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CAS: 402-43-7
分子式: C7H4BrF3
分子量: 225.01
沸点: 154-155 °C(lit.)
中文名称: 
4-溴三氟化苯
对溴三氟甲苯
4-溴三氟甲苯
1-溴-4-三氟甲基苯
英文名称: 
4-bromobenzotrifluoride
1-Bromo-4-(trifluoromethyl)benzene
4-(Trifluoromethyl)bromobenzene
1-Bromo-4-trifluoromethylbenzene
4-Bromo-alpha,alpha,alpha-trifluorotoluene
4-Bromotrifluorotoluene
Benzene,1-bromo-4-(trifluoromethyl)-
1-bromo-4-(trifluoromethyl)-benzen
性质描述: 沸点154-155℃,密度1.607,闪点48℃。
用途: 医药、农药中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
B804080MACKLIN4-溴三氟甲苯99%30元/5g;   39元/25g;   135元/100g;   668元/500g;   展开
储存:室温,易燃物区域
状态:无色液体
折射率:n20/D 1.472(lit.)
B1252TCI4-Bromobenzotrifluoride>98.0%(GC)690元/25G;   2490元/250G;   展开

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C7H4BrF3 = 225.01
外观与形状(20℃)液体
Reaxys-RN2045666
PubChem物质ID87564188
SDBS (AIST Spectral DB)22407
MDL编号MFCD00000398

技术规格

AppearanceColorless to Light yellow clear liquid
Purity(GC)min. 98.0 %

物性(参考值)

沸点155 ℃
闪点48 ℃
比重1.63
折射率1.47

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H226 : 易燃液体和蒸气。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P240 : 容器和装载设备接地/等势联接。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P233 : 保持容器密闭。
P243 : 采取防止静电放电的措施。
P241 : 使用防爆的电气/通风/照明设备。
P242 : 只能使用不产生火花的工具。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P403 + P235 : 存放在通风良好的地方。保持低温。

运输信息

UN编号UN1993
类别3
包装类别 III
监管条件代码(*)
309617J&K4-Bromobenzotrifluoride99%102元/5G;   341元/25G;   1164元/100G;   展开

基本信息

分子式C7H4BrF3
分子量225.01
沸点154-155
闪点49
密度1.607
折光率(n20D)1.4720
MDL编码MFCD00000398
Beilstein2045666
EINECS 编号206-943-6

安全信息

图形或危害标志
提示语Warning
危险说明H226
H315
H319
H335
防范说明P261
P305+P351+P338
UN号码1993
危险分类3
包装等级III
WGK3
TSCA
A15942Alfa Aesar4-Bromobenzotrifluoride99%364元/5g;   1223元/25g;   4231元/100g;   展开

应用
4-Bromobenzotrifluoride is used to study the catalytic activity of palladacycle using Suzuki-Miyaura reaction.

备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which areopened must be carefully resealed and kept upright to prevent leakage. Incompatible with strong bases and strong oxidizing agents.

基本信息

MDL
MFCD00000398

EINECS
206-943-6

分子式
C7H4BrF3

分子量
225.01

沸点
154-155°

闪点
60°(140°F)

密度
1.630

折射率
1.4730

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Not miscible or difficult to mix.

Beilstein
2045666

GHS危害和防范说明

GHS符号

Hazard Statements
H226-H315-H319-H335
Flammable liquid and vapour.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P210-P261-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Avoid breathing dust/fume/gas/mist/vapours/spray.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
3

包装组
III

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
23-26-37-60
Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste

TSCA

C16667Alfa Aesar4-Bromobenzotrifluoride99%668元/5ml;   2273元/25ml;   展开

基本信息

Ref#
16667

MDL
398

分子式
C7 H4 Br F3

分子量
225.01

闪点
48

密度
1.6

安全信息

危险等级
3

包装组
III

152692Sigma-Aldrich4-Bromobenzotrifluoride99%342.68元/5 G;   795.49元/25 G;   1108.45元/100 G;   展开

产品说明

应用

用 4-溴苯并三氟化物进行 Suzuki-Miyaura 反应,研究了环钯配合物的催化活性 。

包装

5, 25, 100 g in glass bottle

基本信息

线性分子式BrC6H4CF3
分子量225.01
Beilstein2045666
EC 号206-943-6
MDL编号MFCD00000398
PubChem化学物质编号24849250
NACRESNA.22

产品性质

质量水平100
测定99%
形式liquid
折射率n20/D 1.472 (lit.)
bp154-155 ℃ (lit.)
密度1.607 g/mL at 25 ℃ (lit.)
SMILES stringFC(F)(F)c1ccc(Br)cc1
InChI1S/C7H4BrF3/c8-6-3-1-5(2-4-6)7(9,10)11/h1-4H
InChI keyXLQSXGGDTHANLN-UHFFFAOYSA-N

安全信息

象形图GHS02GHS07
警示用语:Warning
危险声明H226 - H315 - H319
预防措施声明P210 - P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2
储存分类代码3 - Flammable liquids
WGKWGK 3
闪点(F)120.2 °F - closed cup
闪点(C)49 ℃ - closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
982577Amethyst4-Bromobenzotrifluoride99%, 用于合成53元/5G;   77元/25G;   210元/100G;   728元/500G;   展开

基本信息

分子式C7H4BrF3
分子量225.01
沸点154-155
闪点49
密度1.607
折光率(n20D)1.4720
MDL编码MFCD00000398
Beilstein2045666
EINECS 编号206-943-6

安全信息

图形或危害标志
提示语Warning
危险说明H226
H315
H319
H335
防范说明P261
P305+P351+P338
UN号码1993
危险分类3
包装等级III
WGK3
TSCA
002195Fluorochem4-Bromobenzotrifluoride99%374元/25g;   858元/100g;   2200元/500g;   展开

基本信息

CAS Number402-43-7
MDL NumberMFCD00000398
Boiling Point154-155℃
Density1.607

安全信息

图形或危害标志
危险性说明 H226: Flammable liquid and vapour.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P210: Keep away from – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof ./ equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P370 + P378: In case of fire: Use sand, CO2 or powdered extinguishing agent for extinction.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P403 + P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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