| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | 详情 |
| B894185 | MACKLIN | 1-溴-2,4,6-三-叔丁基苯 | 97% | 28元/100mg; 31元/250mg; 44元/1g; 208元/5g; 829元/25g; | 展开 |
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| Y15868 | Alfa Aesar | 2-Bromo-1,3,5-tri-tert-butylbenzene | | 147元/250mg; 321元/1g; 1065元/5g; 1947元/10g; 3945元/25g; 13711元/100g; | 展开 |
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| 407097 | Sigma-Aldrich | 1-Bromo-2,4,6-tri-tert-butylbenzene | 97% | 1006.66元/1 G; 3585.92元/5 G; | 展开 |
产品说明 一般描述 1-Bromo-2,4,6-tri-tert-butylbenzene (2,4,6-tri-tert-butylbromobenzene) is a hindered aryl bromide. 1-Bromo-2,4,6-tri-tert-butylbenzene on reaction with phenylboronic acid yields α,α-dimethyl-β-phenyl hydrostyrene. 应用 1-Bromo-2,4,6-tri-tert-butylbenzene was used in the synthesis of bulky biarylphosphine ligand. This ligand was reported to participate in the Pd-catalyzed C-O cross-coupling of a wide range of aryl halides and phenols under milder conditions. It was used to investigate the effect on oligomerization of increased steric bulk in dimethylindium(III) chalcogenolates. It may be used to form α,α-dimethyl-β-phenyl hydrostyrene by reacting with phenylboronic acid. 包装 1, 5 g in glass bottle 基本信息 | 线性分子式 | [(CH3)3C]3C6H2Br | | 分子量 | 325.33 | | Beilstein | 1913257 | | MDL编号 | MFCD00191861 | | PubChem化学物质编号 | 24865424 | | NACRES | NA.22 |
产品性质 | 测定 | 97% | | mp | 168-173 ℃ (lit.) | | SMILES string | CC(C)(C)c1cc(c(Br)c(c1)C(C)(C)C)C(C)(C)C | | InChI | 1S/C18H29Br/c1-16(2,3)12-10-13(17(4,5)6)15(19)14(11-12)18(7,8)9/h10-11H,1-9H3 | | InChI key | JOKZWHPYNRDCOA-UHFFFAOYSA-N |
安全信息 | 象形图 |  | | 警示用语： | Warning | | 危险声明 | H315 - H319 - H335 | | 预防措施声明 | P302 + P352 - P305 + P351 + P338 | | 危险分类 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 | | 靶器官 | Respiratory system | | 储存分类代码 | 11 - Combustible Solids | | WGK | WGK 3 | | 闪点(F) | Not applicable | | 闪点(C) | Not applicable | | 个人防护装备 | dust mask type N95 (US), Eyeshields, Gloves |
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| 213414 | Fluorochem | 2-Bromo-1,3,5-tri-tert-butylbenzene | 95% | 792元/1g; 2684元/5g; 4554元/10g; 9086元/25g; | 展开 |
基本信息 | CAS Number | 3975-77-7 | | MDL Number | MFCD00191861 |
安全信息 | 图形或危害标志 | | | 危险性说明 | H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
| | 防范说明 | P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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