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CAS: 348-61-8
分子式: C6H3BrF2
分子量: 193
沸点: 150-151℃
中文名称: 
4-溴-1,2-二氟苯
3,4-二氟溴苯
英文名称: 
1-Bromo-3,4-difluorobenzene
3.4-difluoro-bromobenzene
4-Bromo-1,2-difluorobenzene
3,4-Difluorobromobenzene
性质描述: 无色透明液体。沸点150-151℃,闪点33℃,折光率1.4990,比重 1.707。
用途: 医药、农药、液晶材料中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格详情
D823283MACKLIN3,4-二氟溴苯≥99.5%,GC45元/5g;   108元/25g;   288元/100g;   1380元/500g;   展开
储存:室温
状态:澄清到淡黄色液体
D823046MACKLIN3,4-二氟溴苯≥98%28元/5g;   30元/25g;   98元/100g;   442元/500g;   展开
储存:室温
状态:澄清到淡黄色液体
B1523TCI1-Bromo-3,4-difluorobenzene>98.0%(GC)390元/25G;   2390元/250G;   展开

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C6H3BrF2 = 192.99
外观与形状(20℃)液体
Reaxys-RN1934811
PubChem物质ID87564431
SDBS (AIST Spectral DB)21869
MDL编号MFCD00000304

技术规格

AppearanceColorless to Light yellow to Light orange clear liquid
Purity(GC)min. 98.0 %

物性(参考值)

沸点151 ℃
闪点33 ℃
比重1.71
折射率1.51

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H411 : 对水生生物有毒并具有长期持续影响。
H226 : 易燃液体和蒸气。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P273 : 避免释放到环境中。
P240 : 容器和装载设备接地/等势联接。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P233 : 保持容器密闭。
P243 : 采取防止静电放电的措施。
P241 : 使用防爆的电气/通风/照明设备。
P242 : 只能使用不产生火花的工具。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P391 : 收集溢出物。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P403 + P235 : 存放在通风良好的地方。保持低温。

运输信息

UN编号UN1993
类别3
包装类别 III
监管条件代码(*)
416022J&K1-Bromo-3,4-difluorobenzene98%73元/5G;   292元/25G;   展开

基本信息

分子式C6H3BrF2
分子量192.99
沸点150-151
闪点33
密度1.707
折光率(n20D)1.5050
MDL编码MFCD00000304
Beilstein1934811
EINECS 编号206-481-5

安全信息

图形或危害标志
提示语Warning
危险说明H226
H315
H319
H335
防范说明P261
P305+P351+P338
UN号码1993
危险分类3
包装等级III
WGK2
TSCA
A11934Alfa Aesar4-Bromo-1,2-difluorobenzene98+%677元/5g;   3094元/25g;   5912元/100g;   展开

基本信息

MDL
MFCD00000304

EINECS
206-481-5

分子式
C6H3BrF2

分子量
192.99

熔点
-4°

沸点
150-151°

闪点
33°(91°F)

密度
1.707

折射率
1.5050

灵敏度
Ambient temperatures.

形态
Liquid

Beilstein
1934811

GHS危害和防范说明

GHS符号

Hazard Statements
H226-H315-H319-H335
Flammable liquid and vapour.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P210-P261-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Avoid breathing dust/fume/gas/mist/vapours/spray.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
3

包装组
III

危险类别
10-36/37/38
Flammable.Irritating to eyes, respiratory system and skin.

安全等级
26-37-43-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of fire, use ... (indicate in the space the precise type of fire fighting equipment. If water increases risk, odd 'Never use water')This material and its container must be disposed of as hazardous waste

TSCA

263478Sigma-Aldrich4-Bromo-1,2-difluorobenzene98%635.31元/10 G;   展开

产品说明

一般描述

Regioselective nucleophilic aromatic substitution reaction of 4-bromo-1,2-difluorobenzene with benzyl alcohol has been investigated.

应用

4-Bromo-1,2-difluorobenzene has been used in the preparation of 4-benzyl-2-(3,4-difluorophenyl)-2-hydroxy-morpholine.

包装

10 g in ampule

基本信息

线性分子式BrC6H3F2
分子量192.99
EC 号206-481-5
MDL编号MFCD00000304
PubChem化学物质编号24855975
NACRESNA.22

产品性质

质量水平100
测定98%
折射率n20/D 1.505 (lit.)
bp150-151 ℃ (lit.)
密度1.707 g/mL at 25 ℃ (lit.)
SMILES stringFc1ccc(Br)cc1F
InChI1S/C6H3BrF2/c7-4-1-2-5(8)6(9)3-4/h1-3H
InChI keyYMQPKONILWWJQG-UHFFFAOYSA-N

安全信息

象形图GHS02GHS07GHS09
警示用语:Warning
危险声明H226 - H302 + H332 - H315 - H317 - H411
预防措施声明P210 - P273 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P312
危险分类Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Flam. Liq. 3 - Skin Irrit. 2 - Skin Sens. 1
储存分类代码3 - Flammable liquids
WGKWGK 2
闪点(F)91.4 °F
闪点(C)33 ℃
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
001118Fluorochem1-Bromo-3,4-difluorobenzene98%220元/1g;   286元/25g;   440元/100g;   770元/250g;   1430元/500g;   展开

基本信息

CAS Number348-61-8
MDL NumberMFCD00000304
Boiling Point150-151℃
Melting Point-4℃
Density1.707

安全信息

图形或危害标志
危险性说明 H226: Flammable liquid and vapour.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P210: Keep away from – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof ./ equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P370 + P378: In case of fire: Use sand, CO2 or extinguishing powder for extinction.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P403 + P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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