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CAS: 4282-31-9
分子式: C6H4O4S
分子量: 172.16
熔点: 300℃
中文名称: 
噻酚-2,5-二甲酸
噻吩-2,5二羧酸
噻吩-2,5-二羧酸
2,5-噻吩二羧酸
2,5-二羧基噻吩
英文名称: 
2,5-thiophenedicarboxylic acid
Thiophene-2,5-dicarboxylic acid
Thiophene-,'-dicarboxylic acid
性质描述: 结晶性粉末。熔点358.5-359.5℃,在150-300℃升华。微溶于水。
生产方法: 将己二酸、氯化亚砜以1:(6-10)的重量比混合,在催化剂吡啶的存在下回流20-60h。蒸去溶剂,将残留物在140-160℃加热3-7h。经氢氧化钠处理、酸析、过滤、脱色、提纯,得噻吩-2,5-二羧酸。
用途: 该品与邻氨基酚缩合可制得荧光增白剂EBF。这种增白剂可用于锦纶、涤纶、丙纶、氯纶和三乙酸纤维,是一种性能优良的产品。
推荐供应商
货号品牌产品名称规格包装、参考价格
T819148MACKLIN2,5-噻吩二羧酸98%29元/5g;   72元/25g;   138元/100g;   538元/500g;   咨询
储存:室温
状态:白色到灰白色粉末或晶体
T2347TCI2,5-Thiophenedicarboxylic Acid>98.0%(GC)(T)540元/5G;   1530元/25G;   咨询

基本信息

纯度/分析方法>98.0%(GC)(T)
分子式/分子量C6H4O4S = 172.15
外观与形状(20℃)固体
Reaxys-RN136781
PubChem物质ID87558848
MDL编号MFCD00016896

技术规格

AppearanceWhite to Light yellow powder to crystal
Purity(GC)min. 98.0 %
Purity(Neutralization titration)min. 98.0 %
Solubility in Methanolalmost transparency

物性(参考值)

熔点359 ℃

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
260494J&K2,5-Thiophenedicarboxylic Acid98%79元/5G;   162元/25G;   咨询

基本信息

分子式C6H4O4S
分子量172.16
熔点>300
MDL编码MFCD00016896
Beilstein136781
EINECS 编号224-284-2

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
TSCA
L10293Alfa AesarThiophene-2,5-dicarboxylic acid97%448元/1g;   1270元/5g;   2609元/25g;   咨询

应用
Thiophene-2,5-dicarboxylic acid may be used in the synthesis new cobalt(II) thiophenedicarboxylate coordination polymer and novel mesogenic thiophene based supramolecular liquid crystals.

备注
Stable under recommended storage conditions. Store away from oxidizing agents.

基本信息

MDL
MFCD00016896

EINECS
224-284-2

分子式
C6H4O4S

分子量
172.16

熔点
355-360°

灵敏度
Ambient temperatures.

溶解性
Very soluble in water.

Beilstein
136781

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA

405191Sigma-Aldrich2,5-Thiophenedicarboxylic Acid99%228.23元/5 G;   319.48元/25 G;   咨询

产品说明

一般描述

2,5-噻吩二甲酸 (2,5-TDCA,H 2 TDC) 是制备荧光增白剂、杀菌剂和抗癌药物的重要原料。己二酸用氯化亚砜氯化生成。由于其配位方式的多样性,它作为芳香连接物是生成配位网络的极佳选择。用旋转弹燃烧量热法计算了 2,5-噻吩二甲酸的燃烧焓和升华焓。

应用

2,5-噻吩二甲酸可作为噻吩基连接基团用于镁配位网络的制备。也可作为合成 2,5-二苯并恶唑噻吩 (EBF) 的前体。
可用于以下合成:

  • 新型噻吩二甲酸钴配位聚合物
  • 新型介晶噻吩类超分子液晶
  • 两种新型配位聚合物,分子式为 {[Ln2(2,5-tdc)3(dmso)2]H2O}n (Ln = Tb(III) and Dy(III)), (2,5-tdc2 = 2,5-噻吩二甲酸酯和 dmso = 二甲亚砜)

包装

5, 25 g in poly bottle

基本信息

经验(实验)分子式C6H4O4S
分子量172.16
EC 号224-284-2
MDL编号MFCD00016896
PubChem化学物质编号24865298
NACRESNA.22

产品性质

质量水平100
测定99%
mp>300 ℃ (lit.)
SMILES stringOC(=O)c1ccc(s1)C(O)=O
InChI1S/C6H4O4S/c7-5(8)3-1-2-4(11-3)6(9)10/h1-2H,(H,7,8)(H,9,10)
InChI keyYCGAZNXXGKTASZ-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
013724Fluorochem2,5-Thiophenedicarboxylic Acid97%220元/1g;   330元/25g;   638元/100g;   咨询

基本信息

CAS Number4282-31-9
MDL NumberMFCD00016896
Melting Point>300℃

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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