluoroethyl p-Toluenesulfonate98+%931元/25g;   3164元/100g;   展开

基本信息

MDL
MFCD00000443

EINECS
207-085-5

分子式
C9H9F3O3S

分子量
254.23

熔点
37-42°

沸点
87-92°/0.1mm

闪点
>110°(230°F)

灵敏度
Moisture Sensitive. Ambient temperatures.

形态
Crystals

Beilstein
2699394

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA

177822Sigma-Aldrich2,2,2-Trifluoroethyl p-toluenesulfonate99%773.65元/50 G;   展开

产品说明

应用

2,2,2-Trifluoroethyl p-toluenesulfonate was used in the synthesis of 1-alkyl-2,2-difluorovinylboranes.

包装

50 g in glass bottle

基本信息

线性分子式CH3C6H4SO3CH2CF3
分子量254.23
EC 号207-085-5
MDL编号MFCD00000443
PubChem化学物质编号24850693
NACRESNA.22

产品性质

质量水平100
测定99%
bp87-92 ℃/0.1 mmHg (lit.)
mp36-38 ℃ (lit.)
SMILES stringCc1ccc(cc1)S(=O)(=O)OCC(F)(F)F
InChI1S/C9H9F3O3S/c1-7-2-4-8(5-3-7)16(13,14)15-6-9(10,11)12/h2-5H,6H2,1H3
InChI keyIGKCQDUYZULGBM-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)235.4 °F - closed cup
闪点(C)113 ℃ - closed cup
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
001538Fluorochem2,2,2-Trifluoroethyl p-Toluenesulfonate97%220元/1g;   242元/25g;   726元/100g;   2750元/500g;   展开

基本信息

CAS Number433-06-7
MDL NumberMFCD00000443
Boiling Point87-92℃
Melting Point37-43℃
Density1

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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