| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | |
| N815886 | MACKLIN | N-苯基双(三氟甲烷磺酸亚胺) | 98% | 28元/1g; 40元/5g; 108元/25g; 416元/100g; 2050元/500g; | 咨询 |
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| P1257 | TCI | N-Phenylbis(trifluoromethanesulfonimide) [Triflating Reagent] | >98.0%(GC) | 190元/5G; 750元/25G; | 咨询 |
基本信息 | 纯度/分析方法 | >98.0%(GC) | | 分子式/分子量 | C8H5F6NO4S2 = 357.24 | | 外观与形状(20℃) | 固体 | | Reaxys-RN | 1269141 | | PubChem物质ID | 87575352 | | MDL编号 | MFCD00000404 |
技术规格 | Appearance | White to Almost white powder to crystal | | Purity(GC) | min. 98.0 % | | Solubility in Methanol | almost transparency | | Melting point | 100.0 to 103.0 ℃ |
物性(参考值) 安全信息 | 图形或危害标志 |  | | 信号词 | 警告 | | 危险性说明 | H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
| | 防范说明 | P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染：用水充分清洗。
P337 + P313 : 如仍觉眼刺激：求医/就诊。
P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激：求医/就诊。
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| 251897 | J&K | N-Phenyl bis(trifluoromethanesulfon)imide | 98% | 193元/5G; 889元/25G; | 咨询 |
基本信息 | 分子式 | C8H5F6NO4S2 | | 分子量 | 357.25 | | 熔点 | 100-102 | | MDL编码 | MFCD00000404 | | Beilstein | 1269141 |
安全信息 | 图形或危害标志 | | | 提示语 | Warning | | 危险说明 | H315
H319
H335 | | 防范说明 | P261
P305+P351+P338 | | WGK | 3 | | TSCA | 否 |
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| 346145 | J&K | N-Phenyl bis(trifluoromethanesulfon)imide | 99% | 323元/5G; 1587元/25G; 4399元/100G; | 咨询 |
基本信息 | 分子式 | C8H5F6NO4S2 | | 分子量 | 357.25 | | 熔点 | 100-102 | | MDL编码 | MFCD00000404 | | Beilstein | 1269141 |
安全信息 | 图形或危害标志 | | | 提示语 | Warning | | 危险说明 | H315
H319
H335 | | 防范说明 | P261
P305+P351+P338 | | WGK | 3 | | TSCA | 否 |
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| L12531 | Alfa Aesar | N-Phenylbis(trifluoromethanesulfonimide) | 99% | 270元/1g; 778元/5g; 3826元/25g; | 咨询 |
应用
N-Phenylbis(trifluoromethanesulfonimide) acts as a mild triflating reagent as well as a transparent strong electron-withdrawing p-type dopant in carbon nanotubes. It is also employed as a reactant for the preparation of amphoteric alfa-boryl aldehydes. It plays an important role in the enantioselective synthesis of the core ring skeleton of leucosceptroids A-D and in steroselective sulfoxidation. Further, it is used in the enantioselective synthesis of beta-amino acids through the Mannich reaction. In addition to this, it is used in the preparation of sphingosine 1-phosphate-1 receptor agonists. 备注
Hygroscopic. Store in a cool place. Moisture sensitive. Incompatible with strong oxidizing agents. 基本信息 MDL
MFCD00000404 分子式
(CF3SO2)2NC6H5 分子量
357.25 熔点
100-102° 灵敏度
Moisture Sensitive. Ambient temperatures. 溶解性
Soluble in methanol. Slightly soluble in chloroform and ethyl acetate. Beilstein
1269141 GHS危害和防范说明 GHS符号
Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation. Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations. 安全信息 危险类别
36/37/38
Irritating to eyes, respiratory system and skin. 安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. TSCA
否 |
| C37479 | Alfa Aesar | N-Phenylbis(trifluoromethanesulfonimide) | 97% | 722元/5g; 2475元/25g; 8068元/100g; | 咨询 |
基本信息 Ref#
37479 MDL
404 分子式
C8 H5 F6 N O4 S2 分子量
357.25 |
