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CAS: 3970-21-6
分子式: C4H9ClO2
分子量: 124.5669
沸点: 50-52℃(1
中文名称: 
甲氧基乙氧基氯甲烷
罗红霉素侧链
罗红侧链
B-甲氧基乙氧基甲基氟
2-甲烷氧基乙氧基甲基氯
2-甲氧基乙氧基甲基氯
英文名称: 
2-Methoxyethoxymethyl chloride
beta-Methoxyethoxymethyl chloride
1-Chloro-2,5-dioxahexane
2-Methoxy-1-(Chloromethoxy)
β-Methoxyethoxymethyl chloride
1-(Chloromethoxy)-2-methoxyethane
1-Chloromethoxy-2-methoxyethane
1-(chloromethoxy)-2-methoxy-ethan
Ethylene Glycol Chloromethyl Methyl Ether
mem chloride
MEM-Chloride
2-methoxyethoxy methylchloride
展开更多英文名
性质描述: 无色或淡黄色液体。
用途: 用作罗红霉素的中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
M813727MACKLIN2-甲氧基乙氧基甲基氯95%30元/5g;   50元/25g;   165元/100g;   796元/500g;   展开
储存:2-8°C,干燥
状态:无色到浅黄色液体
折射率:n20/D 1.427(lit.)
M0680TCI2-Methoxyethoxymethyl Chloride>95.0%(GC)725元/25ML;   1990元/100ML;   4390元/500ML;   展开

基本信息

纯度/分析方法>95.0%(GC)
分子式/分子量C4H9ClO2 = 124.56
外观与形状(20℃)液体
储存温度0-10℃
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (分解),加热
Reaxys-RN1900576
PubChem物质ID87572692
SDBS (AIST Spectral DB)4442
MDL编号MFCD00000888

技术规格

AppearanceColorless to Almost colorless clear liquid
Purity(GC)min. 95.0 %
Bis chloromethyl ether(GC)max. 1.0 %

物性(参考值)

沸点52 ℃/13 mmHg
闪点54 ℃
比重1.10
折射率1.43

安全信息

图形或危害标志
信号词危险
危险性说明H300 + H310 + H330 : 吞咽、皮肤接触或吸入致命。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H350 : 可能致癌。
H226 : 易燃液体和蒸气。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P260 : 不要吸入粉尘/ 烟/ 气体/ 烟雾/ 蒸气/ 喷雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P262 : 严防进入眼中、接触皮肤或衣服。
P202 : 在阅读并明了所有安全措施前切勿搬动。
P240 : 容器和装载设备接地/等势联接。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P233 : 保持容器密闭。
P201 : 使用前取得专用说明。
P243 : 采取防止静电放电的措施。
P241 : 使用防爆的电气/通风/照明设备。
P242 : 只能使用不产生火花的工具。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P284 : [在通风不足的情况下]戴呼吸防护装置。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P308 + P313 : 如接触到或有疑虑:求医/就诊。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P361 + P364 : 立即脱掉所有沾染的衣服,清洗后方可重新使用。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P310 + P330 : 如误吞咽:立即呼叫急救中心/医生。漱口。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P403 + P233 : 存放在通风良好的地方。保持容器密闭。
P403 + P235 : 存放在通风良好的地方。保持低温。
P405 : 存放处须加锁。

运输信息

UN编号UN2929
类别6.1 / 3
包装类别 II
监管条件代码(*)
402753J&K2-Methoxyethoxymethyl Chloride94%259元/10G;   568元/25G;   1870元/100G;   展开

基本信息

分子式C4H9ClO2
分子量124.57
沸点50-52
闪点54
密度1.091
折光率(n20D)1.4260 - 1.4280
MDL编码MFCD00000888
Beilstein1900576
EINECS 编号223-589-8
存储条件Store at 2-8℃

安全信息

图形或危害标志
提示语Danger
危险说明H226
H302
H315
H319
H335
H350
防范说明P201
P261
P305+P351+P338
P308+P313
UN号码2810
危险分类6.1
包装等级II
WGK3
TSCA
L01050Alfa Aesar2-Methoxyethoxymethyl Chloride94%847元/5g;   2834元/25g;   展开

应用
2-Methoxyethoxymethyl chloride, is used as selectively cleaved under aprotic conditions in the presence of a wide range of OH-protected reagents. It is used as an OH-protecting reagent. An examples of the target molecule MEM Chloride is the side chain of roxithromycin. It is also used in the protection of the OH groups in serine and threonine during peptide synthesis. Some of the other applications include have the ability to coordinate to metals, which is thought to accelerate the cleavage by Lewis acids. The chelating ability of the MEM ether also makes it useful as a stereodirecting group in organometallic reactions, first noted in the stereo controlled addition of ?-methoxyvinyllithium to a carbonyl in the synthesis of taxusin.

备注
Moisture, Heat, water Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Keep away from oxidizing agents. Stable under recommended storage conditions.

基本信息

MDL
MFCD00000888

EINECS
223-589-8

分子式
C4H9ClO2

分子量
124.57

沸点
50-52°/13mm

闪点
54°(129°F)

密度
1.094

折射率
1.4270

灵敏度
Moisture Sensitive. Store under Nitrogen. Store at -20°C.

形态
Liquid

溶解性
It hydrolyzes with water.

Beilstein
1900576

GHS危害和防范说明

GHS符号

Hazard Statements
H226-H315-H319-H350-H335
Flammable liquid and vapour.Causes skin irritation.Causes serious eye irritation.May cause cancer.May cause respiratory irritation.

Precautionary Statements
P210-P201-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Obtain special instructions before use.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
3

包装组
III

危险类别
45-10-36/37/38
May cause cancer.Flammable.Irritating to eyes, respiratory system and skin.

安全等级
53-45
Avoid exposure - obtain special instructions before use.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

TSCA

C18598Alfa AesarMEM chloride94%1121元/10g;   2102元/25g;   7050元/100g;   展开

基本信息

Ref#
18598

MDL
888

分子式
C4 H9 Cl O2

分子量
124.57

闪点
54

密度
1.09

安全信息

危险等级
3

包装组
III

951723Amethyst2-Methoxyethoxymethyl Chloride95%, 用于合成58元/5G;   206元/25G;   664元/100G;   展开

基本信息

分子式C4H9ClO2
分子量124.57
沸点50-52
闪点54
密度1.091
折光率(n20D)1.426-1.429
MDL编码MFCD00000888
Beilstein1900576
EINECS 编号223-589-8
存储条件Store at 2-8℃

安全信息

图形或危害标志
提示语Danger
危险说明H226
H302
H315
H319
H335
H350
防范说明P201
P261
P305+P351+P338
P308+P313
UN号码2810
危险分类6.1
包装等级II
WGK3
TSCA
540003Fluorochem2-Methoxyethoxymethyl Chloride95%220元/1g;   836元/5g;   2046元/25g;   5258元/100g;   15708元/500g;   展开

基本信息

CAS Number3970-21-6
MDL NumberMFCD00000888
Boiling Point50-52℃
Density1.091

安全信息

图形或危害标志
危险性说明 H226: Flammable liquid and vapour.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H350: May cause cancer ..
防范说明 P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P210: Keep away from – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof ./ equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P281: Use personal protective equipment as required.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313: IF exposed or concerned: Get medical advice/ attention.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P370 + P378: In case of fire: Use sand, CO2 or extinguishing powder for extinction.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P403 + P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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