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CAS: 366-18-7
分子式: C10H8N2
分子量: 156.18
沸点: 273 °C(lit.)
熔点: 70-73 °C(lit.)
中文名称: 
2,2'-二吡啶
2,2'-二吡啶基
2,2-联吡啶
α,α'-联氮杂苯
α,α'-联吡啶
2,2'-联吡啶
英文名称: 
2,2'-Bipyridine
2,2'-Bipyridyl
2,2'-bipyridin
2,2'-dipyridine
2,2'-dipyridyl
2-(2-pyridyl)pyridine
alpha,alpha'-bipyridine
alpha,alpha'-bipyridyl
alpha,alpha'-dipyridine
alpha,alpha'-dipyridyl
alpha,alpha'-dwupirydylu
bipyridine
ci-588
2,2-Dipyridyl
,'-Dipyridyl
[2,2']Bipyridinyl
展开更多英文名
性质描述: 白色至浅红色结晶性粉末。熔点69.5℃,沸点272.5℃。易溶于乙醇、乙醚、苯、氯仿和石油醚,1份本品约溶于200份水。
生产方法: 由吡啶与三氯化铁反应而得。取70g无水吡啶与13g无水三氯化铁混合,在封管中于300℃加热反应约35h。冷却后,反应物固化为红黑色结晶,打开封管,用少量热水洗出固体物的红黑色溶液。用乙醚萃取除去油状不纯物。用碳酸氢钠中和后,用蒸汽加热除去过量的吡啶。然后将混合物调成强碱性,用蒸汽蒸出2,2'-联吡啶。蒸出物酸化后蒸发浓缩,再加氢氧化钠,用乙醚提取,除去乙醚得粗品。粗品用乙来重结晶、活性炭脱色即得纯品。另外,由α-甲基吡啶[109-06-8]与高锰酸钾反应,经提纯处理也可制得该品。
用途: 该品为分析试剂,用于检定亚铁、银、镉、钼,作氧化还原指示剂。
推荐供应商
货号品牌产品名称规格包装、参考价格
B807242MACKLIN2,2'-联吡啶99%32元/5g;   49元/25g;   118元/100g;   445元/500g;   1936元/2.5kg;   7688元/10kg;   5206元/12X500g;   咨询
储存:室温
状态:白色到灰白色到淡黄色粉末,晶体和/或块状
B742546MACKLIN2,2'-联吡啶99.7%180元/5g;   咨询
储存:室温
状态:粉末或晶体
B0468TCI2,2'-Bipyridyl>99.0%(T)275元/25G;   630元/100G;   2350元/500G;   咨询

基本信息

纯度/分析方法>99.0%(T)
分子式/分子量C10H8N2 = 156.19
外观与形状(20℃)固体
应避免的情况
Reaxys-RN113089
PubChem物质ID87563502
SDBS (AIST Spectral DB)1749
Merck Index (14)3347
MDL编号MFCD00006212

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(Nonaqueous Titration)min. 99.0 %
Melting point69.5 to 72.0 ℃
Solubility in EtOHtransparency
Ignition residue(Sulfate)max. 0.05 %
Suitability for iron-analysisto pass test

物性(参考值)

熔点72 ℃
沸点273 ℃
最大吸收波长280(EtOH) nm
水溶性可溶
溶解性(可溶于)乙醇,氯仿,乙醚,苯

安全信息

图形或危害标志
信号词危险
危险性说明H301 : 吞咽会中毒。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H341 : 怀疑可造成遗传性缺陷。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P270 : 使用本产品时不要进食、饮水或吸烟。
P202 : 在阅读并明了所有安全措施前切勿搬动。
P201 : 使用前取得专用说明。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P308 + P313 : 如接触到或有疑虑:求医/就诊。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P310 + P330 : 如误吞咽:立即呼叫急救中心/医生。漱口。
P405 : 存放处须加锁。

相关法规

RTECS#DW1750000

运输信息

UN编号UN2811
类别6.1
包装类别 III
监管条件代码(*)
107095J&K2,2'-Bipyridine99%60元/5G;   197元/25G;   551元/100G;   2043元/500G;   咨询