| 295973 | Sigma-Aldrich | N-Phenyl-bis(trifluoromethanesulfonimide) | 99% | 324.49元/5 G; 1567.86元/25 G; | 咨询 |
产品说明 应用 在碳纳米管中作为透明强吸电子p-型掺杂物
可用作以下反应的反应物：
两性alpha-硼醛合成
防御性二倍半萜化合物A-D主环骨架的对映选择性合成
单胺重摄取抑制物NS9544醋酸酯的空间选择性合成
空间选择性磺化氧化作用
温和的三氟甲磺酸化试剂。
近来用于与 KHMDS (324671) 共同作用将酮转化为三氟甲磺酸烯醇酯，然后与 Pd(PPh3)4 (216666) 和 Bu3SnH (234788) 共同作用进一步转化为烯烃。 包装 5, 25 g in glass bottle 基本信息 | 线性分子式 | C6H5N(SO2CF3)2 | | 分子量 | 357.25 | | Beilstein | 1269141 | | MDL编号 | MFCD00000404 | | PubChem化学物质编号 | 24857826 | | NACRES | NA.22 |
产品性质 | 质量水平 | 200 | | 测定 | 99% | | mp | 100-102 ℃ (lit.) | | SMILES string | FC(F)(F)S(=O)(=O)N(c1ccccc1)S(=O)(=O)C(F)(F)F | | InChI | 1S/C8H5F6NO4S2/c9-7(10,11)20(16,17)15(6-4-2-1-3-5-6)21(18,19)8(12,13)14/h1-5H | | InChI key | DIOHEXPTUTVCNX-UHFFFAOYSA-N |
安全信息 | 象形图 | | | 警示用语： | Warning | | 危险声明 | H315 - H319 - H335 | | 预防措施声明 | P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338 | | 危险分类 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 | | 靶器官 | Respiratory system | | 储存分类代码 | 11 - Combustible Solids | | WGK | WGK 3 | | 闪点(F) | Not applicable | | 闪点(C) | Not applicable | | 个人防护装备 | dust mask type N95 (US), Eyeshields, Gloves |
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| 78175 | Sigma-Aldrich | N-Phenyl-bis(trifluoromethanesulfonimide) | ≥98.0% (HPLC) | 330.94元/5 G; 1572.01元/25 G; 1769.99元/50 G; | 咨询 |
产品说明 应用 在碳纳米管中作为透明强吸电子p-型掺杂物
可用作以下反应的反应物：
两性alpha-硼醛合成
防御性二倍半萜化合物A-D主环骨架的对映选择性合成
单胺重摄取抑制物NS9544醋酸酯的空间选择性合成
空间选择性磺化氧化作用 包装 5, 25, 50 g in glass bottle 其他说明 稳定、易于处理的晶体状三氟甲磺酸化试剂，可用于酚和胺(尤其是脂族仲胺，但不与芳族仲胺反应)的三氟甲磺酸化；用于制备三氟甲砜；用于由酮制备烯醇三氟甲磺酸酯 基本信息 | 线性分子式 | C6H5N(SO2CF3)2 | | 分子量 | 357.25 | | Beilstein | 1269141 | | MDL编号 | MFCD00000404 | | PubChem化学物质编号 | 57652731 | | NACRES | NA.22 |
产品性质 | 质量水平 | 200 | | 测定 | ≥98.0% (HPLC) | | mp | 100-102 ℃ (lit.)
100-102 ℃ | | SMILES string | FC(F)(F)S(=O)(=O)N(c1ccccc1)S(=O)(=O)C(F)(F)F | | InChI | 1S/C8H5F6NO4S2/c9-7(10,11)20(16,17)15(6-4-2-1-3-5-6)21(18,19)8(12,13)14/h1-5H | | InChI key | DIOHEXPTUTVCNX-UHFFFAOYSA-N |
安全信息 | 象形图 | | | 警示用语： | Warning | | 危险声明 | H315 - H319 - H335 | | 预防措施声明 | P302 + P352 - P305 + P351 + P338 | | 危险分类 | Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3 | | 靶器官 | Respiratory system | | 储存分类代码 | 11 - Combustible Solids | | WGK | WGK 3 | | 闪点(F) | Not applicable | | 闪点(C) | Not applicable | | 个人防护装备 | dust mask type N95 (US), Eyeshields, Gloves |
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| 949020 | Amethyst | N-Phenyl bis(trifluoromethanesulfon)imide | 98%, 用于合成 | 53元/1G; 77元/5G; 195元/25G; 637元/100G; 2069元/500G; | 咨询 |
基本信息 | 分子式 | C8H5F6NO4S2 | | 分子量 | 357.25 | | 熔点 | 100-102 | | MDL编码 | MFCD00000404 | | Beilstein | 1269141 |
安全信息 | 图形或危害标志 | | | 提示语 | Warning | | 危险说明 | H315
H319
H335 | | 防范说明 | P261
P305+P351+P338 | | WGK | 3 | | TSCA | 否 |
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| 024773 | Fluorochem | N-Phenyl bis-trifluoromethane sulfonimide | 98% | 308元/5g; 440元/25g; 1210元/100g; | 咨询 |
基本信息 | CAS Number | 37595-74-7 | | MDL Number | MFCD00000404 | | Boiling Point | 305.3℃ | | Melting Point | 100-104℃ | | Density | 1.766 |
安全信息 | 图形或危害标志 |  | | 危险性说明 | H301: Toxic if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
| | 防范说明 | P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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