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CAS: 367-86-2
分子式: C7H3F4NO2
分子量: 209.1
沸点: 92℃(15 t
中文名称: 
2-硝基-4-三氟甲基氟苯
4-氟-3-硝基三氟甲苯
英文名称: 
3-Nitro-α,α,α,4-tetrafluorotoluene
2-Fluoro-5-(trifluoromethyl)nitrobenzene
1-Fluoro-2-nitro-4-(trifluoromethyl)benzene
3-Nitro-alpha,alpha,alpha-4-tetrafluorotoluene
4-fluoro-3-nitrobenzotrifluoride
3-Nitro-alpha,alpha,alpha,4-tetrafluorotoluene
性质描述: 相对密度1.494,沸点92℃(15mmHg),折光率1.4620。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
F809572MACKLIN4-氟-3-硝基三氟甲苯99%30元/5g;   69元/25g;   237元/100g;   947元/500g;   展开
储存:室温,易燃物区域
状态:黄色液体
折射率:n20/D 1.462(lit.)
F0324TCI4-Fluoro-3-nitrobenzotrifluoride>95.0%(GC)150元/25G;   990元/250G;   展开

基本信息

纯度/分析方法>95.0%(GC)
分子式/分子量C7H3F4NO2 = 209.10
外观与形状(20℃)液体
Reaxys-RN1880508
PubChem物质ID87570097
SDBS (AIST Spectral DB)15408
MDL编号MFCD00007059

技术规格

AppearanceLight yellow to Brown clear liquid
Purity(GC)min. 95.0 %

物性(参考值)

沸点208 ℃/262 mmHg
闪点33 ℃
比重1.53
折射率1.46

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H226 : 易燃液体和蒸气。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P240 : 容器和装载设备接地/等势联接。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P233 : 保持容器密闭。
P243 : 采取防止静电放电的措施。
P241 : 使用防爆的电气/通风/照明设备。
P242 : 只能使用不产生火花的工具。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P403 + P235 : 存放在通风良好的地方。保持低温。

运输信息

UN编号UN1993
类别3
包装类别 III
监管条件代码(*)
314395J&K4-Fluoro-3-nitrobenzotrifluoride99%60元/5G;   186元/25G;   613元/100G;   展开

基本信息

分子式C7H3F4NO2
分子量209.10
沸点92
闪点33
密度1.494
折光率(n20D)1.4620
MDL编码MFCD00007059
Beilstein1880508
EINECS 编号206-702-5

安全信息

图形或危害标志
提示语Warning
危险说明H226
H316
H320
H335
防范说明P261
P305+P351+P338
UN号码1993
危险分类3
包装等级III
WGK3
TSCA
A19676Alfa Aesar4-Fluoro-3-nitrobenzotrifluoride97%508元/25g;   1131元/100g;   4390元/500g;   展开

应用
4-Fluoro-3-nitrobenzotrifluoride is used in the pre-column derivatization technique for HPLC with UV/VIS spectrophotometric detection of polyamines. It may be used as derivatization reagent for the HPLC determination of polyamines. It was also used in the synthesis of 2-nitro-4-trifluoromethylphenylhydrazine, derivatization reagent for 1,2-diol compounds and oxo-steroids. • [3-(2-nitro-4-trifluoromethylphenyl)aminophenyl]dihydroxyborane, derivatization reagent for 1,2-diol compounds and oxo-steroids3 • 1-(3-chlorophenyl)-5-trifluoromethyl-3-hydrobenzimidazol-2-one

备注
Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

基本信息

MDL
MFCD00007059

EINECS
206-702-5

分子式
C7H3F4NO2

分子量
209.10

沸点
91-92°/15mm

闪点
90°(194°F)

密度
1.494

折射率
1.4620

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Insoluble in water.

Beilstein
1880508

GHS危害和防范说明

GHS符号

Hazard Statements
H227-H302-H311-H332-H315-H319
Combustible liquid.Harmful if swallowed.Toxic in contact with skin.Harmful if inhaled.Causes skin irritation.Causes serious eye irritation.

Precautionary Statements
P280h-P305+P351+P338-P309-P310-P302+P352
Wear protective gloves/clothing.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF exposed or if you feel unwell:Immediately call a POISON CENTER or doctor/physician.IF ON SKIN: Wash with plenty of soap and water.

安全信息

危险等级
3

包装组
III

危险类别
20/21/22-36/38
Harmful by inhalation, in contact with skin and if swallowed.Irritating to eyes and skin.

安全等级
26-28-36/37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer).Wear suitable protective clothing and gloves.

欧盟危险品标志

TSCA

C20061Alfa Aesar4-Fluoro-3-nitrobenzotrifluoride96%469元/5g;   2953元/100g;   展开

基本信息

Ref#
20061

MDL
7059

分子式
C7 H3 F4 N O2

分子量
209.1

闪点
33

密度
1.49

形态
Liquid

安全信息

危险等级
3

包装组
III

346640Sigma-Aldrich4-Fluoro-3-nitrobenzotrifluoride96%502.08元/100 G;   展开

产品说明

应用

4-Fluoro-3-nitrobenzotrifluoride was used in the pre-column derivatization technique for HPLC with UV/VIS spectrophotometric detection of polyamines. It may be used as derivatization reagent for the HPLC determination of polyamines (spermidine, spermine and the diamine precursor putrescine). It was also used in the synthesis of:

  • 2-nitro-4-trifluoromethylphenylhydrazine, derivatization reagent for 1,2-diol compounds and oxo-steroids
  • [3-(2-nitro-4-trifluoromethylphenyl)aminophenyl]dihydroxyborane, derivatization reagent for 1,2-diol compounds and oxo-steroids
  • 1-(3-chlorophenyl)-5-trifluoromethyl-3-hydrobenzimidazol-2-one

包装

100 g in glass bottle

基本信息

线性分子式FC6H3(NO2)CF3
分子量209.10
Beilstein1880508
EC 号206-702-5
MDL编号MFCD00007059
PubChem化学物质编号24861423
NACRESNA.22

产品性质

质量水平100
测定96%
折射率n20/D 1.462 (lit.)
bp92 ℃/15 mmHg (lit.)
密度1.494 g/mL at 25 ℃ (lit.)
SMILES string[O-][N+](=O)c1cc(ccc1F)C(F)(F)F
InChI1S/C7H3F4NO2/c8-5-2-1-4(7(9,10)11)3-6(5)12(13)14/h1-3H
InChI keyHLDFCCHSOZWKAA-UHFFFAOYSA-N

安全信息

象形图GHS02GHS07
警示用语:Warning
危险声明H226 - H315 - H319 - H335
预防措施声明P210 - P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码3 - Flammable liquids
WGKWGK 3
闪点(F)91.4 °F - closed cup
闪点(C)33 ℃ - closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
005225Fluorochem4-Fluoro-3-nitrobenzotrifluoride99%264元/25g;   484元/100g;   2090元/500g;   展开

基本信息

CAS Number367-86-2
MDL NumberMFCD00007059
Boiling Point92℃/15mm
Density1.494

安全信息

图形或危害标志
危险性说明 H226: Flammable liquid and vapour.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P210: Keep away from – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof ./ equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P370 + P378: In case of fire: Use sand, CO2 or extinguishing powder for extinction.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P403 + P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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