基本信息

技术规格

物性(参考值)

安全信息

图形或危害标志
信号词	危险
危险性说明	H301 + H311 + H331 : 吞咽、皮肤接触或吸入中毒。 H314 : 造成严重皮肤灼伤和眼损伤。 H227 : 可燃液体。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。 P270 : 使用本产品时不要进食、饮水或吸烟。 P210 : 远离热源/火花/明火/热表面。禁止吸烟。 P271 : 只能在室外或通风良好之处使用。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P370 + P378 : 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P361 + P364 : 立即脱掉所有沾染的衣服，清洗后方可重新使用。 P303 + P361 + P353 : 如皮肤(或头发)沾染：立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。 P301 + P330 + P331 : 如误吞咽：漱口。不要诱导呕吐。 P301 + P310 + P330 : 如误吞咽：立即呼叫急救中心/医生。漱口。 P304 + P340 + P310 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。立即呼叫急救中心/医生。 P305 + P351 + P338 + P310 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。 P403 + P233 : 存放在通风良好的地方。保持容器密闭。 P403 + P235 : 存放在通风良好的地方。保持低温。 P405 : 存放处须加锁。

运输信息

基本信息

安全信息

图形或危害标志
提示语	Danger
危险说明	H302 H312 H314 H332
防范说明	P280 P305+P351+P338 P310
UN号码	2922
危险分类	8
次要危险性	6.1
包装等级	II
WGK	3
TSCA	否

应用
Methyl isocyanoacetate is used in the copper-catalyzed, diastereoselective synthesis of oxazolines. It is involved in the direct aldol reaction with carbonyl compounds to prepare corresponding oxazoline by using catechol-copper network catalyst. Further, it is also involved in four-component Ugi condensation reaction. It undergoes asymmetric aldol reaction with fluorinated benzaldehyde using gold(I) as a catalyst.

备注
Light and moisture sensitive. Incompatible with strong oxidizing agents, strong bases, strong acids, hydrated iron(II) sulfate, heavy metals and aluminum. Store in a cool place. Keep the container tightly closed.

基本信息

MDL
MFCD00000006

EINECS
254-593-8

分子式
C₄H₅NO₂

分子量
99.09

沸点
75-76°/10mm

闪点
84°(183°F)

密度
1.09

灵敏度
Keep Cold. Light Sensitive. Store under Nitrogen.

形态
Liquid

溶解性
Miscible with organic solvents. Slightly miscible with water.

GHS危害和防范说明

GHS符号

Hazard Statements
H227-H302-H312-H331-H314-H318
Combustible liquid.Harmful if swallowed.Harmful in contact with skin.Toxic if inhaled.Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P210e-P260h-P303+P361+P353-P305+P351+P338-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
20/21/22-34
Harmful by inhalation, in contact with skin and if swallowed.Causes burns.

安全等级
9-20-23-26-36/37/39-45-60
Keep container in a well-ventilated place.When using do not eat or drink.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA
否

基本信息

Ref#
21900

MDL
6

分子式
C4 H5 N O2

分子量
99.09

闪点
84

密度
1.09

安全信息

危险等级
8

包装组
II

产品说明

一般描述

异氰乙酸甲酯在固相儿茶酚-铜网络催化剂存在下与羰基化合物发生直接羟醛缩合反应生成相应的恶唑啉 。它还参与四组分 Ugi 缩合反应 。

应用

异氰乙酸甲酯已被用于铜催化的、非对映选择性合成恶唑啉类 。

包装

1, 5 g in glass bottle

基本信息

产品性质

安全信息

象形图
警示用语：	Danger
危险声明	H302 + H312 + H332 - H314
预防措施声明	P280 - P305 + P351 + P338 - P310
危险分类	Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Skin Corr. 1B
储存分类代码	6.1B - Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK	WGK 3
闪点(F)	183.2 °F - closed cup
闪点(C)	84 ℃ - closed cup
个人防护装备	Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

基本信息

安全信息

图形或危害标志
提示语	Danger
危险说明	H302 H312 H314 H332
防范说明	P280 P305+P351+P338 P310
UN号码	2922
危险分类	8
次要危险性	6.1
包装等级	II
WGK	3
TSCA	否

基本信息

安全信息

图形或危害标志
危险性说明	H302: Harmful if swallowed. H314: Causes severe skin burns and eye damage. H312 + H332: Harmful in contact with skin or if inhaled
防范说明	P260: Do not breathe . P261: Avoid breathing P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310: Immediately call a POISON CENTER or doctor/physician. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see . on this label). P322: Specific measures (see . on this label). P330: Rinse mouth. P363: Wash contaminated clothing before reuse. P405: Store locked up. P501: Dispose of contents/container to local regulations.