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CAS: 41796-84-3
英文名称: 
difluoromethyl azide solution
azidodifluoromethane
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货号品牌产品名称规格包装、参考价格
CF0038Sigma-AldrichDifluoromethyl azide solution(1.2 M in DME)3368.36元/5 mL;   5522.68元/10 mL;   咨询

产品说明

应用

Difluoromethyl azide dissolved in DME is a conveniently handled form of this rare fluorinated building block, opening a straightforward access to regioisomerically pure N-difluoromethyl triazoles using the conventional copper catalyzed alkyne-azide cycloaddition or the enamine-mediate azide-ketone [3+2] cycloaddition

其他说明

Azidoperfluoroalkanes: Synthesis and Application in Copper(I)-Catalyzed Azide–Alkyne Cycloaddition

Enamine-Mediated Azide-Ketone [3 + 2] Cycloaddition of Azidoperfluoroalkanes

基本信息

线性分子式CHF2N3
MDL编号MFCD24454794

产品性质

形式liquid
浓度 (1.2 M in DME)
SMILES string[N-]=[N+]=NC(F)F

安全信息

象形图GHS02GHS07GHS08
警示用语:Danger
危险声明H225 - H315 - H332 - H360FD
预防措施声明P202 - P210 - P233 - P303 + P361 + P353 - P304 + P340 + P312 - P308 + P313
危险分类Acute Tox. 4 Inhalation - Flam. Liq. 2 - Repr. 1B - Skin Irrit. 2
补充剂危害EUH019
储存分类代码3 - Flammable liquids
WGKWGK 3
闪点(F)26.6 °F
闪点(C)-3 ℃
544449FluorochemDifluoromethyl azide (1,2 M solution in DME)95 %+23364元/5ml;   38632元/10ml;   咨询

基本信息

CAS Number41796-84-3
MDL NumberMFCD24454794
Density0.87

安全信息

图形或危害标志
危险性说明 EUH019: May form explosive peroxides.
H225: Highly flammable liquid and vapour.
H315: Causes skin irritation.
H332: Harmful if inhaled.
H360FD: May damage fertility; May damage the unborn child
防范说明 P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P210: Keep away from – No smoking.
P235: Keep cool.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof ./ equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P261: Avoid breathing
P264: Wash thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P281: Use personal protective equipment as required.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P362: Take off contaminated clothing and wash before reuse.
P370 + P378: In case of fire: Use sand, CO2 or extinguishing powder for extinction.
P403 + P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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