CAS 3395-91-3; β-溴丙酸甲酯; 3-Bromopropionic acid methyl ester

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货号

品牌

产品名称

规格

包装、参考价格

M824051

MACKLIN

甲基-3-溴丙酸酯

98%

44元/25g; 158元/100g; 779元/500g; 3845元/2.5kg;

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储存：2~8℃,干燥,密封
状态：无色液体
折射率：n20/D 1.458(lit.)

B0648

TCI

Methyl 3-Bromopropionate

>99.0%(GC)

490元/25G; 1350元/100G; 3690元/500G;

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基本信息

纯度/分析方法	>99.0%(GC)
分子式/分子量	C₄H₇BrO₂ = 167.00
外观与形状(20℃)	液体
Reaxys-RN	1742949
PubChem物质ID	87563655
SDBS (AIST Spectral DB)	19924
MDL编号	MFCD00000250

技术规格

Appearance	Colorless to Almost colorless clear liquid
Purity(GC)	min. 99.0 %

物性(参考值)

沸点	105 ℃/60 mmHg
闪点	75 ℃
比重	1.53
折射率	1.46

安全信息

图形或危害标志
信号词	警告
危险性说明	H302 : 吞咽有害。 H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。 H227 : 可燃液体。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P270 : 使用本产品时不要进食、饮水或吸烟。 P210 : 远离热源/火花/明火/热表面。禁止吸烟。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/戴防护眼罩/戴防护面具。 P302 + P352 : 如皮肤沾染：用水充分清洗。 P370 + P378 : 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P332 + P313 : 如发生皮肤刺激：求医/就诊。 P301 + P312 + P330 : 如误吞咽：如感觉不适，呼叫急救中心/医生。漱口。 P403 + P235 : 存放在通风良好的地方。保持低温。

相关法规

RTECS#

UA2451790

441677

J&K

Methyl 3-Bromopropionate

99%

154元/5ML; 406元/25ML; 1094元/100ML;

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基本信息

分子式	C₄H₇BrO₂
分子量	167.00
沸点	64-66
闪点	75
密度	1.53
折光率(n20D)	1.4580
MDL编码	MFCD00000250
Beilstein	1742949
EINECS 编号	222-247-5

安全信息

图形或危害标志
提示语	Warning
危险说明	H302 H315 H319 H335
防范说明	P261 P305+P351+P338
WGK	3
RTECS	UA2451790
TSCA	是

L14127

Alfa Aesar

Methyl 3-Bromopropionate

97%

1284元/25g; 2842元/100g;

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应用
Methyl 3-bromopropionate was used in the synthesis of spiroanellated γ-lactones, pinacols and unprecedented 3-(1-hydroxycycloalkyl)-l-oxaspiro[n,m]alkan-2-ones. It can react with 2-Methyl-1H-benzoimidazole to get 1-(2-Methoxycarbonylethyl)-2-methylbenzimidazole.

备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agents.

基本信息

MDL
MFCD00000250

EINECS
222-247-5

分子式
Br(CH₂)₂CO₂CH₃

分子量
167.01

沸点
58-60°/12mm

闪点
75°(167°F)

密度
1.530

折射率
1.4580

灵敏度
Ambient temperatures.

溶解性
Immiscible in water.

Beilstein
1742949

GHS危害和防范说明

GHS符号

Hazard Statements
H227-H301-H315-H319-H335
Combustible liquid.Toxic if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P210e-P261-P301+P310a-P305+P351+P338-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Avoid breathing dust/fume/gas/mist/vapours/spray.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
22-36/37/38
Harmful if swallowed.Irritating to eyes, respiratory system and skin.

安全等级
26-36/37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.

欧盟危险品标志

RTECS
UA2451790

TSCA
是

C22179

Alfa Aesar

Methyl 3-Bromopropionate

97%

2177元/25ml; 4578元/50ml; 8985元/100ml;

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基本信息

Ref#
22179

MDL
250

分子式
C4 H7 Br O2

分子量
167

闪点
75

密度
1.53

形态
Liquid

242373

Sigma-Aldrich

Methyl 3-Bromopropionate

97%

728.31元/25 G; 2016.73元/100 G;

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产品说明

应用

3-溴丙酸甲酯用于螺环烷基 γ-的合成-内酯、频哪醇和前所未有的 3-(1-羟基环烷基)-l-氧杂螺 [ n,m ] 烷基-2-酮。

包装

5, 25, 100 g in glass bottle

基本信息

线性分子式	BrCH₂CH₂COOCH₃
分子量	167.00
Beilstein	1742949
EC 号	222-247-5
MDL编号	MFCD00000250
PubChem化学物质编号	24854554
NACRES	NA.22

产品性质

质量水平	200
测定	97%
折射率	n20/D 1.458 (lit.)
bp	64-66 ℃/18 mmHg (lit.)
密度	1.53 g/mL at 25 ℃ (lit.)
SMILES string	COC(=O)CCBr
InChI	1S/C4H7BrO2/c1-7-4(6)2-3-5/h2-3H2,1H3
InChI key	KQEVIFKPZOGBMZ-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H302 - H315 - H319 - H335
预防措施声明	P301 + P312 + P330 - P302 + P352 - P305 + P351 + P338
危险分类	Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	10 - Combustible liquids
WGK	WGK 3
闪点(F)	167.0 °F - closed cup
闪点(C)	75 ℃ - closed cup
个人防护装备	Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

216315

Fluorochem

Methyl 3-bromopropanoate

95%

220元/1g; 286元/25g; 1034元/100g; 1892元/250g; 4708元/1kg;

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基本信息

CAS Number	3395-91-3
MDL Number	MFCD00000250
Boiling Point	64-66℃
Density	1.53

安全信息

图形或危害标志
危险性说明	H302: Harmful if swallowed. H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing . P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see relevant procedures. on this label). P330: Rinse mouth. P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to in accordance with local regulation .