基本信息

分子式C10H8N2
分子量156.18
熔点70-73
沸点273
MDL编码MFCD00006212
Beilstein113089
Merck14,3347
EINECS 编号206-674-4

安全信息

图形或危害标志
提示语Danger
危险说明H301
H315
H319
H335
防范说明P261
P301+P310
P305+P351+P338
UN号码2811
危险分类6.1
包装等级III
WGK3
RTECSDW1750000
TSCA
07-0290Strem2,2'-Bipyridine99+%1097元/25g;   3225元/100g;   咨询
030569Alfa Aesar2,2'-BipyridineACS, 98%251元/10g;   963元/50g;   3832元/250g;   咨询

应用
2,2'-bipyridine acts as a bidentate chelating ligand which form complexes with transition metal ions and shows antifungal, antibacterial and antiviral activity. It is used for the colorimetric determination of iron as well as oxidation reduction indicators to confirm the presence of ferrous ion in soils. It forms complexes with ruthenium and platinum, exhibit intense luminescence, which may have practical applications. Copper(I) bipyridine complexes involved in the oxidation of alcohols under aerobic conditions.

Grade Specifications
Maximum level of impurities: Clarity and absorbance of solution P.T., Sensitivity to ferrous iron P.T., Melting point ≥70�

备注
Keep container tightly closed in a dry and well-ventilated place. Keep away from sources of ignition.

基本信息

MDL
MFCD00006212

EINECS
206-674-4

分子式
C10H8N2

分子量
156.19

熔点
70°

沸点
272-273°

闪点
121°(249°F)

灵敏度
Ambient temperatures.

形态
Crystalline

溶解性
Soluble in organic solvents and slightly soluble in water.

Beilstein
113089

Merck
14,3347

GHS危害和防范说明

GHS符号

Hazard Statements
H301-H312
Toxic if swallowed.Harmful in contact with skin.

Precautionary Statements
P280h-P301+P310a-P312a-P321-P405-P501a
Wear protective gloves/clothing.Wear protective gloves/clothing.Wear protective gloves/clothing.Specific treatment (see label).Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
III

危险类别
21-25
Harmful in contact with skin.Toxic if swallowed.

安全等级
36/37-45
Wear suitable protective clothing and gloves.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

RTECS
DW1750000

TSCA

A15782Alfa Aesar2,2'-Bipyridine99+%792元/25g;   2583元/100g;   6576元/500g;   咨询

应用
Reagent for iron determinations.2,2'-bipyridine acts as a bidentate chelating ligand which form complexes with transition metal ions and shows antifungal, antibacterial and antiviral activity. It is used for the colorimetric determination of iron as well as oxidation reduction indicators to confirm the presence of ferrous ion in soils. It forms complexes with ruthenium and platinum, exhibit intense luminescence, which may have practical applications. Copper(I) bipyridine complexes involved in the oxidation of alcohols under aerobic conditions.

备注
Keep container tightly closed in a dry and well-ventilated place. Keep away from sources of ignition.

基本信息

MDL
MFCD00006212

EINECS
206-674-4

分子式
C10H8N2

分子量
156.19

熔点
70°

沸点
272-273°

闪点
121°(249°F)

灵敏度
Ambient temperatures.

形态
Crystalline powder

溶解性
Soluble in organic solvents and slightly soluble in water.

Beilstein
113089

Merck
14,3347

GHS危害和防范说明

GHS符号

Hazard Statements
H301-H312
Toxic if swallowed.Harmful in contact with skin.

Precautionary Statements
P280h-P301+P310a-P312a-P321-P405-P501a
Wear protective gloves/clothing.Wear protective gloves/clothing.Wear protective gloves/clothing.Specific treatment (see label).Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
III

危险类别
21-25
Harmful in contact with skin.Toxic if swallowed.

