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CAS: 39416-48-3
分子式: C5H6Br3N
分子量: 319.84
熔点: 127-133℃
中文名称: 
过溴化吡啶氢溴酸盐
三溴化氢·吡啶复合物
英文名称: 
Pyridine perbromide hydrobromide
Hydrogen tribromide-pyridine-complex
hydrogen tribromide, compd. with pyridine (1:1)
pyridinium bromide perbromide
pyridine hydrobromide perbromide
pyridinium tribromide
pyridiniumtribromide
性质描述: 橙色针状结晶,熔点133-136℃,不挥发,不溶于乙酸。
生产方法: 用吡啶与溴化氢、溴素反应制得。
用途: 三烯高诺酮的中间体。有机合成中作为方便的溴化试剂。
推荐供应商
货号品牌产品名称规格包装、参考价格
P741742MACKLIN三溴化吡啶鎓85%46元/100g;   201元/500g;   920元/2.5kg;   咨询
储存:室温
P709011MACKLIN三溴化吡啶鎓98%40元/25g;   51元/100g;   253元/500g;   1262元/2.5kg;   咨询
储存:室温
P829587MACKLIN三溴化吡啶鎓90%30元/25g;   47元/100g;   218元/500g;   998元/2.5kg;   咨询
储存:室温
状态:橙色到非常暗橙色和红色到暗红色粉末或晶体或块状或粉末和块状或晶体和块状
P0825TCIPyridinium Bromide Perbromide>85.0%(T)145元/25G;   330元/100G;   1240元/500G;   咨询

基本信息

纯度/分析方法>85.0%(T)
分子式/分子量C5H6Br3N = 319.82
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (分解)
Reaxys-RN3632802
PubChem物质ID87574955
Merck Index (14)7973
MDL编号MFCD00013223

技术规格

AppearanceLight yellow to Amber to Dark green powder to crystal
Purity(Iodometric Titration)min. 85.0 %

物性(参考值)

熔点136 ℃
溶解性(可溶于)甲醇

安全信息

图形或危害标志
信号词危险
危险性说明H314 : 造成严重皮肤灼伤和眼损伤。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P260 : 不要吸入粉尘或烟雾。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽:漱口。不要诱导呕吐。
P363 : 沾染的衣服清洗后方可重新使用。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P405 : 存放处须加锁。

运输信息

UN编号UN1759
类别8
包装类别 III
监管条件代码(*)
593050J&KPyridinium Tribromide90%65元/25G;   167元/100G;   512元/500G;   咨询

基本信息

分子式C5H6Br3N
分子量319.82
熔点134
MDL编码MFCD00013223
Beilstein3690144
Merck14,7973
EINECS 编号254-446-8

安全信息

图形或危害标志
提示语Danger
危险说明H314
防范说明P280
P305+P351+P338
P310
UN号码3261
危险分类8
包装等级II
WGK3
A15684Alfa AesarPyridine Hydrobromide Perbromidetech. 90%495元/25g;   874元/100g;   3396元/500g;   咨询

应用
Pyridine hydrobromide perbromide is used as a brominating reagent in alfa-bromination and alfa-thiocyanation of ketones, phenols, unsaturated and aromatic ethers. It is used as a raw material in the preparation of beta-adrenergic blocking agents. Furthermore, it is used as an analytical reagent.

备注
Store in cool place. Incompatible with strong oxidizing agents and strong bases.

基本信息

MDL
MFCD00013223

EINECS
254-446-8

分子式
C5H5N?HBr3

分子量
319.82

熔点
128-136°

灵敏度
Ambient temperatures.

形态
Crystalline solid

溶解性
Soluble in methanol, acetic acid, ethanol, n-butanol and terahydrofuran. Insoluble in water, carbon tetrachloride, ethyl bromide, benzene, toluene, ligroin, petroleum ether.

Beilstein
3690144

Merck
14,7973

GHS危害和防范说明

GHS符号

Hazard Statements
H314-H318
Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
III

危险类别
34
Causes burns.

安全等级
26-36/37/39-45-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA

C15836Alfa AesarPyridinium Bromide Perbromide90+%, technical1368元/100g;   4582元/500g;   咨询

基本信息

Ref#
15836

MDL
13223

分子式
C5 H6 Br3 N

分子量
319.83

形态
Red or red-brown cryst solid

安全信息

危险等级
8

包装组
II

133248Sigma-AldrichPyridinium Tribromidetechnical grade, 90%459.05元/25 G;   896.6元/100 G;   2298.95元/500 G;   咨询

产品说明

包装

25, 100, 500 g in glass bottle

应用

易处理的溴化剂。

基本信息

经验(实验)分子式C5H5N·HBr·Br2
分子量319.82
Beilstein3690144
EC 号254-446-8
MDL编号MFCD00013223
PubChem化学物质编号24848096
NACRESNA.22

产品性质

等级technical grade
质量水平200
测定90%
SMILES stringBr[Br-]Br.C1=C[NH+]=CC=C1
InChI1S/C5H5N.Br3/c1-2-4-6-5-3-1;1-3-2/h1-5H;/q;-1/p+1
InChI keyNSBNSZAXNUGWDJ-UHFFFAOYSA-O

安全信息

象形图GHS05GHS07
警示用语:Danger
危险声明H314 - H335
预防措施声明P260 - P280 - P303 + P361 + P353 - P305 + P351 + P338 + P310
危险分类Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
靶器官Respiratory system
储存分类代码8A - Combustible, corrosive hazardous materials
WGKWGK 3
个人防护装备Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
8.14345Sigma-AldrichPyridinium bromide-perbromidefor synthesis428.11元/50 G;   咨询

产品说明

分析说明

Assay (iodometric): ≥ 85.0 %
Identity (IR): passes test

基本信息

经验(实验)分子式C5H6Br3N
分子量319.82
MDL编号MFCD00013223
EC索引号254-446-8

产品性质

质量水平200
mp132-134 ℃
InChI1S/C5H5N.3Br/c1-2-4-6-5-3-1;;;/h1-5H;;;/p+1
InChI keyGWJBDYRGIFGTOG-UHFFFAOYSA-O

安全信息

象形图GHS05GHS07
警示用语:Danger
危险声明H314 - H335
预防措施声明P260 - P271 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P305 + P351 + P338
危险分类Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
靶器官Respiratory system
储存分类代码8A - Combustible, corrosive hazardous materials
WGKWGK 3
906696AmethystPyridinium Tribromide90%, 用于合成58元/25G;   114元/100G;   404元/500G;   咨询

基本信息

分子式C5H6Br3N
分子量319.82
熔点134
MDL编码MFCD00013223
Beilstein3690144
Merck14,7973
EINECS 编号254-446-8

安全信息

图形或危害标志
提示语Danger
危险说明H314
防范说明P280
P305+P351+P338
P310
UN号码3261
危险分类8
包装等级II
WGK3
094222FluorochemPyridine Hydrobromide Perbromide90%220元/1g;   242元/25g;   682元/100g;   1760元/500g;   咨询

基本信息

CAS Number39416-48-3
MDL NumberMFCD00013223
Melting Point133℃

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H314: Causes severe skin burns and eye damage.
H318: Causes serious eye damage.
防范说明 P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P363: Wash contaminated clothing before reuse.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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