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CAS: 4045-44-7
分子式: C10H16
分子量: 136.23
沸点: 58℃(13 t
中文名称: 
五甲基环戊二烯
1,2,3,4,5-五甲基环戊二烯
英文名称: 
1,2,3,4,5-pentamethylcyclopentadiene
推荐供应商
货号品牌产品名称规格包装、参考价格详情
P823779MACKLIN1,2,3,4,5-五甲基环戊二烯94%(GC)51元/1ml;   168元/5ml;   423元/25ml;   1526元/100ml;   展开
储存:室温,干燥,密封,避光
状态:澄清无色到黄色液体
P1292TCI1,2,3,4,5-Pentamethylcyclopentadiene>93.0%(GC)1050元/5ML;   3455元/25ML;   展开

基本信息

纯度/分析方法>93.0%(GC)
分子式/分子量C10H16 = 136.24
外观与形状(20℃)液体
储存在惰性气体下存放于惰性气体之中
应避免的情况光,空气
Reaxys-RN1849832
PubChem物质ID87575386
SDBS (AIST Spectral DB)23780
MDL编号MFCD00001354

技术规格

AppearanceColorless to Light orange to Yellow clear liquid
Purity(GC)min. 93.0 %

物性(参考值)

沸点60 ℃/14 mmHg
闪点44 ℃
比重0.84
折射率1.47

安全信息

图形或危害标志
信号词警告
危险性说明H226 : 易燃液体和蒸气。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P240 : 容器和装载设备接地/等势联接。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P233 : 保持容器密闭。
P243 : 采取防止静电放电的措施。
P241 : 使用防爆的电气/通风/照明设备。
P242 : 只能使用不产生火花的工具。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P403 + P235 : 存放在通风良好的地方。保持低温。

运输信息

UN编号UN3295
类别3
包装类别 III
监管条件代码(*)
273765J&K1,2,3,4,5-Pentamethylcyclopentadiene93.5%251元/1G;   897元/5G;   3027元/25G;   展开

基本信息

分子式C10H16
分子量136.24
沸点58
闪点44
密度0.87
折光率(n20D)1.4725-1.4755
MDL编码MFCD00001354
Beilstein1849832
EINECS 编号223-743-4
存储条件Flammables

安全信息

图形或危害标志
提示语Warning
危险说明H226
防范说明P210
UN号码1993
危险分类3
包装等级III
WGK3
TSCA
06-1290StremPentamethylcyclopentadienemin. 98%540元/1g;   1875元/5g;   6300元/25g;   展开
L10957Alfa Aesar1,2,3,4,5-Pentamethylcyclopentadiene94%734元/1g;   2853元/5g;   9675元/25g;   展开

应用
1,2,3,4,5-Pentamethylcyclopentadiene serves as a precursor to the ligand 1,2,3,4,5-pentamethylcyclopentadienyl. It is used as a growth modifier chemical, during metal organic chemical vapor deposition of iron from iron pentacarbonyl. It is used as a ligand in "one-pot" iridium-catalyzed transformation of alcohols to amides. Further, it acts as an electron mediator in the regeneration process of nicotinamide adenine dinucleotide. In addition to this, it undergoes radical cation catalyzed cycloaddition reaction with allenes to get Diels-Alder product.

备注
Light sensitive. Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00001354

EINECS
223-743-4

分子式
C10H16

分子量
136.24

沸点
57-58°/13mm

闪点
44°(111°F)

密度
0.870

折射率
1.4740

灵敏度
Light Sensitive. Ambient temperatures.

形态
Liquid

溶解性
Miscible with methanol. dichloromethane and ethyl acetate. Slightly miscible with water.

Beilstein
1849832

GHS危害和防范说明

GHS符号

Hazard Statements
H226
Flammable liquid and vapour.

Precautionary Statements
P210-P280a-P240-P241-P303+P361+P353-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Wear protective gloves and eye/face protection.Ground/bond container and receiving equipment.Use explosion-proof electrical/ventilating/lighting/ equipment.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
3

包装组
III

危险类别
10
Flammable.

安全等级
43-60
In case of fire, use ... (indicate in the space the precise type of fire fighting equipment. If water increases risk, odd 'Never use water')This material and its container must be disposed of as hazardous waste

TSCA

C32083Alfa Aesar1,2,3,4,5-Pentamethylcyclopentadiene95%1100元/1ml;   2522元/5ml;   8236元/25ml;   展开

基本信息

Ref#
32083

MDL
1354

分子式
C10 H16

分子量
136.11

闪点
44

密度
0.87

形态
Liquid

安全信息

危险等级
3

包装组
III

8.18534Sigma-Aldrich1,2,3,4,5-Pentamethylcyclopentadienefor synthesis390.72元/1 ML;   705.35元/5 ML;   展开

产品说明

分析说明

Assay (GC, area%): ≥ 88.0 % (a/a)
Density (d 20 °C/ 4 °C): 0.837 - 0.843
Identity (IR): passes test

基本信息

经验(实验)分子式C10H16
分子量136.23
MDL编号MFCD00001354
EC索引号223-743-4

产品性质

质量水平200
测定≥88.0% (GC)
bp58 ℃/17 hPa
转变温度flash point 44 ℃
密度0.84 g/cm3 at 20 ℃
储存温度2-30℃
InChI1S/C10H16/c1-6-7(2)9(4)10(5)8(6)3/h6H,1-5H3
InChI keyWQIQNKQYEUMPBM-UHFFFAOYSA-N

安全信息

象形图GHS02
警示用语:Warning
危险声明H226
预防措施声明P210 - P233 - P240 - P241 - P242 - P243
危险分类Flam. Liq. 3
储存分类代码3 - Flammable liquids
WGKWGK 3
闪点(F)111.2 °F - closed cup
闪点(C)44 ℃ - closed cup
016049Fluorochem1,2,3,4,5-Pentamethylcyclopentadiene90%462元/1g;   1232元/5g;   展开

基本信息

CAS Number4045-44-7
MDL NumberMFCD00001354
Boiling Point58℃/13 mmHg
Density0.87

安全信息

图形或危害标志
危险性说明 H226: Flammable liquid and vapour.
H302: Harmful if swallowed.
H312: Harmful in contact with skin.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
防范说明 P210: Keep away from – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof / equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P322: Specific measures (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P363: Wash contaminated clothing before reuse.
P370 + P378: In case of fire: Use for extinction.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P403 + P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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