安全等级
36/37-45
Wear suitable protective clothing and gloves.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

RTECS
DW1750000

TSCA

C11750Alfa Aesar2,2'-Dipyridyl99+%663元/10g;   1214元/25g;   2860元/100g;   9672元/500g;   咨询

基本信息

Ref#
11750

MDL
6212

分子式
C10 H8 N2

分子量
156.19

闪点
121

形态
Crystalline

安全信息

危险等级
6.1

包装组
III

D95-5Alfa AesarA A DIPYRIDYL CRYSTAL CERT 5G335元/5g;   咨询

基本信息

Ref#
F51759

安全信息

危险等级
6.1

包装组
III

D216305Sigma-Aldrich2,2′-BipyridylReagentPlus®, ≥99%296.7元/2.5 G;   545.78元/10 G;   855.04元/25 G;   1904.4元/100 G;   9045.91元/500 G;   12065.7元/1 KG;   咨询

产品说明

一般描述

2,2′-联吡啶是一种对称的联吡啶,常用作与金属离子螯合的中性配体。通过研究2,2′-联吡啶对矮牵牛(Petunia hybrida)花的影响,发现它可以抑制衰老。
我们致力于为您提供更环保的替代产品,以符合“绿色化学的12项原则”的一项或多项原则要求。该产品为增强型,提高了催化效率。点击此处了解更多详情。

应用

是醇在有氧条件下发生绿色氧化情况下铜的配体。
二合配位体,用于过渡金属催化和铝引发的聚合反应(无机合成)。
作为铜催化醇的环保型有氧氧化反应的配体。

在环境空气中,铜(I)/TEMPO催化的有氧氧化反应,将伯醇转化为醛
2,2′-联吡啶已被用于制备铜(II)-联吡啶-柚皮素复合物。它可用于制备 2,2′联吡啶氢溴酸盐。

包装

25, 100, 500 g in poly bottle
2.5, 10 g in glass bottle
12 kg in poly drum
1 kg in poly bottle

生化/生理作用

金属蛋白酶抑制剂,铁的高亲和力螯合剂;在10−8 M浓度下可以抑制含Fe2+的酶。

法律信息

ReagentPlus is a registered trademark of sigma-aldrich Co. LLC

基本信息

经验(实验)分子式C10H8N2
分子量156.18
Beilstein113089
EC 号206-674-4
MDL编号MFCD00006212
PubChem化学物质编号57654082
NACRESNA.21

产品性质

质量水平200
生物来源synthetic (organic)
产品线ReagentPlus®
测定≥99%
形式powder or crystals
powder or granules
环保替代产品特性Catalysis
Learn more about the Principles of Green Chemistry.
bp273 ℃ (lit.)
mp70-73 ℃ (lit.)
溶解性ethanol: 100 mg/mL, clear, colorless to faintly yellow
储存温度room temp
SMILES stringc1ccc(nc1)-c2ccccn2
InChI1S/C10H8N2/c1-3-7-11-9(5-1)10-6-2-4-8-12-10/h1-8H
InChI keyROFVEXUMMXZLPA-UHFFFAOYSA-N
Gene Informationhuman ... EPHX2(2053), FNTA(2339)
mouse ... Ephx2(13850)

安全信息

象形图GHS06
警示用语:Danger
危险声明H301 + H311
预防措施声明P264 - P270 - P280 - P301 + P310 - P302 + P352 + P312 - P361 + P364
危险分类Acute Tox. 3 Dermal - Acute Tox. 3 Oral
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 3
闪点(F)267.8 °F - closed cup
闪点(C)131 ℃ - closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
798533Sigma-Aldrich2,2′-Bipyridylanhydrous, free-flowing, Redi-Dri, ReagentPlus®, 99%1710.2元/50 G;   3249.38元/100 G;   4280.35元/500 G;   咨询

产品说明

一般描述

我们致力于为您带来更环保的替代产品,以符合一项或多项绿色化学12项原则。该产品为增强型,提高了催化效率。点击此处以获取更多信息。
2,2′-联吡啶是一种对称的联吡啶,通常用作与金属离子络合的中性配体。该分子是平面的,具有反式构象,并在单斜晶体系统中结晶。

