CAS 3240-34-4; 二乙酸碘苯; Iodobenzene I,I-diacetate

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货号

品牌

产品名称

规格

包装、参考价格

D807066

MACKLIN

碘苯二乙酸

98%

24元/5g; 52元/25g; 150元/100g; 720元/500g; 3550元/2.5kg;

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储存：室温,避光
状态：白色到淡黄色晶体粉末

在橙花醇转化为橙花醛的 TEMPO 氧化反应中，作为计量氧化剂。

用作铑催化的烯烃与氨基磺酸酯进行氮杂环丙化反应中的氧化剂。

用于合成各种杂环化合物的试剂。

用于室温下钯催化的吲哚的 2-芳基化反应。

I0330

TCI

Iodobenzene Diacetate

>97.0%(T)

190元/10G; 460元/25G; 3250元/250G;

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基本信息

纯度/分析方法	>97.0%(T)
分子式/分子量	C₁₀H₁₁IO₄ = 322.10
外观与形状(20℃)	固体
储存在惰性气体下	存放于惰性气体之中
应避免的情况	湿气 (分解)
Reaxys-RN	1879369
PubChem物质ID	87571686
SDBS (AIST Spectral DB)	12662
MDL编号	MFCD00008692

技术规格

Appearance	White to Light yellow powder to crystal
Purity(Iodometric Titration)	min. 97.0 %
Solubility in Methanol	almost transparency

物性(参考值)

熔点	158 ℃(dec.)
水溶性	不溶
溶解性(可溶于)	甲醇
溶解性(不溶于)	乙醚

安全信息

图形或危害标志
信号词	警告
危险性说明	H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。
防范说明	P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/戴防护眼罩/戴防护面具。 P302 + P352 : 如皮肤沾染：用水充分清洗。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P332 + P313 : 如发生皮肤刺激：求医/就诊。

相关法规

RTECS#

DA3525000

138123

J&K

(Diacetoxyiodo)benzene

98%

327元/25G; 886元/100G; 3755元/500G;

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基本信息

分子式	C₁₀H₁₁IO₄
分子量	322.09
熔点	161-163
MDL编码	MFCD00008692
Beilstein	1879369
EINECS 编号	221-808-1

安全信息

图形或危害标志
提示语	Warning
危险说明	H315 H319
防范说明	P264 P280 P302+P352+P332+P313+P362+P364 P305+P351+P338+P337+P313
WGK	3
RTECS	DA3525000
TSCA	是

B24531

Alfa Aesar

Iodosobenzene diacetate

98+%

688元/25g; 2070元/100g; 9108元/500g;

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应用
Iodosobenzene is used as an oxidizing and acetoxylating agent in organic synthesis. It is actively involved in the preparation of (Z)-3,7-dimethyl-2,6-octadien-1-al(neral) from (Z)-3,7-dimethyl-2,6-octadien-1-ol (nerol) in presence of 2,2,6,6-tetramethylpiperidin-1-oxyl (TEMPO). It is a useful reagent for the synthesis of a wide variety of heterocyclic compounds. It is also used in the Pd-catalyzed 2-arylation of indoles.

备注
Light sensitive. Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00008692

EINECS
221-808-1

分子式
C₁₀H₁₁IO₄

分子量
322.10

熔点
159-161°

灵敏度
Light Sensitive. Ambient temperatures.

形态
Crystalline powder

溶解性
Insoluble in water.

Beilstein
1879369

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste

RTECS
DA3525000

TSCA
是

C17656

Alfa Aesar

Iodobenzene Diacetate

98%

949元/25g; 2689元/100g; 10427元/500g;

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基本信息

Ref#
17656

MDL
8692

分子式
C10 H11 I O4

分子量
322.09

形态
White to pale yellow cryst powder

安全信息

危险等级
6.1

包装组
III

178721

Sigma-Aldrich

(Diacetoxyiodo)benzene

98%

241.03元/5 G; 663.85元/25 G; 2061.38元/100 G; 6957.5元/1 KG;

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产品说明

应用

Rh2(esp)2: 一种非常高效的C-H胺化选择性催化剂
用于合成各种杂环化合物的试剂。
橙花醇转化为橙花醛的 TEMPO 氧化反应中的化学计量氧化剂。用作铑催化的烯烃与氨基磺酸酯进行氮杂环丙化反应中的氧化剂。
用于室温下钯催化的吲哚的 2-芳基化反应。
肟和吡啶底物的未活化sp³ C-H键与PhI(OAc)₂作为化学计量氧化剂进行高度区域选择性和化学选择性Pd(II)催化氧化。

包装

1 kg in glass bottle
5, 25, 100 g in glass bottle

基本信息

线性分子式	C₆H₅I(O₂CCH₃)₂
分子量	322.10
Beilstein	1879369
EC 号	221-808-1
MDL编号	MFCD00008692
PubChem化学物质编号	24850764

产品性质

质量水平	200
测定	98%
形式	powder
reaction suitability	reagent type: oxidant reaction type: C-H Activation
mp	161-163 ℃ (lit.)
SMILES string	CC(OI(OC(C)=O)C1=CC=CC=C1)=O
InChI	1S/C10H11IO4/c1-8(12)14-11(15-9(2)13)10-6-4-3-5-7-10/h3-7H,1-2H3
InChI key	ZBIKORITPGTTGI-UHFFFAOYSA-N

安全信息

储存分类代码	13 - Non Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Gloves, type N95 (US)

971899

Amethyst

Iodobenzene Diacetate

98%, 用于合成

84元/25G; 209元/100G; 788元/500G;

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基本信息

分子式	C₁₀H₁₁IO₄
分子量	322.09
熔点	161-163
MDL编码	MFCD00008692
EINECS 编号	221-808-1

安全信息

防范说明	P260 P262
WGK	3
RTECS	DA3525000
TSCA	是

091213

Fluorochem

(Diacetoxyiodo)benzene

98%

264元/1g; 330元/25g; 770元/100g; 2640元/500g;

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基本信息

CAS Number	3240-34-4
MDL Number	MFCD00008692
Melting Point	158-167℃

安全信息

图形或危害标志
危险性说明	H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing . P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see relevant procedures. on this label). P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to in accordance with local regulation .