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CAS: 41593-58-2
分子式: (C6H5)2PH·BH3
分子量: 200.02
沸点: 148℃(10
熔点: 47-50℃
英文名称: 
Borane diphenylphosphine complex
borane-diphenylphosphine complex
推荐供应商
货号品牌产品名称规格包装、参考价格详情
B857083MACKLIN硼烷二苯基膦络合物98%466元/250mg;   1400元/1g;   展开
储存:室温,干燥,惰性气体存储
状态:白色到灰白色粉末或晶体或块状或粉末和块状或晶体和块状
449563Sigma-AldrichBorane diphenylphosphine complex98%2979.89元/5 G;   展开

产品说明

应用

Reactant for:

  • Nucleophilic addition reactions (anion)
  • Catalytic dehydrogenation in the presence of ruthenium bidentate phosphine compelxes
  • Deprotonation reactions
  • Catalytic coupling with alkynyl bromides
  • Catalyst-free Staudinger ligation for indirect 18F-radiolabeling
  • Preparation of chiral phosphine-phosphite bidentate ligands with biphenyl backbone
  • Reactions with frustrated lewis pair combinations of group 14 triflates and sterically hindered nitrogen bases

包装

5 g in glass bottle

基本信息

线性分子式(C6H5)2PH·BH3
分子量200.02
MDL编号MFCD00274254
PubChem化学物质编号24868492
NACRESNA.22

产品性质

质量水平100
测定98%
reaction suitabilityreaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Reductions
reagent type: reductant
bp148-150 ℃/10 mmHg (lit.)
mp47-50 ℃ (lit.)
官能团phosphine
SMILES stringB.[H]P(c1ccccc1)c2ccccc2
InChI1S/C12H11P.BH3/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10,13H;1H3
InChI keyXUFGOLYVDOBYLK-UHFFFAOYSA-N

安全信息

象形图GHS02
警示用语:Danger
危险声明H261
预防措施声明P231 + P232 - P422
危险分类Water-react. 2
储存分类代码4.3 - Hazardous materials, which set free flammable gases upon contact with water
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
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