应用

2,2′-联吡啶基可用于使用 CuI/TEMPO(TEMPO = 2,2,6,6-四甲基-1-哌啶基氧基)催化剂系统通过需氧氧化从伯醇制备醛。

包装

50, 100, 500 g in poly bottle
1 kg in poly bottle

生化/生理作用

金属蛋白酶抑制剂,铁的高亲和力螯合剂;在10−8 M浓度下可以抑制含Fe2+的酶。

法律信息

ReagentPlus is a registered trademark of sigma-aldrich Co. LLC
Redi-Dri is a trademark of sigma-aldrich Co. LLC

基本信息

经验(实验)分子式C10H8N2
分子量156.18
Beilstein113089
EC 号206-674-4
MDL编号MFCD00006212
PubChem化学物质编号329768657

产品性质

质量水平100
等级anhydrous
产品线ReagentPlus®
Redi-Dri
测定99%
质量free-flowing
环保替代产品特性Catalysis
Learn more about the Principles of Green Chemistry.
bp273 ℃ (lit.)
mp70-73 ℃ (lit.)
SMILES stringc1ccc(nc1)-c2ccccn2
InChI1S/C10H8N2/c1-3-7-11-9(5-1)10-6-2-4-8-12-10/h1-8H
InChI keyROFVEXUMMXZLPA-UHFFFAOYSA-N

安全信息

象形图GHS06
警示用语:Danger
危险声明H301 + H311
预防措施声明P264 - P270 - P280 - P301 + P310 - P302 + P352 + P312 - P361 + P364
危险分类Acute Tox. 3 Dermal - Acute Tox. 3 Oral
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 3
闪点(F)267.8 °F - closed cup
闪点(C)131 ℃ - closed cup
V900145Sigma-Aldrich2,2′-BipyridylVetec, reagent grade, 98%293.2元/25 G;   咨询

产品说明

包装

25 g in poly bottle

生化/生理作用

金属蛋白酶抑制剂,铁的高亲和力螯合剂;在10−8 M浓度下可以抑制含Fe2+的酶。

法律信息

Vetec is a trademark of sigma-aldrich International GmbH

基本信息

经验(实验)分子式C10H8N2
分子量156.18
Beilstein113089
EC 号206-674-4
MDL编号MFCD00006212
PubChem化学物质编号329829581

产品性质

等级reagent grade
产品线Vetec
测定98%
形式solid
bp273 ℃ (lit.)
mp70-73 ℃ (lit.)
溶解性ethanol: 100 mg/mL, clear, colorless to faintly yellow
SMILES stringc1ccc(nc1)-c2ccccn2
InChI1S/C10H8N2/c1-3-7-11-9(5-1)10-6-2-4-8-12-10/h1-8H
InChI keyROFVEXUMMXZLPA-UHFFFAOYSA-N

安全信息

象形图GHS06
警示用语:Danger
危险声明H301 + H311
预防措施声明P264 - P270 - P280 - P301 + P310 - P302 + P352 + P312 - P361 + P364
危险分类Acute Tox. 3 Dermal - Acute Tox. 3 Oral
储存分类代码6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGKWGK 3
闪点(F)267.8 °F - closed cup
闪点(C)131 ℃ - closed cup
222772Amethyst2,2'-Bipyridine99%, 试剂级40元/5G;   62元/25G;   182元/100G;   675元/500G;   咨询

基本信息

分子式C10H8N2
分子量156.18
熔点70-73
沸点273
MDL编码MFCD00006212
Beilstein113089
Merck14,3347
EINECS 编号206-674-4

安全信息

图形或危害标志
提示语Danger
危险说明H301
H315
H319
H335
防范说明P261
P301+P310
P305+P351+P338
UN号码2811
危险分类6.1
包装等级III
WGK3
RTECSDW1750000
TSCA
003434Fluorochem2,2'-Dipyridyl98%242元/25g;   440元/100g;   1914元/250g;   咨询

基本信息

CAS Number366-18-7
MDL NumberMFCD00006212
Boiling Point272.2℃
Melting Point68-74℃
Density1.1668

安全信息

图形或危害标志
危险性说明 H301: Toxic if swallowed.
H311: Toxic in contact with skin.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P322: Specific measures (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P361: Remove/Take off immediately all contaminated clothing.
P362: Take off contaminated clothing and wash before reuse.
P363: Wash contaminated clothing before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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