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CAS: 3453-00-7
分子式: C12H17O4P
分子量: 256.24
沸点: 193°C/11mmHg(lit.)
英文名称: 
DIETHYL (2-OXO-2-PHENYLETHYL)PHOSPHONATE
Diethyl(2-oxo-2-phenylethyl)phosphonate
(2-Oxo-2-phenylethyl)phosphonic Acid Diethyl Ester
Diethyl Phenacylphosphonate
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货号品牌产品名称规格包装、参考价格详情
D866109MACKLIN(2-氧代-2-苯乙基)膦酸二乙酯97%132元/200mg;   310元/1g;   展开
储存:室温,干燥
状态:无色到黄色到绿色澄清液体
D3339TCIDiethyl (2-Oxo-2-phenylethyl)phosphonate>97.0%(GC)490元/1G;   1990元/5G;   展开

基本信息

纯度/分析方法>97.0%(GC)
分子式/分子量C12H17O4P = 256.24
外观与形状(20℃)液体
储存在惰性气体下存放于惰性气体之中
应避免的情况空气
Reaxys-RN2942070
PubChem物质ID87558638

技术规格

AppearanceWhite to Yellow to Green clear liquid
Purity(GC)min. 97.0 %
Refractive index n20/D1.5040 to 1.5160

物性(参考值)

沸点193 ℃/11 mmHg
比重1.18
折射率1.51
410756Sigma-AldrichDiethyl (2-Oxo-2-phenylethyl)phosphonate97%299.35元/1 G;   2094.91元/10 G;   展开

产品说明

应用

Reactant involved in:

  • Asymmetric Michael addition of β-oxo phosphonates to nitro olefins
  • Gem-chlorofluorination of keto phosphonates with subsequent functionalization of the products
  • Cyclocondensation reactions to produce arylphosphonates
  • Diazo transfer reactions for synthesis of diazo-phosphonyl compounds
  • Horner-Wadsworth-Emmons reactions
  • Inverse-electron-demand Diels-Alder reactions

包装

1, 10 g in glass bottle

基本信息

线性分子式C6H5COCH2P(O)(OC2H5)2
分子量256.23
MDL编号MFCD00015342
PubChem化学物质编号24865704
NACRESNA.22

产品性质

测定97%
reaction suitabilityreaction type: C-C Bond Formation
折射率n20/D 1.513 (lit.)
bp192-193 ℃/11 mmHg (lit.)
密度1.179 g/mL at 25 ℃ (lit.)
SMILES stringCCOP(=O)(CC(=O)c1ccccc1)OCC
InChI1S/C12H17O4P/c1-3-15-17(14,16-4-2)10-12(13)11-8-6-5-7-9-11/h5-9H,3-4,10H2,1-2H3
InChI keyHPEVTTNSIPGLEL-UHFFFAOYSA-N

安全信息

储存分类代码12 - Non Combustible Liquids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves
243206FluorochemDiethyl (2-Oxo-2-phenylethyl)phosphonate95%946元/1g;   2838元/5g;   5038元/10g;   展开

基本信息

CAS Number3453-00-7
MDL NumberMFCD00015342

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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